Heterogenization of Homogeneous Catalysts in Metal–Organic Frameworks via Cation Exchange

2013 ◽  
Vol 135 (29) ◽  
pp. 10586-10589 ◽  
Author(s):  
Douglas T. Genna ◽  
Antek G. Wong-Foy ◽  
Adam J. Matzger ◽  
Melanie S. Sanford
Keyword(s):  
Cation Exchange ◽  
Metal Organic Frameworks ◽  
Homogeneous Catalysts ◽  
Metal Organic

Postsynthetic Ligand and Cation Exchange in Robust Metal–Organic Frameworks

2012 ◽  
Vol 134 (43) ◽  
pp. 18082-18088 ◽  
Author(s):  
Min Kim ◽  
John F. Cahill ◽  
Honghan Fei ◽  
Kimberley A. Prather ◽  
Seth M. Cohen
Keyword(s):  
Cation Exchange ◽  
Metal Organic Frameworks ◽  
Metal Organic

Trimetallic conductive metal–organic frameworks as precatalysts for the oxygen evolution reaction with enhanced activity

2020 ◽  
Vol 4 (9) ◽  
pp. 4589-4597
Author(s):  
Xiaofei Shi ◽  
Rui Hua ◽  
Yulong Xu ◽  
Tong Liu ◽  
Guang Lu
Keyword(s):  
Cation Exchange ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Solvothermal Synthesis ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Enhanced Activity ◽  
Metal Organic ◽  
Organic Framework

A strategy based on solvothermal synthesis and cation-exchange was developed to prepare the trimetallic FeCo0.6Ni0.4-CAT metal–organic framework (MOF) as the precatalyst for oxygen evolution reaction.

Pore with Gate: Enhancement of the Isosteric Heat of Adsorption of Dihydrogen via Postsynthetic Cation Exchange in Metal−Organic Frameworks

2011 ◽  
Vol 50 (19) ◽  
pp. 9374-9384 ◽  
Author(s):  
Sihai Yang ◽  
Gregory S. B. Martin ◽  
Jeremy J. Titman ◽  
Alexander J. Blake ◽  
David R. Allan ◽  
...  
Keyword(s):  
Cation Exchange ◽  
Metal Organic Frameworks ◽  
Isosteric Heat ◽  
Heat Of Adsorption ◽  
Isosteric Heat Of Adsorption ◽  
Metal Organic

scholarly journals Correction: Fluorescent metal ion chemosensors via cation exchange reactions of complexes, quantum dots, and metal–organic frameworks

The Analyst ◽  
2015 ◽  
Vol 140 (22) ◽  
pp. 7827-7827 ◽  
Author(s):  
Jinghui Cheng ◽  
Xiangge Zhou ◽  
Haifeng Xiang
Keyword(s):  
Quantum Dots ◽  
Cation Exchange ◽  
Metal Ion ◽  
Metal Organic Frameworks ◽  
Exchange Reactions ◽  
Metal Organic

Correction for ‘Fluorescent metal ion chemosensors via cation exchange reactions of complexes, quantum dots, and metal–organic frameworks’ by Jinghui Cheng, et al., Analyst, 2015, DOI: 10.1039/c5an01398d.

scholarly journals Directing both the Morphology and Packing of Chiral Metal-Organic Frameworks by Cation Exchange Mediated by Nanochannels

2021 ◽  
Author(s):  
Hadar Nasi ◽  
Maria Chiara di Gregorio ◽  
Qiang Wen ◽  
Linda J. W. Shimon ◽  
Ifat Kaplan-Ashiri ◽  
...  
Keyword(s):  
Cation Exchange ◽  
Metal Organic Frameworks ◽  
Rare Metal ◽  
Metal Salts ◽  
Direct Reaction ◽  
Bulk Properties ◽  
X Ray ◽  
Pyridyl Ligands ◽  
Exchange Processes ◽  
Metal Organic

Crystals are among the most challenging materials to design, both at the molecular and macroscopic levels. We show here that metal-organic frameworks, based on tetrahedral pyridyl ligands, can be used as a morpho-logical and structural mold to form a series of other isostructural crystals having different metal ions. The cati-on exchange is versatile, based on the use of diverse first-row metals; it occurs with retention of the morpholo-gy. Different morphologies were obtained by a direct reaction between the ligand and metal salts. An iterative crystal-to-crystal conversion has also been demonstrated by two consecutive cation exchange processes. The primary manganese-based crystals have a complex connectivity characterized by a rare space group (P622). The molecular structure generates two types of homochiral channels that span longitudinally the entire hex-agonal prism. These channels mediate the cation exchange, as indicated by energy-dispersive X-ray spectros-copy combined with scanning electron microscopy measurements on microtome-sectioned crystals. The occur-rence of the observed cation exchange is in excellent agreement with the Irving-Williams series (Mn < Fe < Co < Ni < Cu > Zn) that are associated with the relative stability of the resulting coordination nodes. The overall approach allows for the predictability of the structural properties of rare metal-organic frameworks based on tetrahedral pyridyl ligands at different hierarchies: from elemental composition, molecular packing, and mor-phology to the bulk properties.

scholarly journals Precise control of pore hydrophilicity enabled by post-synthetic cation exchange in metal–organic frameworks

2018 ◽  
Vol 9 (15) ◽  
pp. 3856-3859 ◽  
Author(s):  
Ashley M. Wright ◽  
Adam J. Rieth ◽  
Sungwoo Yang ◽  
Evelyn N. Wang ◽  
Mircea Dincă
Keyword(s):  
Relative Humidity ◽  
Cation Exchange ◽  
Water Uptake ◽  
Metal Organic Frameworks ◽  
Precise Control ◽  
Metal Organic

The ability to control the relative humidity at which water uptake occurs in a given adsorbent is advantageous, making that material applicable to a variety of different applications.

scholarly journals Cation exchange at the secondary building units of metal–organic frameworks

2014 ◽  
Vol 43 (16) ◽  
pp. 5456-5467 ◽  
Author(s):  
C. K. Brozek ◽  
M. Dincă
Keyword(s):  
Cation Exchange ◽  
Metal Organic Frameworks ◽  
Secondary Building Units ◽  
Metal Organic

This review examines the governing factors of cation exchange at the secondary building units of MOFs and reviews its applications.

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