Monochromophoric iridium(iii) pyridyl–tetrazine complexes as a unique design strategy for bioorthogonal probes with luminogenic behavior

2017 ◽  
Vol 53 (23) ◽  
pp. 3299-3302 ◽  
Author(s):  
Tommy Siu-Ming Tang ◽  
Hua-Wei Liu ◽  
Kenneth Kam-Wing Lo
Keyword(s):  
Reaction Kinetics ◽  
Design Strategy ◽  
Alder Reaction ◽  
Diels Alder ◽  
Metal Coordination ◽  
Coordination Property ◽  
Inverse Electron Demand ◽  
Diels Alder Reaction ◽  
Electron Demand

This is the first reported use of the metal-coordination property of tetrazine in the construction of luminogenic bioorthogonal probes and modulation of the inverse electron-demand Diels–Alder reaction kinetics.

scholarly journals Iridium(iii) complexes of 1,2,4-triazines as potential bioorthogonal reagents: metal coordination facilitates luminogenic reaction with strained cyclooctynes

2019 ◽  
Vol 55 (95) ◽  
pp. 14283-14286 ◽  
Author(s):  
Valery N. Kozhevnikov ◽  
Michael E. Deary ◽  
Theodora Mantso ◽  
Mihalis I. Panayiotidis ◽  
Mark T. Sims
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Metal Coordination ◽  
Inverse Electron Demand ◽  
Diels Alder Reaction ◽  
Electron Demand

Unprecedented Ir(iii) complexes of 5-(2-pyridyl)-1,2,4-triazine are described. The metal coordination drastically increases the speed of the Inverse Electron Demand Diels Alder reaction with strained bicyclooctyne BCN.

Single wall carbon nanotube (SWCNT)–gold nanorod (AuNR) conjugates via thermally-mild reaction conditions

2017 ◽  
Vol 41 (21) ◽  
pp. 12392-12396 ◽  
Author(s):  
Siting Ni ◽  
Jun Zhu ◽  
Mohamed Amine Mezour ◽  
R. Bruce Lennox
Keyword(s):  
Carbon Nanotube ◽  
Covalent Binding ◽  
Alder Reaction ◽  
Diels Alder ◽  
Gold Nanorod ◽  
Reaction Conditions ◽  
Single Wall Carbon ◽  
Inverse Electron Demand ◽  
Diels Alder Reaction ◽  
Electron Demand

A thermally-mild method for covalent binding of SWCNTs to AuNRs, based on an inverse-electron-demand Diels–Alder reaction, is established and discussed.

Total syntheses of ericifolione and analogues via a biomimetic inverse-electron-demand Diels-Alder reaction

2021 ◽  
Author(s):  
Tingting Zhou ◽  
Anquan Zheng ◽  
Luqiong Huo ◽  
Changgeng Li ◽  
Haibo Tan ◽  
...  
Keyword(s):  
Sodium Acetate ◽  
Alder Reaction ◽  
Diels Alder ◽  
Total Syntheses ◽  
Inverse Electron Demand ◽  
Diels Alder Reaction ◽  
Sterically Hindered ◽  
Electron Demand

Driven by bioinspiration and appreciation of the structure of ericifolione, a biomimetic tautomerization/intermolecular inverse-electron-demand hetero Diels-Alder reaction cascade sequence promoted by sodium acetate to rapidly construct sterically hindered dihydropyran scaffolds...

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