Cooperative proton transportation based on the reversible single crystal–single crystal transformation in a highly water-stable Cu-MOF with its facile and scalable preparation

CrystEngComm ◽  
2019 ◽  
Vol 21 (44) ◽  
pp. 6693-6697
Author(s):  
Jun Zhang ◽  
Xiaofan Ma ◽  
Weili Kong ◽  
Guodong Lu ◽  
Xiaopeng Xuan
Keyword(s):  
Single Crystal ◽  
Proton Conductivity ◽  
Boiling Water ◽  
Acid Base ◽  
Mild Conditions ◽  
Crystal Transformation ◽  
Base Stability

A Cu-MOF with excellent acid–base stability in boiling water was constructed under mild conditions. This MOF was very suitable for scaled-up preparation, and exhibits distinct proton conductivity at temperatures above and below 75 °C.

Single-crystal-to-single-crystal transformation and proton conductivity of three hydrogen-bonded organic frameworks

2020 ◽  
Vol 56 (99) ◽  
pp. 15529-15532
Author(s):  
Yijie Wang ◽  
Minghui Zhang ◽  
Qianqian Yang ◽  
Jianbo Yin ◽  
Di Liu ◽  
...  
Keyword(s):  
Single Crystal ◽  
Proton Conductivity ◽  
Water Molecules ◽  
Crystal Transformation ◽  
Hydrogen Bonded

In this communication, we report the SCSC transformation and proton conductivity of three H-bonded organic frameworks. The results show that H-bonded systems can improve their proton conductivity by uptaking water molecules based on the adaptability.

scholarly journals Enhanced proton conductivity in a flexible metal–organic framework promoted by single-crystal-to-single-crystal transformation

2021 ◽  
Vol 57 (1) ◽  
pp. 65-68
Author(s):  
Xi Chen ◽  
Zhongyue Zhang ◽  
Jin Chen ◽  
Sergei Sapchenko ◽  
Xue Han ◽  
...  
Keyword(s):  
Single Crystal ◽  
Proton Conductivity ◽  
Structural Transition ◽  
Metal Organic Framework ◽  
Crystal Transformation ◽  
P Transformation ◽  
Metal Organic ◽  
Flexible Metal ◽  
Organic Framework

Transformation of MFM-722(Pb)-DMA to MFM-722(Pb)-H2O leads to an increase in proton conductivity linked to a structural transition.

Single crystal to single crystal transformation of spin-crossover coordination polymers from 3D frameworks to 2D layers

2021 ◽  
Vol 9 (15) ◽  
pp. 5082-5087
Author(s):  
Yu Gong ◽  
Wang-Kang Han ◽  
Hui-Shu Lu ◽  
Qing-Tao Hu ◽  
Huan Tu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Ligand Exchange ◽  
Spin Crossover ◽  
Metal Organic Frameworks ◽  
Crystal Transformation ◽  
Metal Organic

New Hofmann-type metal–organic frameworks display rare and complete ligand exchange induced single crystal to single crystal transformations from 3D frameworks to 2D layers, accompanied by magnetic properties transition from two-step SCO behavior to hysteretic SCO behavior.

scholarly journals Solid-State Conformational Flexibility at Work: Energetic Landscape of a Single Crystal-to-Single Crystal Transformation in a Cyclic Hexapeptoid

2021 ◽  
Vol 21 (2) ◽  
pp. 897-907
Author(s):  
Giovanni Pierri ◽  
Marta Corno ◽  
Eleonora Macedi ◽  
Maria Voccia ◽  
Consiglia Tedesco
Keyword(s):  
Solid State ◽  
Single Crystal ◽  
Conformational Flexibility ◽  
Crystal Transformation

Water molecule induced reversible single-crystal-to-single-crystal transformation between two trinuclear Fe(ii) complexes with different spin crossover behaviour

2018 ◽  
Vol 47 (12) ◽  
pp. 4307-4314 ◽  
Author(s):  
Wen-Bin Chen ◽  
Yan-Cong Chen ◽  
Meng Yang ◽  
Ming-Liang Tong ◽  
Wen Dong
Keyword(s):  
Water Molecule ◽  
Single Crystal ◽  
Spin Crossover ◽  
Crystal Transformation

Water molecule induced reversible single-crystal-to-single-crystal transformation between two trinuclear Fe(ii) complexes with different spin crossover behaviour.

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