Three Hydrogen-Bonded Organic Frameworks with Water-Induced Single-Crystal-to-Single-Crystal Transformation and High Proton Conductivity

2020 ◽  
Vol 20 (5) ◽  
pp. 3456-3465 ◽  
Author(s):  
Qianqian Yang ◽  
Yijie Wang ◽  
Yanxue Shang ◽  
Juan Du ◽  
Jianbo Yin ◽  
...  
Keyword(s):  
Single Crystal ◽  
Proton Conductivity ◽  
High Proton Conductivity ◽  
Crystal Transformation ◽  
High Proton ◽  
Hydrogen Bonded

Single-crystal-to-single-crystal transformation and proton conductivity of three hydrogen-bonded organic frameworks

2020 ◽  
Vol 56 (99) ◽  
pp. 15529-15532
Author(s):  
Yijie Wang ◽  
Minghui Zhang ◽  
Qianqian Yang ◽  
Jianbo Yin ◽  
Di Liu ◽  
...  
Keyword(s):  
Single Crystal ◽  
Proton Conductivity ◽  
Water Molecules ◽  
Crystal Transformation ◽  
Hydrogen Bonded

In this communication, we report the SCSC transformation and proton conductivity of three H-bonded organic frameworks. The results show that H-bonded systems can improve their proton conductivity by uptaking water molecules based on the adaptability.

Purely inorganic frameworks based on polyoxometalate clusters with abundant phosphate groups: single-crystal to single-crystal structural transformation and remarkable proton conduction

2020 ◽  
Vol 56 (3) ◽  
pp. 391-394 ◽  
Author(s):  
Shan Zhang ◽  
Ying Lu ◽  
Xiu-Wei Sun ◽  
Zhuo Li ◽  
Tian-Yi Dang ◽  
...  
Keyword(s):  
Single Crystal ◽  
Proton Conductivity ◽  
Structural Transformation ◽  
Proton Conduction ◽  
High Proton Conductivity ◽  
High Proton ◽  
Crystal Structural ◽  
Inorganic Framework ◽  
Phosphate Groups ◽  
New Framework

A pure-inorganic framework 1 underwent a SCSC transformation to form a new framework 1′, which has high proton conductivity.

Proton conduction in a hydrogen-bonded complex of copper(ii)-bipyridine glycoluril nitrate

2017 ◽  
Vol 46 (21) ◽  
pp. 6968-6974 ◽  
Author(s):  
Sakharam B. Tayade ◽  
Vishal M. Dhavale ◽  
Avinash S. Kumbhar ◽  
Sreekumar Kurungot ◽  
Peter Lönnecke ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Proton Conduction ◽  
Secondary Building Unit ◽  
High Proton Conductivity ◽  
Building Unit ◽  
High Proton ◽  
Hydrogen Bonded

Bipyridine glycoluril (BPG) forms a square-pyramidal secondary building unit with copper(ii) which further self-assembles to give a porous hydrogen-bonded complex with high proton conductivity.

High proton conductivity in a nickel(ii) complex and its hybrid membrane

2019 ◽  
Vol 48 (6) ◽  
pp. 2190-2196 ◽  
Author(s):  
Shuai-Liang Yang ◽  
Yue-Ying Yuan ◽  
Fei Ren ◽  
Chen-Xi Zhang ◽  
Qing-Lun Wang
Keyword(s):  
Hydrogen Bond ◽  
Proton Conductivity ◽  
Hybrid Membrane ◽  
Water Molecules ◽  
Hybrid Membranes ◽  
High Proton Conductivity ◽  
High Proton ◽  
Hydrogen Bond Networks

A novel 2D nickel(ii) complex (1) has been successfully synthesized using a 2,2′-bipyridyl, polycarboxylsulfonate ligand H4SBTC and Ni2+ ions. Owing to the presence of abundant water molecules, hydrogen bond networks and other protons, 1 and its hybrid membranes demonstrate high proton conductivity.

Synthesis and characterization of chemically stable sulfonated copoly(triazole imide)s with high proton conductivity

2019 ◽  
Vol 59 (11) ◽  
pp. 2279-2289 ◽  
Author(s):  
Asheesh Singh ◽  
Anaparthi G. Kumar ◽  
Sayantani Saha ◽  
Rajdeep Mukherjee ◽  
Soumendu Bisoi ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Synthesis And Characterization ◽  
High Proton Conductivity ◽  
High Proton

Cations mediating proton conductivity in an oxalate based microporous coordination polymer

2019 ◽  
Vol 43 (1) ◽  
pp. 24-27 ◽  
Author(s):  
Xing Meng ◽  
Hai-Ning Wang ◽  
Xiao-Kun Wang ◽  
Long-Zhang Dong ◽  
Yan-Hong Zou
Keyword(s):  
Structural Change ◽  
Relative Humidity ◽  
Coordination Polymer ◽  
Proton Conductivity ◽  
Cation Substitution ◽  
High Proton Conductivity ◽  
High Proton

Through cation substitution in a zirconium based coordination polymer, an isostructural framework 1@NH4+ has been prepared without any apparent structural change. The proton conductivity of 1@NH4+ is successfully improved. It exhibits high proton conductivity (1.39 × 10−2 S cm−1) at 98% relative humidity and 60 °C.

Metal–organic frameworks derived from a semi-rigid anthracene-based ligand and sulfonates: proton conductivity and dye degradation studies

CrystEngComm ◽  
2021 ◽  
Author(s):  
Aurobinda Mohanty ◽  
Udai P. Singh ◽  
Arijit Ghorai ◽  
Susanta Banerjee ◽  
R. J. Butcher
Keyword(s):  
Methylene Blue ◽  
Relative Humidity ◽  
Proton Conductivity ◽  
Dye Degradation ◽  
Metal Organic Frameworks ◽  
High Proton Conductivity ◽  
Methylene Blue Degradation ◽  
High Proton ◽  
Metal Organic ◽  
Degradation Studies

The MOFs were constructed by ligand AHP and sulfonate analogues. MOF4 exhibits a high proton conductivity of 1.95 × 10−3 S cm−1 at 95 °C and 98% relative humidity. MOFs 1–5 also serve as photocatalysts for methylene blue degradation.

Simple and universal synthesis of sulfonated porous organic polymers with high proton conductivity

2020 ◽  
Vol 4 (8) ◽  
pp. 2339-2345 ◽  
Author(s):  
Zhongping Li ◽  
Yuze Yao ◽  
Dongjin Wang ◽  
Md. Mahmudul Hasan ◽  
Athchaya Suwansoontorn ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Organic Polymers ◽  
High Proton Conductivity ◽  
Porous Organic Polymers ◽  
Conductive Materials ◽  
High Proton

By using a simple and universal process, we successfully synthesized various sulfonated porous organic polymers with high proton conductivity, and therefore this strategy could evolve structural designs for high proton-conductive materials.

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