High-performance piezoelectric nanogenerators based on chemically-reinforced composites

2018 ◽  
Vol 11 (6) ◽  
pp. 1425-1430 ◽  
Author(s):  
Eun Jung Lee ◽  
Tae Yun Kim ◽  
Sang-Woo Kim ◽  
Sunho Jeong ◽  
Youngmin Choi ◽  
...  

A high-performance piezoelectric nanocomposite generator (PNG) based on chemically reinforced composites is demonstrated by incorporating amine-functionalized lead zirconate titanate (PZT-NH2) nanoparticles into a polymer matrix.

2016 ◽  
Vol 6 (1) ◽  
Author(s):  
Iñigo Bretos ◽  
Ricardo Jiménez ◽  
Monika Tomczyk ◽  
Enrique Rodríguez-Castellón ◽  
Paula M. Vilarinho ◽  
...  

2012 ◽  
Vol 33 (10) ◽  
pp. 1483-1485 ◽  
Author(s):  
Sarah S. Bedair ◽  
Jeffrey S. Pulskamp ◽  
Christopher D. Meyer ◽  
Manrico Mirabelli ◽  
Ronald G. Polcawich ◽  
...  

2021 ◽  
Author(s):  
SNEHAMOYEE HAZRA ◽  
Subhamita Sengupta ◽  
Soumyaranjan Ratha ◽  
Ankita Ghatak ◽  
Arup Kumar Raychaudhuri ◽  
...  

Abstract The high internal resistance of the perovskite materials used in Nanogenerators (NGs) lowers the power generation. It severely restricts their application for mechanical energy harvesting from the ambient source. In this work, we demonstrate a flexible Piezoelectric NG (PENG) with an improved device structure. Hydrothermally grown one-dimensional Lead Zirconate Titanate (Pb(ZrTi)O3) of different morphologies are used as the generating material. The morphology of the PZT nanostructures, engineered from nanoparticles to needle-shaped nanowires to increase the surface to volume ratio, provides effective mechanical contact with the electrode. The reduction of the internal resistance of the PENG has been achieved by two ways: i) fabrication of interdigitated electrodes (IDE) to increase the interfacial polarization and ii) lowering of Schottky barrier height (SBH) at the junction of the PZT nanostructure and the metal electrode by varying the electrode materials of different work functions. We find that lowering of the SBH at the interface contributes to an increased piezo voltage generation. The flexible nano needles-based PENG can deliver output voltage 9.5 V and power density 615 μW/cm2 on application low mechanical pressure (~1 kPa) by tapping motion. The internal resistance of the device is ~0.65 MΩ. It can charge a 35 μF super-capacitor up to 5 V within 20 s. This study provides a systematic pathway to solve the bottlenecks in the piezoelectric nanogenerators due to the high internal resistance.


2015 ◽  
Vol 35 (1-4) ◽  
pp. 53-58 ◽  
Author(s):  
Dong-Hyung Kang ◽  
Kwang Lok Kim ◽  
Dong Gyu Yang ◽  
Young Hun Jeong ◽  
Chang-Il Kim ◽  
...  

2016 ◽  
Vol 6 (1) ◽  
Author(s):  
Iñigo Bretos ◽  
Ricardo Jiménez ◽  
Monika Tomczyk ◽  
Enrique Rodríguez-Castellón ◽  
Paula M. Vilarinho ◽  
...  

Abstract Applications of ferroelectric materials in modern microelectronics will be greatly encouraged if the thermal incompatibility between inorganic ferroelectrics and semiconductor devices is overcome. Here, solution-processable layers of the most commercial ferroelectric compound ─ morphotrophic phase boundary lead zirconate titanate, namely Pb(Zr0.52Ti0.48)O3 (PZT) ─ are grown on silicon substrates at temperatures well below the standard CMOS process of semiconductor technology. The method, potentially transferable to a broader range of Zr:Ti ratios, is based on the addition of crystalline nanoseeds to photosensitive solutions of PZT resulting in perovskite crystallization from only 350 °C after the enhanced decomposition of metal precursors in the films by UV irradiation. A remanent polarization of 10.0 μC cm−2 is obtained for these films that is in the order of the switching charge densities demanded for FeRAM devices. Also, a dielectric constant of ~90 is measured at zero voltage which exceeds that of current single-oxide candidates for capacitance applications. The multifunctionality of the films is additionally demonstrated by their pyroelectric and piezoelectric performance. The potential integration of PZT layers at such low fabrication temperatures may redefine the concept design of classical microelectronic devices, besides allowing inorganic ferroelectrics to enter the scene of the emerging large-area, flexible electronics.


2014 ◽  
Vol 895 ◽  
pp. 204-210 ◽  
Author(s):  
Swee Leong Kok ◽  
Kok Tee Lau ◽  
Qumrul Ahsan

Lead Zirconate Titanate or PZT is a high performance piezoelectric material which is able to generate charges when a proportional amount of stress is applied on the material. It has the potential to be used to fabricate micro-power generator for powering low power electronic devices, on top of already existence sensors and actuators. One of the indicators for comparing the performance of the smart materials is the piezoelectric charge coefficient, d33. In this paper, the actual d33 of PZT fabricated in the form of substrate-free thick-films were measured using Berlincourt Method whereby a standard dynamic force is applied to the materials and the resultant value of charges is recorded and compared over a period of time after the thick-films were polarized. The d33 values are compared between substrate-based and substrate-free specimens show a difference of about 45 % as a result of clamping effect contributed by d31. The experiment results also show that the thick-film PZT processed at 950 °C and polarized at 220 V with a thickness of about 120 μm has a piezoelectric charge coefficient of 82 pC/N.


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