Thermal and light-induced spin transition in a nanometric film of a new high-vacuum processable spin crossover complex

2018 ◽  
Vol 6 (33) ◽  
pp. 8885-8889 ◽  
Author(s):  
Matteo Atzori ◽  
Lorenzo Poggini ◽  
Lorenzo Squillantini ◽  
Brunetto Cortigiani ◽  
Mathieu Gonidec ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Ultrathin Films ◽  
Spin Crossover ◽  
Spin Transition ◽  
High Vacuum ◽  
Nanometric Film

Herein, we report the identification of a novel high-vacuum processable spin-crossover complex which can be efficiently used to prepare continuous ultrathin films with retention of switchable magnetic properties.

Abrupt spin crossover in iron(iii) complexes with aromatic anions

2019 ◽  
Vol 48 (41) ◽  
pp. 15515-15520 ◽  
Author(s):  
Sharon E. Lazaro ◽  
Adil Alkaş ◽  
Seok J. Lee ◽  
Shane G. Telfer ◽  
Keith S. Murray ◽  
...  
Keyword(s):  
Transition Temperature ◽  
Spin Crossover ◽  
Spin Transition ◽  
Halogen Bonds ◽  
Aromatic Anions

Two iron(iii) complexes, [Fe(qsal-X)2]OTs·nH2O, are found to exhibit abrupt spin crossover with the spin transition temperature substituent dependent, and X⋯O halogen bonds linking the spin centres.

Single crystal to single crystal transformation of spin-crossover coordination polymers from 3D frameworks to 2D layers

2021 ◽  
Vol 9 (15) ◽  
pp. 5082-5087
Author(s):  
Yu Gong ◽  
Wang-Kang Han ◽  
Hui-Shu Lu ◽  
Qing-Tao Hu ◽  
Huan Tu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Ligand Exchange ◽  
Spin Crossover ◽  
Metal Organic Frameworks ◽  
Crystal Transformation ◽  
Metal Organic

New Hofmann-type metal–organic frameworks display rare and complete ligand exchange induced single crystal to single crystal transformations from 3D frameworks to 2D layers, accompanied by magnetic properties transition from two-step SCO behavior to hysteretic SCO behavior.

scholarly journals Spin‐Crossover Molecules on Surfaces: From Isolated Molecules to Ultrathin Films

2021 ◽  
pp. 2008141
Author(s):  
Lalminthang Kipgen ◽  
Matthias Bernien ◽  
Felix Tuczek ◽  
Wolfgang Kuch
Keyword(s):  
Ultrathin Films ◽  
Spin Crossover ◽  
Isolated Molecules

scholarly journals Electrical read-out of light-induced spin transition in thin film spin crossover/graphene heterostructures

2021 ◽  
Author(s):  
Nikita Konstantinov ◽  
Arthur Tauzin ◽  
Ulrich Nguetchuissi Noumbé ◽  
Diana Dragoe ◽  
Bohdan Kundys ◽  
...  
Keyword(s):  
Thin Film ◽  
Spin Crossover ◽  
Spin Transition ◽  
Switching Device ◽  
Electronic Switching ◽  
Spin Transitions

An opto-electronic switching device made from an evaporated spin crossover thin film over a graphene sensor is presented. The electrical transduction of both temperature and light-induced reversible spin transitions are demonstrated.

Spin-crossover in a trans-[FeL2(NCS)2] family (L = triaryltriazole): remote substituent effects on spin transition modes and temperature

2013 ◽  
Vol 42 (28) ◽  
pp. 10144 ◽  
Author(s):  
Guo-Ping Shen ◽  
Li Qi ◽  
Lei Wang ◽  
Yan Xu ◽  
Jing-Jing Jiang ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Spin Transition ◽  
Substituent Effects ◽  
Transition Modes ◽  
Remote Substituent

Influence of the interface on the magnetic properties of ferromagnetic ultrathin films with various adjacent copper thicknesses

2014 ◽  
Vol 115 (17) ◽  
pp. 17C108 ◽  
Author(s):  
Dong Zhang ◽  
Sheng Jiang ◽  
Chen Luo ◽  
Yukun Wang ◽  
Wenbin Rui ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Ultrathin Films

scholarly journals Thermal and near-infrared light induced spin crossover in a mononuclear iron(ii) complex with a tetrathiafulvalene-fused dipyridophenazine ligand

2016 ◽  
Vol 45 (28) ◽  
pp. 11267-11271 ◽  
Author(s):  
F. Pointillart ◽  
X. Liu ◽  
M. Kepenekian ◽  
B. Le Guennic ◽  
S. Golhen ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Near Infrared ◽  
Spin Transition ◽  
Infrared Light ◽  
Near Infrared Light ◽  
Mononuclear Iron

A thermal and photo-induced spin transition in a tetrathiafulvalene-based Fe(ii) complex.

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