Spin Crossover Complex Film, [FeII(H-trz)3]-Nafion, with a Spin Transition around Room Temperature

2003 ◽  
Vol 32 (5) ◽  
pp. 476-476
Keyword(s):  
Room Temperature ◽  
Spin Crossover ◽  
Spin Transition ◽  
Complex Film

Spin Crossover Complex Film, [FeII(H-trz)3]-Nafion, with a Spin Transition around Room Temperature

2003 ◽  
Vol 32 (4) ◽  
pp. 336-337 ◽  
Author(s):  
Akio Nakamoto ◽  
Yuuki Ono ◽  
Norimichi Kojima ◽  
Daiju Matsumura ◽  
Toshihiko Yokoyama
Keyword(s):  
Room Temperature ◽  
Spin Crossover ◽  
Spin Transition ◽  
Complex Film

One Shot Laser Pulse Induced Reversible Spin Transition in the Spin-Crossover Complex [Fe(C4H4N2){Pt(CN)4}] at Room Temperature

2005 ◽  
Vol 117 (26) ◽  
pp. 4137-4141 ◽  
Author(s):  
Sébastien Bonhommeau ◽  
Gábor Molnár ◽  
Ana Galet ◽  
Antoine Zwick ◽  
José-Antonio Real ◽  
...  
Keyword(s):  
Laser Pulse ◽  
Room Temperature ◽  
Spin Crossover ◽  
Spin Transition

Demonstration of the thermally induced high spin–low spin transition for a transparent spin crossover complex film [Fe(II)(H-trz)3]-Nafion (trz=triazole)

Polyhedron ◽  
2005 ◽  
Vol 24 (16-17) ◽  
pp. 2909-2912 ◽  
Author(s):  
Akio Nakamoto ◽  
Norimichi Kojima ◽  
Liu XiaoJun ◽  
Yutaka Moritomo ◽  
Arao Nakamura
Keyword(s):  
High Spin ◽  
Spin Crossover ◽  
Spin Transition ◽  
Thermally Induced ◽  
Complex Film

Towards direct correlations between spin-crossover and structural features in iron(II) complexes

2003 ◽  
Vol 59 (4) ◽  
pp. 479-486 ◽  
Author(s):  
Mathieu Marchivie ◽  
Philippe Guionneau ◽  
Jean-François Létard ◽  
Daniel Chasseau
Keyword(s):  
Crystal Structures ◽  
Room Temperature ◽  
Spin Crossover ◽  
Spin Transition ◽  
Intermolecular Hydrogen Bond ◽  
Structural Features ◽  
Gradual Transition ◽  
Hydrogen Bond Interaction ◽  
First Approximation ◽  
Two Phases

The [Fe(PM-BiA)2(NCS)2] complex, where PM is N-2-pyridylmethylene and BiA is 4-aminobiphenyl, crystallizes in two polymorphs. The two phases, denoted (I) and (II), undergo a spin-crossover when the sample is cooled and present distinct spin-transition features as (I) shows a very abrupt spin transition, while (II) exhibits a gradual transition. The two forms of the complex are used to investigate the correlations that exist between the spin-transition features and structural features. This article presents the crystal structures of polymorph (II) at room temperature (high spin) and at 120 K (low spin), including a comparison with those of polymorph (I). This study reveals that the packing, in a first approximation, is similar in both forms. In order to look at the crystal structures in more detail, a new angular parameter, denoted θNCS, as well as a particular type of intermolecular hydrogen-bond interaction, which involves the S atoms of the NCS ligands, are investigated. Interestingly, this angle and this intermolecular interaction can be directly connected to the cooperativity of the spin transition. Such a result is extended to all the SCO iron(II) complexes belonging to the same family of the general formula [Fe(PM-L)2(NCS)2].

Spin transition and its photo-induced effect in spin crossover complex film based on [Fe(II)(trz)3]

2003 ◽  
Vol 137 (1-3) ◽  
pp. 1219-1220 ◽  
Author(s):  
A. Nakamoto ◽  
Y. Ono ◽  
N. Kojima ◽  
D. Matsumura ◽  
T. Yokoyama ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Spin Transition ◽  
Complex Film

Titelbild: One Shot Laser Pulse Induced Reversible Spin Transition in the Spin-Crossover Complex [Fe(C4H4N2){Pt(CN)4}] at Room Temperature (Angew. Chem. 26/2005)

2005 ◽  
Vol 117 (26) ◽  
pp. 4011-4011 ◽  
Author(s):  
Sébastien Bonhommeau ◽  
Gábor Molnár ◽  
Ana Galet ◽  
Antoine Zwick ◽  
José-Antonio Real ◽  
...  
Keyword(s):  
Laser Pulse ◽  
Room Temperature ◽  
Spin Crossover ◽  
Spin Transition

One Shot Laser Pulse Induced Reversible Spin Transition in the Spin-Crossover Complex [Fe(C4H4N2){Pt(CN)4}] at Room Temperature

2005 ◽  
Vol 44 (26) ◽  
pp. 4069-4073 ◽  
Author(s):  
Sébastien Bonhommeau ◽  
Gábor Molnár ◽  
Ana Galet ◽  
Antoine Zwick ◽  
José-Antonio Real ◽  
...  
Keyword(s):  
Laser Pulse ◽  
Room Temperature ◽  
Spin Crossover ◽  
Spin Transition

scholarly journals Five 2,6-Di(pyrazol-1-yl)pyridine-4-carboxylate Esters, and the Spin States of their Iron(II) Complexes

2019 ◽  
Vol 5 (1) ◽  
pp. 9 ◽  
Author(s):  
Iurii Galadzhun ◽  
Rafal Kulmaczewski ◽  
and Malcolm A. Halcrow
Keyword(s):  
Room Temperature ◽  
Spin Crossover ◽  
Thermal Hysteresis ◽  
Spin Transition ◽  
Benzyl Ester ◽  
The Other ◽  
Spin States ◽  
Phenyl Ester ◽  
Coupling Reagent ◽  
Complex Salts

Two phenyl ester and three benzyl ester derivatives have been synthesized from 2,6-di(pyrazol-1-yl)pyridine-4-carboxylic acid and the appropriate phenyl or benzyl alcohol using N,N’-dicyclohexylcarbodiimide as the coupling reagent. Complexation of the ligands with Fe[BF4]2·6H2O in acetone yielded the corresponding [FeL2][BF4]2 complex salts. Four of the new ligands and four of the complexes have been crystallographically characterised. Particularly noteworthy are two polymorphs of [Fe(L3)2][BF4]2·2MeNO2 (L3 = 3,4-dimethoxyphenyl 2,6-di{pyrazol-1-yl}pyridine-4-carboxylate), one of which is crystallographically characterised as high-spin while the other exhibits the onset of spin-crossover above room temperature. The other complexes are similarly low-spin at low temperature but exhibit gradual spin-crossover on heating, except for an acetone solvate of [Fe(L5)2][BF4]2 (L5 = benzyl 2,6-di{pyrazol-1-yl}pyridine-4-carboxylate), which exhibits a more abrupt spin-transition at T½ = 273 K with 9 K thermal hysteresis.

Two New Iron(II) Spin-Crossover Complexes with N4O2Coordination Sphere and Spin Transition around Room Temperature

2009 ◽  
Vol 2009 (36) ◽  
pp. 5527-5534 ◽  
Author(s):  
Birgit Weber ◽  
Jaroslava Obel ◽  
Dunie Henner-Vásquez ◽  
Wolfgang Bauer
Keyword(s):  
Room Temperature ◽  
Spin Crossover ◽  
Spin Transition ◽  
Spin Crossover Complexes
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