Rapid solvo-microwave annealing for optimizing ordered nanostructures and crystallization of regioregular polythiophene-based block copolymers

2019 ◽  
Vol 10 (36) ◽  
pp. 4962-4972 ◽  
Author(s):  
Junghun Han ◽  
Jin-Seong Kim ◽  
Jae Man Shin ◽  
Hongseok Yun ◽  
Youngkwon Kim ◽  
...  
Keyword(s):  
Thin Films ◽  
Block Copolymers ◽  
Processing Time ◽  
Ordered Structures ◽  
High Crystallinity ◽  
Microwave Annealing ◽  
Short Processing Time ◽  
Ordered Nanostructures

Solvo-microwave annealing is an effective method for producing thin films of polythiophene-based block copolymers with ordered structures and high crystallinity in a very short processing time (∼3 min).

scholarly journals Precise Synthesis and Thin Film Self-Assembly of PLLA-b-PS Bottlebrush Block Copolymers

Molecules ◽  
2021 ◽  
Vol 26 (5) ◽  
pp. 1412
Author(s):  
Eunkyung Ji ◽  
Cian Cummins ◽  
Guillaume Fleury
Keyword(s):  
Thin Film ◽  
Block Copolymers ◽  
Self Assembly ◽  
Ring Opening ◽  
Periodic Structures ◽  
One Pot ◽  
Ordered Structures ◽  
Carbonyl Chloride ◽  
Thin Film Patterning ◽  
Nanoporous Templates

The ability of bottlebrush block copolymers (BBCPs) to self-assemble into ordered large periodic structures could greatly expand the scope of photonic and membrane technologies. In this paper, we describe a two-step synthesis of poly(l-lactide)-b-polystyrene (PLLA-b-PS) BBCPs and their rapid thin-film self-assembly. PLLA chains were grown from exo-5-norbornene-2-methanol via ring-opening polymerization (ROP) of l-lactide to produce norbornene-terminated PLLA. Norbonene-terminated PS was prepared using anionic polymerization followed by a termination reaction with exo-5-norbornene-2-carbonyl chloride. PLLA-b-PS BBCPs were prepared from these two norbornenyl macromonomers by a one-pot sequential ring opening metathesis polymerization (ROMP). PLLA-b-PS BBCPs thin-films exhibited cylindrical and lamellar morphologies depending on the relative block volume fractions, with domain sizes of 46–58 nm and periodicities of 70–102 nm. Additionally, nanoporous templates were produced by the selective etching of PLLA blocks from ordered structures. The findings described in this work provide further insight into the controlled synthesis of BBCPs leading to various possible morphologies for applications requiring large periodicities. Moreover, the rapid thin film patterning strategy demonstrated (>5 min) highlights the advantages of using PLLA-b-PS BBCP materials beyond their linear BCP analogues in terms of both dimensions achievable and reduced processing time.

Ordered Structures of Styrene Butadiene Block Copolymers

1967 ◽  
Vol 40 (5) ◽  
pp. 1526-1528
Author(s):  
Ed Vanzo
Keyword(s):  
Solid State ◽  
Block Copolymers ◽  
Mechanical Deformation ◽  
Solution Properties ◽  
Two Dimensional ◽  
Ordered Structure ◽  
Ordered Structures ◽  
Polymer Molecules ◽  
Cast Films ◽  
Styrene Butadiene

Abstract Anionically prepared block copolymers of butadiene and styrene exhibit solution properties which result from a two dimensional ordering of the polymer molecules. The most notable of these properties is the iridescent colors of toluene solutions which are dependent on concentration and abruptly change on mechanical deformation. Electron micrographs of the surface of cast films indicate that the ordered structure is retained to some degree in the solid state.

scholarly journals Role of dissimilar interfaces in thin films of cylinder-forming block copolymers

2004 ◽  
Vol 120 (2) ◽  
pp. 1127-1137 ◽  
Author(s):  
K. S. Lyakhova ◽  
G. J. A. Sevink ◽  
A. V. Zvelindovsky ◽  
A. Horvat ◽  
R. Magerle
Keyword(s):  
Thin Films ◽  
Block Copolymers

Highly ordered nanoporous thin films by blending of PSt-b-PMMA block copolymers and PEO additives as structure directing agents

2008 ◽  
Vol 46 (24) ◽  
pp. 8041-8048 ◽  
Author(s):  
Sung Chan Park ◽  
Hyunjung Jung ◽  
Ken-ichi Fukukawa ◽  
Luis M. Campos ◽  
Kyunghee Lee ◽  
...  
Keyword(s):  
Thin Films ◽  
Block Copolymers ◽  
Structure Directing Agents

