scholarly journals Poly(methacrylic acid-ran-2-vinylpyridine) Statistical Copolymer and Derived Dual pH-Temperature Responsive Block Copolymers by Nitroxide-Mediated Polymerization

Processes ◽  
2017 ◽  
Vol 5 (4) ◽  
pp. 7 ◽  
Author(s):  
Milan Marić ◽  
Chi Zhang ◽  
Daniel Gromadzki
Keyword(s):  
Block Copolymers ◽  
Methacrylic Acid ◽  
Temperature Responsive ◽  
Statistical Copolymer ◽  
Nitroxide Mediated Polymerization

scholarly journals Nitroxide-mediated polymerization-induced self-assembly of amphiphilic block copolymers with a pH/temperature dual sensitive stabilizer block

2017 ◽  
Vol 8 (27) ◽  
pp. 4014-4029 ◽  
Author(s):  
X. G. Qiao ◽  
P.-Y. Dugas ◽  
B. Charleux ◽  
M. Lansalot ◽  
E. Bourgeat-Lami
Keyword(s):  
Block Copolymers ◽  
Emulsion Polymerization ◽  
Self Assembly ◽  
Small Proportion ◽  
Amphiphilic Block Copolymers ◽  
Temperature Responsive ◽  
Responsive Behavior ◽  
Nitroxide Mediated Polymerization

Comb-like P(PEOMA300-co-MAA-co-S)-SG1 macroalkoxyamine terpolymer initiators with dual pH/temperature responsive behavior were synthesized by nitroxide-mediated polymerization and used to control the emulsion polymerization of BMA with a small proportion of styrene.

Mechanical and Structural Consequences of Associative Dynamic Cross-Linking in Acrylic Diblock Copolymers

2019 ◽  
Author(s):  
Jacob Ishibashi ◽  
Yan Fang ◽  
Julia Kalow
Keyword(s):  
Block Copolymers ◽  
Rheological Properties ◽  
Diblock Copolymers ◽  
Cross Linking ◽  
Statistical Copolymer

<p>Block copolymers are used to construct covalent adaptable networks that employ associative exchange chemistry (vitrimers). The resulting vitrimers display markedly different nanostructural, thermal and rheological properties relative to those of their statistical copolymer-derived counterparts. This study demonstrates that prepolymer sequence is a versatile strategy to modify the properties of vitrimers.</p>

On the nitroxide mediated polymerization of methacrylates derived from bio-sourced terpenes in miniemulsion, a step towards sustainable products

2020 ◽  
Vol 11 (6) ◽  
pp. 1151-1160 ◽  
Author(s):  
Sayrung Noppalit ◽  
Alexandre Simula ◽  
Laurent Billon ◽  
José M. Asua
Keyword(s):  
Block Copolymers ◽  
Sustainable Products ◽  
Nitroxide Mediated Polymerization

The typical use of toxic solvents, expensive control agents and the need of intermediate purification steps hinders the introduction of bio-sourced monomers into industrially viable block copolymers. This study aims at overcoming these limitations.

scholarly journals Recent Advances in Dual Temperature Responsive Block Copolymers and Their Potential as Biomedical Applications

Polymers ◽  
2016 ◽  
Vol 8 (11) ◽  
pp. 380 ◽  
Author(s):  
Yohei Kotsuchibashi ◽  
Mitsuhiro Ebara ◽  
Takao Aoyagi ◽  
Ravin Narain
Keyword(s):  
Block Copolymers ◽  
Biomedical Applications ◽  
Temperature Responsive ◽  
Recent Advances

A nanoparticle-preparation kit using ethylene glycol-based block copolymers with a common temperature-responsive block

2017 ◽  
Vol 8 (47) ◽  
pp. 7311-7315 ◽  
Author(s):  
Yohei Kotsuchibashi ◽  
Chun Man Lee ◽  
Iren Constantinescu ◽  
Lily E. Takeuchi ◽  
Sreeparna Vappala ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Ethylene Glycol ◽  
Temperature Responsive ◽  
Nanoparticle Preparation

A nanoparticle-preparation kit system using ethylene glycol-based block copolymers with a common temperature-responsive block was developed.

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