scholarly journals Ecofriendly synthesis and characterization of carboxylated GAP copolymers

RSC Advances ◽  
2018 ◽  
Vol 8 (36) ◽  
pp. 20032-20038 ◽  
Author(s):  
Hancheul Kim ◽  
Yoorim Jang ◽  
Sitae Noh ◽  
Jongoh Jeong ◽  
Donghyun Kim ◽  
...  
Keyword(s):  
Sodium Azide ◽  
Substitution Reaction ◽  
Synthesis And Characterization ◽  
Sodium Carboxylate ◽  
Simultaneous Substitution

Carboxylated GAP copolymers (polyGA-carboxylate) compounds (1–7), were synthesized by the simultaneous substitution reaction with PECH, sodium azide, and sodium carboxylate in DMSO.

scholarly journals Bi(NO3)3 · 5H2O mediated synthesis of 4,4′-diaminotriarylmethane leuco malachite compounds under solvent-free conditions

2009 ◽  
Vol 7 (1) ◽  
pp. 138-142 ◽  
Author(s):  
Ghasem Bardajee ◽  
Farnaz Jafarpour
Keyword(s):  
Functional Groups ◽  
Substitution Reaction ◽  
Solvent Free ◽  
Synthesis And Characterization ◽  
Electrophilic Aromatic Substitution ◽  
Aromatic Substitution ◽  
Aryl Aldehydes ◽  
Solvent Free Conditions

AbstractIn this report, we described the synthesis and characterization of a variety of diaminotriarylmethane derivatives with dimethylamino functional groups. These compounds were synthesized by the tandem regio-selective electrophilic aromatic substitution reaction of N,N-dimethylaniline with aryl aldehydes to form the corresponding diaminotriarylmethane compounds. In our strategy, Bi(NO3)3 was used as a catalyst under solvent free conditions to afford the desired products in good to excellent yields.

Reaction ofm-Terphenyldichlorophosphanes with Sodium Azide:  Synthesis and Characterization of Stable Azidocyclophosphazenes

2001 ◽  
Vol 40 (12) ◽  
pp. 2756-2762 ◽  
Author(s):  
Rudolf J. Wehmschulte ◽  
Masood A. Khan ◽  
Shawn I. Hossain
Keyword(s):  
Sodium Azide ◽  
Synthesis And Characterization

scholarly journals Synthesis and Characterization of New Thioxanthone Derivatives

2013 ◽  
Vol 10 (3) ◽  
pp. 724-735
Author(s):  
Baghdad Science Journal
Keyword(s):  
Sulfuric Acid ◽  
Benzoic Acid ◽  
Sodium Azide ◽  
Aromatic Amines ◽  
Chlorosulfonic Acid ◽  
Starting Material ◽  
Phosphorus Compounds ◽  
Synthesis And Characterization

This work comprises the synthesis of new thioxanthone derivatives containing C-substituted thioxanthone. To obtain these derivatives, the o-mercapto benzoic acid was chosen as the starting material, which was reacted with dry benzene in sulfuric acid (98 %) to produce the thioxanthone (1). The 2,7-(disulfonyl phosphine imine) thioxanthone (4-8) were prepared from reaction of compound (1) with chlorosulfonic acid gave 2,7-(disulfonyl chloride) thioxanthone (2). Treatment of (2) with sodium azide to produce 2,7-(disulfonyl azide) thioxanthone (3). Condensation of (3) with phosphorus compounds afforded compounds (4-8). The 2,7-(disulfonamide) thioxanthone (9-21) was obtained when compound (2) condensed with different aromatic amines, it gave the expected amides (9-21).

scholarly journals Synthesis and Characterization of Some New Monemer and Polymers Containing Hetero Cyclic Rings With Study of Their Physical Properties.

