3D flower-like hierarchical NiCo2O4architecture on carbon cloth fibers as an anode catalyst for high-performance, durable direct urea fuel cells

2018 ◽  
Vol 6 (45) ◽  
pp. 23019-23027 ◽  
Author(s):  
M. Ranjani ◽  
N. Senthilkumar ◽  
G. Gnana kumar ◽  
Arumugam Manthiram

A 3D NiCo2O4hierarchical architecture composed of interlaced and self-stacked 2D nanoflakes is realized as a urea oxidation reaction catalyst for the generation of green energy in direct urea fuel cells.

2021 ◽  
Vol 9 (12) ◽  
pp. 7726-7735
Author(s):  
Da Liu ◽  
Weicheng Huang ◽  
Qinghuan Chang ◽  
Lu Zhang ◽  
Ruiwen Wang ◽  
...  

TiN nanoarrays, in situ grown on carbon cloth gather 97.2% of the model exoelectrogen Geobacter, greatly enhancing the MFCs' performance. The experimental results and DFT calculation certify the importance of the micro–nano-hierarchical structure.


2021 ◽  
Vol 57 (80) ◽  
pp. 10415-10418
Author(s):  
Mengrui Zhang ◽  
Jianping Zhu ◽  
Bin Liu ◽  
Yongkang Hou ◽  
Chao Zhang ◽  
...  

Ultrafine Co6W6C nanoparticles were successfully synthesized, and this ternary carbide exhibit high catalytic activities for hydrazine oxidation reaction in a practical oxygen–hydrazine fuel cell.


2014 ◽  
Vol 175 (5) ◽  
pp. 2637-2646 ◽  
Author(s):  
Li-Zhen Zeng ◽  
Shao-Fei Zhao ◽  
Wei-Shan Li

2007 ◽  
Vol 154 (1) ◽  
pp. B53 ◽  
Author(s):  
Pilwon Heo ◽  
Masahiro Nagao ◽  
Mitsuru Sano ◽  
Takashi Hibino

2017 ◽  
Vol 5 (7) ◽  
pp. 3208-3213 ◽  
Author(s):  
Danni Liu ◽  
Tingting Liu ◽  
Lixue Zhang ◽  
Fengli Qu ◽  
Gu Du ◽  
...  

Ni2P nanoflake arrays on carbon cloth act as an efficient and durable catalyst electrode for the urea oxidation reaction (UOR) and hydrogen evolution reaction (HER). Its two-electrode alkaline electrolyzer needs 1.35 V for 50 mA cm−2, which is 0.58 V less than that required for pure water splitting.


2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Yanrong Xue ◽  
Lin Shi ◽  
Xuerui Liu ◽  
Jinjie Fang ◽  
Xingdong Wang ◽  
...  

Abstract The development of cost-effective hydroxide exchange membrane fuel cells is limited by the lack of high-performance and low-cost anode hydrogen oxidation reaction catalysts. Here we report a Pt-free catalyst Ru7Ni3/C, which exhibits excellent hydrogen oxidation reaction activity in both rotating disk electrode and membrane electrode assembly measurements. The hydrogen oxidation reaction mass activity and specific activity of Ru7Ni3/C, as measured in rotating disk experiments, is about 21 and 25 times that of Pt/C, and 3 and 5 times that of PtRu/C, respectively. The hydroxide exchange membrane fuel cell with Ru7Ni3/C anode can deliver a high peak power density of 2.03 W cm−2 in H2/O2 and 1.23 W cm−2 in H2/air (CO2-free) at 95 °C, surpassing that using PtRu/C anode catalyst, and good durability with less than 5% voltage loss over 100 h of operation. The weakened hydrogen binding of Ru by alloying with Ni and enhanced water adsorption by the presence of surface Ni oxides lead to the high hydrogen oxidation reaction activity of Ru7Ni3/C. By using the Ru7Ni3/C catalyst, the anode cost can be reduced by 85% of the current state-of-the-art PtRu/C, making it highly promising in economical hydroxide exchange membrane fuel cells.


Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 1006
Author(s):  
Tse-Wei Chen ◽  
Rasu Ramachandran ◽  
Shen-Ming Chen ◽  
Ganesan Anushya ◽  
Selvarajan Divya Rani ◽  
...  

Perovskite-based electrode catalysts are the most promising potential candidate that could bring about remarkable scientific advances in widespread renewable energy-storage devices, especially supercapacitors, batteries, fuel cells, solid oxide fuel cells, and solar-cell applications. This review demonstrated that perovskite composites are used as advanced electrode materials for efficient energy-storage-device development with different working principles and various available electrochemical technologies. Research efforts on increasing energy-storage efficiency, a wide range of electro-active constituents, and a longer lifetime of the various perovskite materials are discussed in this review. Furthermore, this review describes the prospects, widespread available materials, properties, synthesis strategies, uses of perovskite-supported materials, and our views on future perspectives of high-performance, next-generation sustainable-energy technology.


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