N2O5 reactive uptake kinetics and chlorine activation on authentic biomass-burning aerosol

2019 ◽  
Vol 21 (10) ◽  
pp. 1684-1698
Author(s):  
Lexie A. Goldberger ◽  
Lydia G. Jahl ◽  
Joel A. Thornton ◽  
Ryan C. Sullivan

The reactive uptake kinetics of nitrogen pentoxide (N2O5) to authentic biomass-burning aerosol and the production of nitryl chloride (ClNO2) was determined using an entrained aerosol flow tube reactor.

Author(s):  
Domenik Schleier ◽  
Engelbert Reusch ◽  
Marius Gerlach ◽  
Tobias Preitschopf ◽  
Deb Pratim Mukhopadhyay ◽  
...  

The reaction kinetics of the isomers of the methylallyl radical with molecular oxygen has been studied in a flow tube reactor at the vacuum ultraviolet (VUV) beamline of the Swiss Light Source storage ring.


2018 ◽  
Vol 20 (16) ◽  
pp. 10721-10731 ◽  
Author(s):  
D. Schleier ◽  
P. Constantinidis ◽  
N. Faßheber ◽  
I. Fischer ◽  
G. Friedrichs ◽  
...  

The kinetics of the allyl + O2 reaction has been studied in a flow tube reactor, using VUV synchrotron radiation for product detection.


RSC Advances ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 4230-4238 ◽  
Author(s):  
Qilei Zhang ◽  
Xiaoxiao Lin ◽  
Yanbo Gai ◽  
Qiao Ma ◽  
Weixiong Zhao ◽  
...  

Reaction kinetics of O3with fourcis-3-hexenyl esters were studied using experimental methods in a flow tube reactor as well as using theoretical methods.


1993 ◽  
Vol 334 ◽  
Author(s):  
Bruce H. Weiller

AbstractThis paper explores the use of a flow-tube reactor coupled to an FTIR spectrometer to study gas-phase chemical reactions in CVD systems. We show that our apparatus can generate reliable kinetics data by reproducing the literature rate constant for the reaction between O3 and isobutene. We present data from this apparatus on two technologically important systems: TiN from Ti(NMe2)4 (TDMAT) and NH3 and SiO2 from tetraethoxysilane (TEOS) and O3. The results presented include kinetics data for the reaction of Ti(NMe2)4 with NH3 and ND3 at room temperature and the IR spectra of the products from the reaction of TEOS with O3 at 175°C.


2021 ◽  
Vol 13 (10) ◽  
pp. 2001
Author(s):  
Antonella Boselli ◽  
Alessia Sannino ◽  
Mariagrazia D’Emilio ◽  
Xuan Wang ◽  
Salvatore Amoruso

During the summer of 2017, multiple huge fires occurred on Mount Vesuvius (Italy), dispersing a large quantity of ash in the surrounding area ensuing the burning of tens of hectares of Mediterranean scrub. The fires affected a very large area of the Vesuvius National Park and the smoke was driven by winds towards the city of Naples, causing daily peak values of particulate matter (PM) concentrations at ground level higher than the limit of the EU air quality directive. The smoke plume spreading over the area of Naples in this period was characterized by active (lidar) and passive (sun photometer) remote sensing as well as near-surface (optical particle counter) observational techniques. The measurements allowed us to follow both the PM variation at ground level and the vertical profile of fresh biomass burning aerosol as well as to analyze the optical and microphysical properties. The results evidenced the presence of a layer of fine mode aerosol with large mean values of optical depth (AOD > 0.25) and Ångstrom exponent (γ > 1.5) above the observational site. Moreover, the lidar ratio and aerosol linear depolarization obtained from the lidar observations were about 40 sr and 4%, respectively, consistent with the presence of biomass burning aerosol in the atmosphere.


1990 ◽  
Vol 124 (2) ◽  
pp. 175-182 ◽  
Author(s):  
A. Jungk ◽  
C. J. Asher ◽  
D. G. Edwards ◽  
D. Meyer

2016 ◽  
Vol 17 (11) ◽  
pp. 577-585 ◽  
Author(s):  
Aline Macedo de Oliveira ◽  
Glauber Lopes Mariano ◽  
Marcelo Félix Alonso ◽  
Ericka Voss Chagas Mariano

Sign in / Sign up

Export Citation Format

Share Document