2016 ◽  
Vol 13 (2) ◽  
pp. 172-180
Author(s):  
Baghdad Science Journal
Keyword(s):  
Acetic Acid ◽  
Schiff Base ◽  
Maleic Anhydride ◽  
Phthalic Anhydride ◽  
Sodium Azide ◽  
Heterocyclic Compounds ◽  
Synthesis And Characterization ◽  
X Ray ◽  
Ft Ir

Number of new polyester and polyamide are prepared as derivatives from 5,5`-(1,4-phenylene)-bis-(1,3,4-thiadiazole-2-amine) [C1], three series of heterocyclic compounds were synthesized.The first series includes the Schiff base [C2] prepared from the reaction between compound [C1] with p-hydroxy benzaldehyde in presence of acetic acid and absolute ethanol , then these derivatives have reaction with maleic anhydride , phthalic anhydride and sodium azide, respectively to obtain the compounds [C3-5] contaning (oxazepine and tetrazole) rings.The third series of compounds [C1-5] has transformed to their polymers [C6-15] by reaction with adipoyl chloride and glutroyl chloride , respectively. The reaction was followed by T.L.C and identified by FT-IR , 1H-NMR ,C.H.N analysis , softening point , viscosity, TGA , DSC and X-ray.

The synthesis and characterization of azido and cyanato dithiocarbamato nitrosyl complexes of molybdenum : Reduction of coordinated azide in Azidobis(N,N-diethyldithiocarbamato)(dimethyl sulphoxide)nitrosylmolybdenum

1976 ◽  
Vol 29 (2) ◽  
pp. 275 ◽  
Author(s):  
JA Broomhead ◽  
JR Budge ◽  
WD Grumley ◽  
TR Norman ◽  
M Sterns
Keyword(s):  
Nitrogen Atom ◽  
Sodium Azide ◽  
Strong Acid ◽  
Dimethyl Sulphoxide ◽  
Synthesis And Characterization ◽  
Nitrosyl Complexes

The new complexes [MoL(S2CNR2)2(Me2SO)NO] (R = Et, L = NCO- or N3-; R = Me, L = NCO-) and (R'4N) [MO(NCO)2(S2CNR2)2NO] (R = R' = Et; R = Me, R' = Me or Et) have been isolated following the reactions of cis MO(S2CNR~)2(NO)2] with sodium azide and potassium cyanate. Use of 15N-labelled azide has confirmed that molybdenum bonded to a single nitrogen atom must be involved in the reduction of this ligand to ammonia and dinitrogen in strong acid.

scholarly journals Synthesis of New bis 1-Substituted 1H-Tetrazoles via Efficient Heterocyclizations from Symmetric Dianilines, Methyl Orthoester, and Sodium Azide

Proceedings ◽  
2019 ◽  
Vol 41 (1) ◽  
pp. 26
Author(s):  
Julio C. Flores-Reyes ◽  
Roberto E. Blanco-Carapia ◽  
Alfredo López-Olvera ◽  
Perla Islas-Jácome ◽  
Yizrell Medina-Martínez ◽  
...  
Keyword(s):  
Relative Humidity ◽  
Sodium Azide ◽  
Primary Amine ◽  
Single Step ◽  
Primary Amines ◽  
Synthesis And Characterization ◽  
Synthetic Strategy ◽  
Group Reduction ◽  
Nitro Group Reduction

The synthesis and characterization of three new bis 1-substituted 1H-tetrazoles are described. Two products were synthesized in a single step via a direct heterocyclization of primary amines, methyl orthoester (trymethyl orthoformate), and sodium azide in 30% and 91% yields, respectively. Besides, another one was prepared via a three-step synthetic strategy: SNAr (32%), nitro-group reduction (66%), and primary amine heterocyclization (83%), yielding 18%, overall. The aim behind the synthesis of new tetrazole-containing products is to construct novel MOF-like structures to evaluate their gas capture properties (CO2, CO, and SO2) under relative humidity conditions.

scholarly journals Synthesis and characterization of carboxylated PBAMO copolymers as promising prepolymers for energetic binders

RSC Advances ◽  
2020 ◽  
Vol 10 (15) ◽  
pp. 8967-8972
Author(s):  
Minkyung Lim ◽  
Meilan Bu ◽  
Yoorim Jang ◽  
Jongoh Jeong ◽  
Sitae Noh ◽  
...  
Keyword(s):  
Sodium Azide ◽  
Synthesis And Characterization

The carboxylated poly[3,3-bis(3-azidomethyl)oxetane] (PBAMO) copolymers (poly(BAMO-carboxylate)) were synthesized by substitution of poly[3,3-bis(3-chloromethyl)oxetane] (PBCMO) with potassium carboxylate and sodium azide in DMSO.

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