Carboxylation of terminal alkynes promoted by silver carbamate at ambient pressure

Giulio Bresciani; Fabio Marchetti; Guido Pampaloni

doi:10.1039/c9nj02203a

Carboxylation of terminal alkynes promoted by silver carbamate at ambient pressure

New Journal of Chemistry ◽

10.1039/c9nj02203a ◽

2019 ◽

Vol 43 (27) ◽

pp. 10821-10825 ◽

Cited By ~ 2

Author(s):

Giulio Bresciani ◽

Fabio Marchetti ◽

Guido Pampaloni

Keyword(s):

Ambient Pressure ◽

Terminal Alkynes ◽

Silver Carbamate

Simple and easily available silver and copper carbamates were investigated as catalysts for the carboxylation of terminal alkynes. Ag(O2CNMe2), combined with Cs2CO3, afforded propiolic acids at ambient CO2 pressure in satisfying yields.

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A Schiff base-modified silver catalyst for efficient fixation of CO2 as carboxylic acid at ambient pressure

Green Chemistry ◽

10.1039/c7gc00923b ◽

2017 ◽

Vol 19 (9) ◽

pp. 2080-2085 ◽

Cited By ~ 30

Author(s):

Zhilian Wu ◽

Lei Sun ◽

Qinggang Liu ◽

Xiaofeng Yang ◽

Xue Ye ◽

...

Keyword(s):

Schiff Base ◽

Carboxylic Acid ◽

Carboxylic Acids ◽

Ambient Pressure ◽

Terminal Alkynes ◽

Silver Catalyst ◽

Efficient Synthesis

A Schiff base-modified silver catalyst was developed for the direct carboxylation of terminal alkynes with CO2, enabling the efficient synthesis of valuable alkynyl carboxylic acids.

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Copper(i)/phosphine-catalyzed tandem carboxylation/annulation of terminal alkynes under ambient pressure of CO2: one-pot access to 3a-hydroxyisoxazolo[3,2-a]isoindol-8(3aH)-ones

Green Chemistry ◽

10.1039/c5gc00926j ◽

2015 ◽

Vol 17 (7) ◽

pp. 4061-4067 ◽

Cited By ~ 28

Author(s):

Jia-Ning Xie ◽

Bing Yu ◽

Chun-Xiang Guo ◽

Liang-Nian He

Keyword(s):

Catalytic System ◽

Ambient Pressure ◽

Terminal Alkynes ◽

One Pot ◽

Simultaneous Formation ◽

Stepwise Manner

A tandem carboxylation/annulation sequence promoted by a copper(i)/phosphine catalytic system was developed with simultaneous formation of four novel bonds i.e. two C–C bonds and two C–O bonds in a one-pot stepwise manner.

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Carboxylation of terminal alkynes with CO2 catalyzed by bis(amidate) rare-earth metal amides

Green Chemistry ◽

10.1039/c4gc02200a ◽

2015 ◽

Vol 17 (3) ◽

pp. 1675-1682 ◽

Cited By ~ 44

Author(s):

Hao Cheng ◽

Bei Zhao ◽

Yingming Yao ◽

Chengrong Lu

Keyword(s):

Rare Earth ◽

Rare Earth Metal ◽

Ambient Pressure ◽

Earth Metal ◽

Terminal Alkynes ◽

Metal Amides

Three novel bis(amidate) rare-earth metal amides were prepared and characterized. Treatment of CO2 with terminal alkynes obtained propiolic acids in high to excellent yields using the highest reactive Nd-based catalyst at ambient pressure.

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Silver nanoparticles embedded over porous metal organic frameworks for carbon dioxide fixation via carboxylation of terminal alkynes at ambient pressure

Journal of Colloid and Interface Science ◽

10.1016/j.jcis.2016.05.037 ◽

2016 ◽

Vol 477 ◽

pp. 220-229 ◽

Cited By ~ 48

Author(s):

Rostam Ali Molla ◽

Kajari Ghosh ◽

Biplab Banerjee ◽

Md. Asif Iqubal ◽

Sudipta K. Kundu ◽

...

Keyword(s):

Carbon Dioxide ◽

Silver Nanoparticles ◽

Ambient Pressure ◽

Metal Organic Frameworks ◽

Porous Metal ◽

Carbon Dioxide Fixation ◽

Terminal Alkynes ◽

Metal Organic

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ChemInform Abstract: Copper(I)/Phosphine-Catalyzed Tandem Carboxylation/Annulation of Terminal Alkynes under Ambient Pressure of CO2: One-Pot Access to 3a-Hydroxyisoxazolo[3,2-a]isoindol-8(3aH)-ones.

ChemInform ◽

10.1002/chin.201547134 ◽

2015 ◽

Vol 46 (47) ◽

pp. no-no

Author(s):

Jia-Ning Xie ◽

Bing Yu ◽

Chun-Xiang Guo ◽

Liang-Nian He

Keyword(s):

Ambient Pressure ◽

Terminal Alkynes ◽

One Pot

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Environmental microscopy of capillary stress-induced strain behavior in ambient-pressure aerogels

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100166713 ◽

1996 ◽

Vol 54 ◽

pp. 850-851

Author(s):

Sudeep M. Rao ◽

Joshua Samuel ◽

Sai S. Prakash ◽

C. Jeffrey Brinker

Keyword(s):

Silica Aerogel ◽

Ambient Pressure ◽

Drying Shrinkage ◽

Pore Filling ◽

Silica Network ◽

Strain Behavior ◽

Partially Saturated ◽

Capillary Stress ◽

Wetting Liquid ◽

Aerogel Films

Ambient pressure silica aerogel thin films have recently been prepared by exploiting reversible drying shrinkage caused by derivatization of the internal gel surface. Aerogels have porosities of upto 99.9% and due to the small size of the pores (few nanometers), large capillary stresses are produced in gels that are partially saturated with a wetting liquid. As a result of these capillary stresses, the flexible silica network undergoes strain which has been observed using environmental microscopy. This technique allows variation of the equilibrium vapor pressure and temperature, and a simultaneous monitoring of the deformation of the unconstrained film thickness. We have observed >600% deformation during the pore-filling and pore-emptying cycles. In this presentation, we discuss the unique stress-strain behavior of these films.Ref.: Sai S. Prakash, C. Jeffrey Brinker, Alan J. Hurd & Sudeep M. Rao, "Silica aerogel films prepared at ambient pressure by using surface derivatization to induce reversible drying shrinkage", Nature. Vol. 374, 30 March, 1995, 439-443.

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