Metal–organic frameworks derived from a semi-rigid anthracene-based ligand and sulfonates: proton conductivity and dye degradation studies

CrystEngComm ◽  
2021 ◽  
Author(s):  
Aurobinda Mohanty ◽  
Udai P. Singh ◽  
Arijit Ghorai ◽  
Susanta Banerjee ◽  
R. J. Butcher
Keyword(s):  
Methylene Blue ◽  
Relative Humidity ◽  
Proton Conductivity ◽  
Dye Degradation ◽  
Metal Organic Frameworks ◽  
High Proton Conductivity ◽  
Methylene Blue Degradation ◽  
High Proton ◽  
Metal Organic ◽  
Degradation Studies

The MOFs were constructed by ligand AHP and sulfonate analogues. MOF4 exhibits a high proton conductivity of 1.95 × 10−3 S cm−1 at 95 °C and 98% relative humidity. MOFs 1–5 also serve as photocatalysts for methylene blue degradation.

scholarly journals High proton conductivity in cyanide-bridged metal–organic frameworks: understanding the role of water

2015 ◽  
Vol 3 (44) ◽  
pp. 22347-22352 ◽  
Author(s):  
Yuan Gao ◽  
Richard Broersen ◽  
Wouter Hageman ◽  
Ning Yan ◽  
Marjo C. Mittelmeijer-Hazeleger ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Metal Organic Frameworks ◽  
Water Molecules ◽  
High Proton Conductivity ◽  
Lattice Water ◽  
High Proton ◽  
Metal Organic

Hop hop hop: the proton conductivity of the [Nd(mpca)2Nd(H2O)6Mo(CN)8]·nH2O is enabled by lattice water molecules in its channels.

Ba-MOFs with tetrazole-based acetic acids: unusual configuration, novel topology and high proton conductivity

2021 ◽  
Author(s):  
Jie Yang ◽  
Shunlin Zhang ◽  
Zhe Feng ◽  
Ying Cao ◽  
Dunru Zhu
Keyword(s):  
Proton Conductivity ◽  
Proton Exchange Membrane ◽  
Metal Organic Frameworks ◽  
Proton Exchange ◽  
High Proton Conductivity ◽  
Conductive Materials ◽  
High Proton ◽  
Metal Organic ◽  
Exchange Membrane ◽  
Acetic Acids

Metal-organic frameworks (MOFs) as proton conductive materials have attracted increasing attention due to their applications in proton-exchange membrane fuel cells. While the majority of the MOFs are based on transition...

High proton conductivity at low relative humidity in an anionic Fe-based metal–organic framework

2016 ◽  
Vol 4 (10) ◽  
pp. 3638-3641 ◽  
Author(s):  
Thach N. Tu ◽  
Nghi Q. Phan ◽  
Thanh T. Vu ◽  
Ha L. Nguyen ◽  
Kyle E. Cordova ◽  
...  
Keyword(s):  
Relative Humidity ◽  
Proton Conductivity ◽  
Metal Organic Framework ◽  
Operating Conditions ◽  
High Proton Conductivity ◽  
High Proton ◽  
Metal Organic ◽  
Organic Framework

High proton conductivity (2.90 × 10−2 S cm−1) in an anionic Fe-based metal–organic framework was reached under more practical operating conditions (95 °C and 60% RH).

Enhancing proton conductivity in Zr-MOFs through tuning metal cluster connectivity

2022 ◽  
Author(s):  
Guang-Rui Si ◽  
Fan Yang ◽  
Tao He ◽  
Xiang-Jing Kong ◽  
Wei Wu ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Sulfonic Acid ◽  
Metal Cluster ◽  
Metal Organic Frameworks ◽  
High Proton Conductivity ◽  
High Proton ◽  
Metal Organic

We design and synthesize two stable Zr(IV)-based metal-organic frameworks with high proton conductivity, namely BUT-76 and BUT-77, which are constructed with the same sulfonic acid containing ligand and 8/12 connected...

Cations mediating proton conductivity in an oxalate based microporous coordination polymer

2019 ◽  
Vol 43 (1) ◽  
pp. 24-27 ◽  
Author(s):  
Xing Meng ◽  
Hai-Ning Wang ◽  
Xiao-Kun Wang ◽  
Long-Zhang Dong ◽  
Yan-Hong Zou
Keyword(s):  
Structural Change ◽  
Relative Humidity ◽  
Coordination Polymer ◽  
Proton Conductivity ◽  
Cation Substitution ◽  
High Proton Conductivity ◽  
High Proton

Through cation substitution in a zirconium based coordination polymer, an isostructural framework 1@NH4+ has been prepared without any apparent structural change. The proton conductivity of 1@NH4+ is successfully improved. It exhibits high proton conductivity (1.39 × 10−2 S cm−1) at 98% relative humidity and 60 °C.

Ground to conduct: mechanochemical synthesis of a metal–organic framework with high proton conductivity

2015 ◽  
Vol 51 (36) ◽  
pp. 7637-7640 ◽  
Author(s):  
Dariusz Matoga ◽  
Marcin Oszajca ◽  
Marcin Molenda
Keyword(s):  
Proton Conductivity ◽  
Mechanochemical Synthesis ◽  
Metal Organic Framework ◽  
Environmentally Friendly ◽  
High Proton Conductivity ◽  
Proton Conducting ◽  
High Proton ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

A high proton-conducting metal–organic framework (PCMOF) is prepared for the first time by economical and environmentally-friendly mechanochemistry.

High Proton Conductivity and Spectroscopic Investigations of Metal–Organic Framework Materials Impregnated by Strong Acids

2014 ◽  
Vol 6 (7) ◽  
pp. 5161-5167 ◽  
Author(s):  
Danil N. Dybtsev ◽  
Valentina G. Ponomareva ◽  
Sokhrab B. Aliev ◽  
Alexei P. Chupakhin ◽  
Marsel R. Gallyamov ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Metal Organic Framework ◽  
High Proton Conductivity ◽  
Framework Materials ◽  
Spectroscopic Investigations ◽  
High Proton ◽  
Metal Organic ◽  
Strong Acids ◽  
Organic Framework
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