Selective on/off switching at room temperature of a magnetic bistable {Fe2Co2} complex with single crystal-to-single crystal transformation via intramolecular electron transfer

2014 ◽  
Vol 50 (14) ◽  
pp. 1665-1667 ◽  
Author(s):  
Li Cao ◽  
Jun Tao ◽  
Qian Gao ◽  
Tao Liu ◽  
Zhengcai Xia ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Single Crystal ◽  
Room Temperature ◽  
Intramolecular Electron Transfer ◽  
Crystal Transformation

Reversible single-crystal-to-single-crystal transformation from a mononuclear complex to a fourfold interpenetrated MOF with selective adsorption of CO2

2015 ◽  
Vol 44 (46) ◽  
pp. 19796-19799 ◽  
Author(s):  
Min-Min Liu ◽  
Yan-Lin Bi ◽  
Qin-Qin Dang ◽  
Xian-Ming Zhang
Keyword(s):  
Single Crystal ◽  
Room Temperature ◽  
Selective Adsorption ◽  
Low Pressure ◽  
Mononuclear Complex ◽  
Crystal Transformation ◽  
Adsorption Of Co ◽  
Adsorption Of Co2

Reversible crystal transformation was observed between a mononuclear complex to a fourfold interpenetrated MOF with selective adsorption of CO2 up to 12.5 wt% at room temperature and low pressure.

A 3D MOF showing unprecedented solvent-induced single-crystal-to-single-crystal transformation and excellent CO2 adsorption selectivity at room temperature

2014 ◽  
Vol 50 (100) ◽  
pp. 15886-15889 ◽  
Author(s):  
Tao Qin ◽  
Jun Gong ◽  
Junhan Ma ◽  
Xin Wang ◽  
Yonghua Wang ◽  
...  
Keyword(s):  
Single Crystal ◽  
Structural Transformation ◽  
Room Temperature ◽  
Co2 Adsorption ◽  
Adsorption Selectivity ◽  
Crystal Transformation ◽  
Co2 Adsorption Selectivity

A multifunctional MOF material showing rare solvent-induced structural transformation with substitution of bridging-water and guest-exchange at 298 K is reported.

Hindered Intramolecular Electron Transfer in Room-Temperature Ionic Liquid†

2010 ◽  
Vol 114 (45) ◽  
pp. 14420-14425 ◽  
Author(s):  
Haixia Wu ◽  
Haixia Wang ◽  
Lin Xue ◽  
Yan Shi ◽  
Xiyou Li
Keyword(s):  
Electron Transfer ◽  
Ionic Liquid ◽  
Room Temperature ◽  
Room Temperature Ionic Liquid ◽  
Intramolecular Electron Transfer

scholarly journals Single-crystal-to-single-crystal transformation of an anion exchangeable dynamic metal–organic framework

CrystEngComm ◽  
2015 ◽  
Vol 17 (46) ◽  
pp. 8796-8800 ◽  
Author(s):  
Biplab Manna ◽  
Aamod V. Desai ◽  
Naveen Kumar ◽  
Avishek Karmakar ◽  
Sujit K. Ghosh
Keyword(s):  
Single Crystal ◽  
Room Temperature ◽  
Dynamic Behaviour ◽  
Metal Organic Framework ◽  
Donor Ligand ◽  
Crystal Transformation ◽  
Metal Organic ◽  
Transformation Experiment ◽  
Organic Framework

A 3D cationic Metal–Organic Framework has been fabricated with a neutral N-donor ligand and Cd(ClO4)2 which shows guest triggered dynamic behaviour at room temperature. This structural dynamism has been demonstrated from the SCSC transformation experiment.

Intramolecular electron transfer in rigid media at room temperature

1992 ◽  
Vol 114 (1) ◽  
pp. 387-388 ◽  
Author(s):  
Wayne E. Jones ◽  
Pingyun Chen ◽  
Thomas J. Meyer
Keyword(s):  
Electron Transfer ◽  
Room Temperature ◽  
Intramolecular Electron Transfer

Double-step CO2 sorption and guest-induced single-crystal-to-single-crystal transformation in a flexible porous framework

2015 ◽  
Vol 44 (22) ◽  
pp. 10141-10145 ◽  
Author(s):  
Wei-Ping Wu ◽  
Zhi-Sen Li ◽  
Bo Liu ◽  
Ping Liu ◽  
Zheng-Ping Xi ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Room Temperature ◽  
Double Step ◽  
Co2 Sorption ◽  
Porous Framework ◽  
Crystal Transformation ◽  
Porous Coordination Polymer

A new 2D highly flexible and breathing porous coordination polymer has been synthesized, which exhibits selective and double-step hysteretic adsorption for CO2, and shows a single-crystal-to-single-crystal transformation induced by CH2Cl2 at room temperature.

Mechanical Properties and Dislocation Structure of Single Crystal Cdte Deformed in Compression at 300°C

1976 ◽  
Vol 34 ◽  
pp. 592-593
Author(s):  
Ernest L. Hall ◽  
J. B. Vander Sande
Keyword(s):  
Mechanical Properties ◽  
Single Crystal ◽  
Dislocation Structure ◽  
Room Temperature ◽  
Elevated Temperatures ◽  
Strain Curve ◽  
Optical Devices ◽  
Semiconductor Compound ◽  
Wide Range ◽  
Sample Orientation

The present paper describes research on the mechanical properties and related dislocation structure of CdTe, a II-VI semiconductor compound with a wide range of uses in electrical and optical devices. At room temperature CdTe exhibits little plasticity and at the same time relatively low strength and hardness. The mechanical behavior of CdTe was examined at elevated temperatures with the goal of understanding plastic flow in this material and eventually improving the room temperature properties. Several samples of single crystal CdTe of identical size and crystallographic orientation were deformed in compression at 300°C to various levels of total strain. A resolved shear stress vs. compressive glide strain curve (Figure la) was derived from the results of the tests and the knowledge of the sample orientation.

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