Hexagonally ordered arrays of metallic nanodots from thin films of functional block copolymers

Polymer ◽  
2010 ◽  
Vol 51 (12) ◽  
pp. 2661-2667 ◽  
Author(s):  
E. Bhoje Gowd ◽  
Bhanu Nandan ◽  
Nadja C. Bigall ◽  
Alexander Eychmüller ◽  
Petr Formanek ◽  
...  
Keyword(s):  
Thin Films ◽  
Block Copolymers ◽  
Ordered Arrays ◽  
Functional Block ◽  
Hexagonally Ordered ◽  
Functional Block Copolymers

Study of the Kinetics and Mechanism of Rapid Self-Assembly in Block Copolymer Thin Films during Solvo-Microwave Annealing

Langmuir ◽  
2014 ◽  
Vol 30 (35) ◽  
pp. 10728-10739 ◽  
Author(s):  
Parvaneh Mokarian-Tabari ◽  
Cian Cummins ◽  
Sozaraj Rasappa ◽  
Claudia Simao ◽  
Clivia M. Sotomayor Torres ◽  
...  
Keyword(s):  
Thin Films ◽  
Block Copolymer ◽  
Self Assembly ◽  
Kinetics And Mechanism ◽  
Microwave Annealing

scholarly journals USULAN PENJADWALAN PRODUKSI PRODUK ST 37777 PT EBAKO NUSANTARA PADA DEPARTEMEN SMOOTHMILLING UNTUK MEMINIMASI MAKESPAN

2018 ◽  
Vol 13 (1) ◽  
pp. 61
Author(s):  
Mellysa Asmawar
Keyword(s):  
Production Process ◽  
Processing Time ◽  
Manufacturing Industry ◽  
Job Scheduling ◽  
Makespan Minimization ◽  
Central Java ◽  
Short Processing Time ◽  
Jobshop Scheduling ◽  
Machine Work

AbstrakProses produksi ST 37777 di PT Ebako Nusantara menggunakan jadwal yang didasarkan oleh proses-proses yang dilakukan dengan menggunakan data historis yang telah ada dari proses produksi yang telah dilakukan. PT Ebako Nusantara merupakan industri manufaktur yang bergerak di bidang furnitur yang berlokasi di Terboyo, Semarang, Jawa Tengah. Dalam proses produksi ST 37777, terdapat 11 mesin dan 16 job dimana setiap job memiliki urutan mesin yang berbeda. Penjadwalan yang ada untuk produk tipe ST 37777 dengan tipe jobshop belum menerapkan suatu ketetapan dalam penentuan waktu dan urutan pengerjaan mesin yang efektif sehingga masih banyak job yang selesai terlambat. Untuk itu diperlukan suatu penjadwalan mesin yang efektif sehingga dapat memenuhi waktu produksi pesanan sesuai dengan yang telah disepakati. Penjadwalan jobshop diperlukan untuk memaksimumkan efisiensi dan utilitas sumber daya di lantai produksi. Penentuan jadwal mesin ini bertujuan meminimasi makespan dengan menggunakan Software WINQSB modul job schedulling. Metode yang digunakan adalah metode Short Processing Time. Hasil penjadwalan menggunakan Software WINQSB diperoleh makespan menjadi 15 jam dengan hasil penjadwalan tersebut tidak ada job yang terlambat dan semua job dikerjakan berurutan. AbstractThe production process of ST 37777 in PT Ebako Nusantara uses a schedule based on the processes performed using existing historical data from the production process that has been done. PT Ebako Nusantara is a manufacturing industry engaged in furnitur located in Terboyo, Semarang, Central Java. In the production process ST 37777, there are 11 machines and 16 jobs where each job has a different sequence of machines. The existing scheduling for ST 37777 type product with jobshop type has not been applied a determination in the timing and sequence of effective machine work so that many jobs are finished too late. For that required an effective engine scheduling so that it can meet the production time of orders in accordance with the agreed. Jobshop scheduling is needed to maximize efficiency and resource utilities on the production floor. Determination of this machine schedule aims to minimize the makespan using WINQSB Software job scheduling module. The method used is the method of Short Processing Time. The scheduling result using WINQSB software obtained makespan to 15 hours with scheduling result no job is late and all job done in sequence. Keywords: Jobshop Scheduling; Short Processing Time; Makespan Minimization

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