scholarly journals The mechanistic investigations of photochemical carbonyl elimination and oxidative addition reactions of (η5-C5H5)M(CO)3, (M = Mn and Re) complexes

RSC Advances ◽  
2018 ◽  
Vol 8 (20) ◽  
pp. 10987-10998 ◽  
Author(s):  
Zheng-Feng Zhang ◽  
Ming-Der Su
Keyword(s):  
Singlet State ◽  
Oxidative Addition ◽  
Addition Product ◽  
Conical Intersection ◽  
Addition Reactions ◽  
Intersystem Crossing ◽  
Mechanistic Investigations

The theoretical works suggest that under UV photoirradiation, η5-CpMn(CO)3 follows either the conical intersection mechanism or the intersystem crossing mechanism to obtain the final oxidative addition product. However, η5-CpRe(CO)3 proceeds only the singlet state channel.

Mechanistic investigations of CO-photoextrusion and oxidative addition reactions of early transition-metal carbonyls: (η5-C5H5)M(CO)4(M = V, Nb, Ta)

2016 ◽  
Vol 18 (24) ◽  
pp. 16396-16403 ◽  
Author(s):  
Shih-Hao Su ◽  
Ming-Der Su
Keyword(s):  
Transition Metal ◽  
Oxidative Addition ◽  
Addition Reactions ◽  
Metal Carbonyls ◽  
Early Transition Metal ◽  
Model Study ◽  
Transition Metal Carbonyls ◽  
Mechanistic Investigations ◽  
Group 5 ◽  
Early Transition

A model study of the photoactivation reactions of Si–H bonds in trimethylsilane by group 5 (η5-C5H5)M(CO)4(M = V, Nb and Ta;Rea-S0-M) complexes is undertaken using the M06-2X/Def2-SVPD level of theory.

scholarly journals The mechanistic investigations of photochemical decarbonylations and oxidative addition reactions for M(CO)5 (M = Fe, Ru, Os) complexes

RSC Advances ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 2626-2640
Author(s):  
Zheng-Feng Zhang ◽  
Ming-Der Su
Keyword(s):  
Oxidative Addition ◽  
Addition Reactions ◽  
Model Study ◽  
Mechanistic Investigations

Model study of the photoactivation reactions for Si–H bonds in trimethylsilane for group 8 M(CO)5 (M = Fe, Ru, and Os) complexes using the CASSCF and MP2-CAS levels of theory.

Ionic dimerisation of trifluoropropenenitrile and its addition reactions with methyl trifluoropropenoate

1980 ◽  
Vol 45 (2) ◽  
pp. 406-414 ◽  
Author(s):  
Jiří Svoboda ◽  
Oldřich Paleta ◽  
Václav Dědek
Keyword(s):  
Reaction Mechanism ◽  
Proton Transfer ◽  
Substituent Effect ◽  
Solvent Molecule ◽  
Addition Product ◽  
Potassium Fluoride ◽  
Relative Reactivity ◽  
Addition Reactions ◽  
Tertiary Amines ◽  
Optimum Conditions

Dimerisation of trifluoropropenenitrile (I) in the presence of potassium fluoride and tertiary amines afforded a mixture of stereoisomeric perfluoro-4-methyl-pentenedinitriles (II), higher-boiling compounds, and 2,3,3,3-tetrafluoropropanenitrile (III) which arises by proton transfer from the solvent molecule. Under optimum conditions, product II was obtained in about 50% yield. Reaction of the nitrile I with methyl trifluoropropenoate (IV) gave, besides the dimers II and V, the product of addition of the nitrile I to the propenoate, IV, i.e. methyl 4-cyanoperfluoro-2-pentenoate (VI), and the addition product of the propenoate IV to the nitrile I, i.e. methyl 4-cyanoperfluoro-2-methyl-3-butenoate (VII). The relative reactivity if I and IV is discussed. The ratio of stereoisomers in II, V, VI and VII indicates that the magnitude of the steric substituent effect, operating in the reaction mechanism, decreases in the order -CFCF3.(COOCH3) > -CFCF3(CN) > -COOCH3 > -CN.

Oxidative addition reactions of an iridium(I) complex containing phosphine-NHC

Polyhedron ◽  
2021 ◽  
Vol 198 ◽  
pp. 115083
Author(s):  
Aziza Ahmida ◽  
Fatin M. Elmagbari ◽  
Hans Egold ◽  
Gerald Henkel
Keyword(s):  
Oxidative Addition ◽  
Addition Reactions

Reactions of the Ni(0) Compound Ni(PPh3)4 with Unactivated Alkyl Halides: Oxidative Addition Reactions Involving Radical Processes and Nickel(I) Intermediates

2018 ◽  
Vol 37 (15) ◽  
pp. 2450-2467 ◽  
Author(s):  
Ryley Kehoe ◽  
Markshun Mahadevan ◽  
Adeela Manzoor ◽  
Gillian McMurray ◽  
Patrick Wienefeld ◽  
...  
Keyword(s):  
Oxidative Addition ◽  
Alkyl Halides ◽  
Addition Reactions ◽  
Radical Processes
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