scholarly journals Iridium(iii) complexes of 1,2,4-triazines as potential bioorthogonal reagents: metal coordination facilitates luminogenic reaction with strained cyclooctynes

2019 ◽  
Vol 55 (95) ◽  
pp. 14283-14286 ◽  
Author(s):  
Valery N. Kozhevnikov ◽  
Michael E. Deary ◽  
Theodora Mantso ◽  
Mihalis I. Panayiotidis ◽  
Mark T. Sims
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Metal Coordination ◽  
Inverse Electron Demand ◽  
Diels Alder Reaction ◽  
Electron Demand

Unprecedented Ir(iii) complexes of 5-(2-pyridyl)-1,2,4-triazine are described. The metal coordination drastically increases the speed of the Inverse Electron Demand Diels Alder reaction with strained bicyclooctyne BCN.

Monochromophoric iridium(iii) pyridyl–tetrazine complexes as a unique design strategy for bioorthogonal probes with luminogenic behavior

2017 ◽  
Vol 53 (23) ◽  
pp. 3299-3302 ◽  
Author(s):  
Tommy Siu-Ming Tang ◽  
Hua-Wei Liu ◽  
Kenneth Kam-Wing Lo
Keyword(s):  
Reaction Kinetics ◽  
Design Strategy ◽  
Alder Reaction ◽  
Diels Alder ◽  
Metal Coordination ◽  
Coordination Property ◽  
Inverse Electron Demand ◽  
Diels Alder Reaction ◽  
Electron Demand

This is the first reported use of the metal-coordination property of tetrazine in the construction of luminogenic bioorthogonal probes and modulation of the inverse electron-demand Diels–Alder reaction kinetics.

Single wall carbon nanotube (SWCNT)–gold nanorod (AuNR) conjugates via thermally-mild reaction conditions

2017 ◽  
Vol 41 (21) ◽  
pp. 12392-12396 ◽  
Author(s):  
Siting Ni ◽  
Jun Zhu ◽  
Mohamed Amine Mezour ◽  
R. Bruce Lennox
Keyword(s):  
Carbon Nanotube ◽  
Covalent Binding ◽  
Alder Reaction ◽  
Diels Alder ◽  
Gold Nanorod ◽  
Reaction Conditions ◽  
Single Wall Carbon ◽  
Inverse Electron Demand ◽  
Diels Alder Reaction ◽  
Electron Demand

A thermally-mild method for covalent binding of SWCNTs to AuNRs, based on an inverse-electron-demand Diels–Alder reaction, is established and discussed.

Total syntheses of ericifolione and analogues via a biomimetic inverse-electron-demand Diels-Alder reaction

2021 ◽  
Author(s):  
Tingting Zhou ◽  
Anquan Zheng ◽  
Luqiong Huo ◽  
Changgeng Li ◽  
Haibo Tan ◽  
...  
Keyword(s):  
Sodium Acetate ◽  
Alder Reaction ◽  
Diels Alder ◽  
Total Syntheses ◽  
Inverse Electron Demand ◽  
Diels Alder Reaction ◽  
Sterically Hindered ◽  
Electron Demand

Driven by bioinspiration and appreciation of the structure of ericifolione, a biomimetic tautomerization/intermolecular inverse-electron-demand hetero Diels-Alder reaction cascade sequence promoted by sodium acetate to rapidly construct sterically hindered dihydropyran scaffolds...

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