Carboxylation of terminal alkynes with CO2 catalyzed by bis(amidate) rare-earth metal amides

Hao Cheng; Bei Zhao; Yingming Yao; Chengrong Lu

doi:10.1039/c4gc02200a

Carboxylation of terminal alkynes with CO2 catalyzed by bis(amidate) rare-earth metal amides

Green Chemistry ◽

10.1039/c4gc02200a ◽

2015 ◽

Vol 17 (3) ◽

pp. 1675-1682 ◽

Cited By ~ 44

Author(s):

Hao Cheng ◽

Bei Zhao ◽

Yingming Yao ◽

Chengrong Lu

Keyword(s):

Rare Earth ◽

Rare Earth Metal ◽

Ambient Pressure ◽

Earth Metal ◽

Terminal Alkynes ◽

Metal Amides

Three novel bis(amidate) rare-earth metal amides were prepared and characterized. Treatment of CO2 with terminal alkynes obtained propiolic acids in high to excellent yields using the highest reactive Nd-based catalyst at ambient pressure.

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ChemInform Abstract: Carboxylation of Terminal Alkynes with CO2Catalyzed by Bis(amidate) Rare-Earth Metal Amides.

ChemInform ◽

10.1002/chin.201529069 ◽

2015 ◽

Vol 46 (29) ◽

pp. no-no

Author(s):

Hao Cheng ◽

Bei Zhao ◽

Yingming Yao ◽

Chengrong Lu

Keyword(s):

Rare Earth ◽

Rare Earth Metal ◽

Earth Metal ◽

Terminal Alkynes ◽

Metal Amides

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Reactivity of 3-Imino-Functionalized Indoles with Rare-Earth-Metal Amides: Unexpected Substituent Effects on C–H Activation Pathways and Assembly of Rare-Earth-Metal Complexes

Organometallics ◽

10.1021/acs.organomet.6b00221 ◽

2016 ◽

Vol 35 (11) ◽

pp. 1838-1846 ◽

Cited By ~ 14

Author(s):

Xiancui Zhu ◽

Yang Li ◽

Yun Wei ◽

Shaowu Wang ◽

Shuangliu Zhou ◽

...

Keyword(s):

Rare Earth ◽

Metal Complexes ◽

Rare Earth Metal ◽

Substituent Effects ◽

Earth Metal ◽

Metal Amides ◽

Activation Pathways ◽

Rare Earth Metal Complexes

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Synthesis and characterization of anionic rare-earth metal amides stabilized by phenoxy-amido ligands and their catalytic behavior for the polymerization of lactide

Dalton Transactions ◽

10.1039/c0dt00025f ◽

2010 ◽

Vol 39 (40) ◽

pp. 9530 ◽

Cited By ~ 32

Author(s):

Min Lu ◽

Yingming Yao ◽

Yong Zhang ◽

Qi Shen

Keyword(s):

Rare Earth ◽

Rare Earth Metal ◽

Earth Metal ◽

Synthesis And Characterization ◽

Amido Ligands ◽

Catalytic Behavior ◽

Metal Amides

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Addition of Thiols to Isocyanates Catalyzed by Simple Rare-Earth-Metal Amides: Synthesis of S-Alkyl Thiocarbamates and Dithiocarbamates

Organometallics ◽

10.1021/acs.organomet.9b00147 ◽

2019 ◽

Vol 38 (9) ◽

pp. 2167-2173 ◽

Cited By ~ 3

Author(s):

Chengrong Lu ◽

Lijuan Hu ◽

Bei Zhao ◽

Yingming Yao

Keyword(s):

Rare Earth ◽

Rare Earth Metal ◽

Earth Metal ◽

Metal Amides

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Synthesis of (Z)-1-Aza-1,3-enynes by the Cross-Coupling of Terminal Alkynes with Isocyanides Catalyzed by Rare-Earth Metal Complexes

Angewandte Chemie International Edition ◽

10.1002/anie.200804306 ◽

2008 ◽

Vol 47 (50) ◽

pp. 9700-9703 ◽

Cited By ~ 49

Author(s):

Wen-Xiong Zhang ◽

Masayoshi Nishiura ◽

Zhaomin Hou

Keyword(s):

Rare Earth ◽

Metal Complexes ◽

Rare Earth Metal ◽

Earth Metal ◽

Cross Coupling ◽

Terminal Alkynes ◽

The Cross ◽

Rare Earth Metal Complexes

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ChemInform Abstract: Synthesis, Characterization, Selective Catalytic Activity, and Reactivity of Rare Earth Metal Amides with Different MetalâNitrogen Bonds.

ChemInform ◽

10.1002/chin.200949179 ◽

2009 ◽

Vol 40 (49) ◽

Cited By ~ 1

Author(s):

Shaowu Wang ◽

et al. et al.

