scholarly journals The mechanistic investigations of photochemical decarbonylations and oxidative addition reactions for M(CO)5 (M = Fe, Ru, Os) complexes

RSC Advances ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 2626-2640
Author(s):  
Zheng-Feng Zhang ◽  
Ming-Der Su
Keyword(s):  
Oxidative Addition ◽  
Addition Reactions ◽  
Model Study ◽  
Mechanistic Investigations

Model study of the photoactivation reactions for Si–H bonds in trimethylsilane for group 8 M(CO)5 (M = Fe, Ru, and Os) complexes using the CASSCF and MP2-CAS levels of theory.

Mechanistic investigations of CO-photoextrusion and oxidative addition reactions of early transition-metal carbonyls: (η5-C5H5)M(CO)4(M = V, Nb, Ta)

2016 ◽  
Vol 18 (24) ◽  
pp. 16396-16403 ◽  
Author(s):  
Shih-Hao Su ◽  
Ming-Der Su
Keyword(s):  
Transition Metal ◽  
Oxidative Addition ◽  
Addition Reactions ◽  
Metal Carbonyls ◽  
Early Transition Metal ◽  
Model Study ◽  
Transition Metal Carbonyls ◽  
Mechanistic Investigations ◽  
Group 5 ◽  
Early Transition

A model study of the photoactivation reactions of Si–H bonds in trimethylsilane by group 5 (η5-C5H5)M(CO)4(M = V, Nb and Ta;Rea-S0-M) complexes is undertaken using the M06-2X/Def2-SVPD level of theory.

scholarly journals The mechanistic investigations of photochemical carbonyl elimination and oxidative addition reactions of (η5-C5H5)M(CO)3, (M = Mn and Re) complexes

RSC Advances ◽  
2018 ◽  
Vol 8 (20) ◽  
pp. 10987-10998 ◽  
Author(s):  
Zheng-Feng Zhang ◽  
Ming-Der Su
Keyword(s):  
Singlet State ◽  
Oxidative Addition ◽  
Addition Product ◽  
Conical Intersection ◽  
Addition Reactions ◽  
Intersystem Crossing ◽  
Mechanistic Investigations

The theoretical works suggest that under UV photoirradiation, η5-CpMn(CO)3 follows either the conical intersection mechanism or the intersystem crossing mechanism to obtain the final oxidative addition product. However, η5-CpRe(CO)3 proceeds only the singlet state channel.

Oxidative addition reactions of an iridium(I) complex containing phosphine-NHC

Polyhedron ◽  
2021 ◽  
Vol 198 ◽  
pp. 115083
Author(s):  
Aziza Ahmida ◽  
Fatin M. Elmagbari ◽  
Hans Egold ◽  
Gerald Henkel
Keyword(s):  
Oxidative Addition ◽  
Addition Reactions

Reactions of the Ni(0) Compound Ni(PPh3)4 with Unactivated Alkyl Halides: Oxidative Addition Reactions Involving Radical Processes and Nickel(I) Intermediates

2018 ◽  
Vol 37 (15) ◽  
pp. 2450-2467 ◽  
Author(s):  
Ryley Kehoe ◽  
Markshun Mahadevan ◽  
Adeela Manzoor ◽  
Gillian McMurray ◽  
Patrick Wienefeld ◽  
...  
Keyword(s):  
Oxidative Addition ◽  
Alkyl Halides ◽  
Addition Reactions ◽  
Radical Processes

SRN1 and oxidative addition reactions of nitroimidazole anions

1986 ◽  
Vol 27 (17) ◽  
pp. 1943-1946 ◽  
Author(s):  
Adelaide T.O.M. Adebayo ◽  
W.Russell Bowman ◽  
W.G. Salt
Keyword(s):  
Oxidative Addition ◽  
Addition Reactions
Sign in / Sign up

Export Citation Format

Share Document