scholarly journals Precise control of pore hydrophilicity enabled by post-synthetic cation exchange in metal–organic frameworks

2018 ◽  
Vol 9 (15) ◽  
pp. 3856-3859 ◽  
Author(s):  
Ashley M. Wright ◽  
Adam J. Rieth ◽  
Sungwoo Yang ◽  
Evelyn N. Wang ◽  
Mircea Dincă
Keyword(s):  
Relative Humidity ◽  
Cation Exchange ◽  
Water Uptake ◽  
Metal Organic Frameworks ◽  
Precise Control ◽  
Metal Organic

The ability to control the relative humidity at which water uptake occurs in a given adsorbent is advantageous, making that material applicable to a variety of different applications.

Improving porosity and water uptake of aluminum metal-organic frameworks (Al-MOFs) as graphite oxide (GO) composites

2021 ◽  
pp. 111352
Author(s):  
Ülkü Kökçam-Demir ◽  
Niels Tannert ◽  
Marco Bengsch ◽  
Alex Spieß ◽  
Carsten Schlüsener ◽  
...  
Keyword(s):  
Water Uptake ◽  
Graphite Oxide ◽  
Metal Organic Frameworks ◽  
Aluminum Metal ◽  
Metal Organic

Metal–organic frameworks derived from a semi-rigid anthracene-based ligand and sulfonates: proton conductivity and dye degradation studies

CrystEngComm ◽  
2021 ◽  
Author(s):  
Aurobinda Mohanty ◽  
Udai P. Singh ◽  
Arijit Ghorai ◽  
Susanta Banerjee ◽  
R. J. Butcher
Keyword(s):  
Methylene Blue ◽  
Relative Humidity ◽  
Proton Conductivity ◽  
Dye Degradation ◽  
Metal Organic Frameworks ◽  
High Proton Conductivity ◽  
Methylene Blue Degradation ◽  
High Proton ◽  
Metal Organic ◽  
Degradation Studies

The MOFs were constructed by ligand AHP and sulfonate analogues. MOF4 exhibits a high proton conductivity of 1.95 × 10−3 S cm−1 at 95 °C and 98% relative humidity. MOFs 1–5 also serve as photocatalysts for methylene blue degradation.

scholarly journals Record-Setting Sorbents for Reversible Water Uptake by Systematic Anion Exchanges in Metal–Organic Frameworks

2019 ◽  
Vol 141 (35) ◽  
pp. 13858-13866 ◽  
Author(s):  
Adam J. Rieth ◽  
Ashley M. Wright ◽  
Grigorii Skorupskii ◽  
Jenna L. Mancuso ◽  
Christopher H. Hendon ◽  
...  
Keyword(s):  
Water Uptake ◽  
Metal Organic Frameworks ◽  
Metal Organic

Postsynthetic Ligand and Cation Exchange in Robust Metal–Organic Frameworks

2012 ◽  
Vol 134 (43) ◽  
pp. 18082-18088 ◽  
Author(s):  
Min Kim ◽  
John F. Cahill ◽  
Honghan Fei ◽  
Kimberley A. Prather ◽  
Seth M. Cohen
Keyword(s):  
Cation Exchange ◽  
Metal Organic Frameworks ◽  
Metal Organic

Trimetallic conductive metal–organic frameworks as precatalysts for the oxygen evolution reaction with enhanced activity

2020 ◽  
Vol 4 (9) ◽  
pp. 4589-4597
Author(s):  
Xiaofei Shi ◽  
Rui Hua ◽  
Yulong Xu ◽  
Tong Liu ◽  
Guang Lu
Keyword(s):  
Cation Exchange ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Solvothermal Synthesis ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Enhanced Activity ◽  
Metal Organic ◽  
Organic Framework

A strategy based on solvothermal synthesis and cation-exchange was developed to prepare the trimetallic FeCo0.6Ni0.4-CAT metal–organic framework (MOF) as the precatalyst for oxygen evolution reaction.

Pore with Gate: Enhancement of the Isosteric Heat of Adsorption of Dihydrogen via Postsynthetic Cation Exchange in Metal−Organic Frameworks

2011 ◽  
Vol 50 (19) ◽  
pp. 9374-9384 ◽  
Author(s):  
Sihai Yang ◽  
Gregory S. B. Martin ◽  
Jeremy J. Titman ◽  
Alexander J. Blake ◽  
David R. Allan ◽  
...  
Keyword(s):  
Cation Exchange ◽  
Metal Organic Frameworks ◽  
Isosteric Heat ◽  
Heat Of Adsorption ◽  
Isosteric Heat Of Adsorption ◽  
Metal Organic

Heterogenization of Homogeneous Catalysts in Metal–Organic Frameworks via Cation Exchange

2013 ◽  
Vol 135 (29) ◽  
pp. 10586-10589 ◽  
Author(s):  
Douglas T. Genna ◽  
Antek G. Wong-Foy ◽  
Adam J. Matzger ◽  
Melanie S. Sanford
Keyword(s):  
Cation Exchange ◽  
Metal Organic Frameworks ◽  
Homogeneous Catalysts ◽  
Metal Organic

scholarly journals Precise Control of Molecular Self‐Diffusion in Isoreticular and Multivariate Metal‐Organic Frameworks

ChemPhysChem ◽  
2019 ◽  
Vol 21 (1) ◽  
pp. 32-35 ◽  
Author(s):  
Thomas M. Osborn Popp ◽  
Ariel Z. Plantz ◽  
Omar M. Yaghi ◽  
Jeffrey A. Reimer
Keyword(s):  
Metal Organic Frameworks ◽  
Precise Control ◽  
Self Diffusion ◽  
Metal Organic
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