Keyword(s):

Catalytic Activity ◽

Rare Earth ◽

Rare Earth Metal ◽

Earth Metal ◽

Metal Amides ◽

Nitrogen Bonds

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Synthesis of Rare-Earth Metal Amides Bearing an Imidazolidine-Bridged Bis(phenolato) Ligand and Their Application in the Polymerization ofl-Lactide

Inorganic Chemistry ◽

10.1021/ic802177y ◽

2009 ◽

Vol 48 (13) ◽

pp. 5715-5724 ◽

Cited By ~ 89

Author(s):

Zhongjian Zhang ◽

Xiaoping Xu ◽

Wenyi Li ◽

Yingming Yao ◽

Yong Zhang ◽

...

Keyword(s):

Rare Earth ◽

Rare Earth Metal ◽

Earth Metal ◽

Metal Amides

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Highly Efficient Regio- and Stereoselective Dimerization of (Hetero)aromatic Terminal Alkynes by Organo Rare-Earth Metal Catalysts

Organometallics ◽

10.1021/om700893f ◽

2007 ◽

Vol 26 (26) ◽

pp. 6508-6510 ◽

Cited By ~ 34

Author(s):

Shaozhong Ge ◽

Victor F. Quiroga Norambuena ◽

Bart Hessen

Keyword(s):

Rare Earth ◽

Rare Earth Metal ◽

Earth Metal ◽

Metal Catalysts ◽

Terminal Alkynes ◽

Highly Efficient

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Rare-Earth Metal Boroxide with Formal Triple Metal–Oxygen Orbital Interaction: Synthesis from B(C 6 F 5 ) 3 ·H 2 O and Radical-Anion Ligated Rare-Earth Metal Amides

CCS Chemistry ◽

10.31635/ccschem.020.202000587 ◽

2020 ◽

pp. 2772-2781

Author(s):

Haihan Yan ◽

Botao Wu ◽

Xiao-Kun Zhao ◽

Chao Yu ◽

Junnian Wei ◽

...

Keyword(s):

Rare Earth ◽

Rare Earth Metal ◽

Radical Anion ◽

Earth Metal ◽

Orbital Interaction ◽

Metal Amides

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Cyclopentadienyl-Free Rare-Earth Metal Amides [{(CH2SiMe2){(2,6-iPr2C6H3)N}2}Ln{N(SiMe3)2}(THF)] as Highly Efficient Versatile Catalysts for CâC and CâN Bond Formation

European Journal of Organic Chemistry ◽

10.1002/ejoc.200901015 ◽

2010 ◽

Vol 2010 (2) ◽

pp. 326-332 ◽

Cited By ~ 39

Author(s):

Yunjun Wu ◽

Shaowu Wang ◽

Lijun Zhang ◽

Gaosheng Yang ◽

Xiancui Zhu ◽

...

Keyword(s):

Rare Earth ◽

Rare Earth Metal ◽

Bond Formation ◽

Earth Metal ◽

Metal Amides ◽

Highly Efficient

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Carboxylation of terminal alkynes with CO2 catalyzed by bis(amidate) rare-earth metal amides

ChemInform Abstract: Carboxylation of Terminal Alkynes with CO2Catalyzed by Bis(amidate) Rare-Earth Metal Amides.

Reactivity of 3-Imino-Functionalized Indoles with Rare-Earth-Metal Amides: Unexpected Substituent Effects on C–H Activation Pathways and Assembly of Rare-Earth-Metal Complexes

Synthesis and characterization of anionic rare-earth metal amides stabilized by phenoxy-amido ligands and their catalytic behavior for the polymerization of lactide

Addition of Thiols to Isocyanates Catalyzed by Simple Rare-Earth-Metal Amides: Synthesis of S-Alkyl Thiocarbamates and Dithiocarbamates

Synthesis of (Z)-1-Aza-1,3-enynes by the Cross-Coupling of Terminal Alkynes with Isocyanides Catalyzed by Rare-Earth Metal Complexes

ChemInform Abstract: Synthesis, Characterization, Selective Catalytic Activity, and Reactivity of Rare Earth Metal Amides with Different MetalâNitrogen Bonds.

Synthesis of Rare-Earth Metal Amides Bearing an Imidazolidine-Bridged Bis(phenolato) Ligand and Their Application in the Polymerization ofl-Lactide

Highly Efficient Regio- and Stereoselective Dimerization of (Hetero)aromatic Terminal Alkynes by Organo Rare-Earth Metal Catalysts

Rare-Earth Metal Boroxide with Formal Triple Metal–Oxygen Orbital Interaction: Synthesis from B(C 6 F 5 ) 3 ·H 2 O and Radical-Anion Ligated Rare-Earth Metal Amides

Cyclopentadienyl-Free Rare-Earth Metal Amides [{(CH2SiMe2){(2,6-iPr2C6H3)N}2}Ln{N(SiMe3)2}(THF)] as Highly Efficient Versatile Catalysts for CâC and CâN Bond Formation

ChemInform Abstract: Synthesis, Characterization, Selective Catalytic Activity, and Reactivity of Rare Earth Metal Amides with Different MetalâNitrogen Bonds.

Cyclopentadienyl-Free Rare-Earth Metal Amides [{(CH2SiMe2){(2,6-iPr2C6H3)N}2}Ln{N(SiMe3)2}(THF)] as Highly Efficient Versatile Catalysts for CâC and CâN Bond Formation