Alkene-alkyl interconversion: an experimental and computational study of the olefin insertion and β-hydride elimination processes

S. Azpeitia; U. Prieto; E. San Sebastián; A. Rodríguez-Diéguez; M. A. Garralda; M. A. Huertos

doi:10.1039/c8dt00448j

Alkene-alkyl interconversion: an experimental and computational study of the olefin insertion and β-hydride elimination processes

Dalton Transactions ◽

10.1039/c8dt00448j ◽

2018 ◽

Vol 47 (19) ◽

pp. 6808-6818 ◽

Cited By ~ 3

Author(s):

S. Azpeitia ◽

U. Prieto ◽

E. San Sebastián ◽

A. Rodríguez-Diéguez ◽

M. A. Garralda ◽

...

Keyword(s):

Computational Study ◽

Alkyl Complexes ◽

Hydride Elimination

Six new silyl-thioether rhodium and iridium compounds have been used to study the transformation of alkene- into alkyl-complexes and vice versa.

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The synthesis, characterization and properties of alkyl complexes of the type [CpFe(CO)2R] (Cp=η5-C5(CH3)5; R=n-C3H7 to n-C12H25); the X-ray crystal and molecular structure of [Cp*Fe(CO)2(n-C5H11)] and molecular orbital and density functional calculations on the β-hydride elimination of [CpFe(CO)2(CH2CH3)]

Journal of Organometallic Chemistry ◽

10.1016/s0022-328x(99)00260-0 ◽

1999 ◽

Vol 587 (1) ◽

pp. 28-37 ◽

Cited By ~ 16

Author(s):

R.Oliver Hill ◽

Charles F. Marais ◽

John R. Moss ◽

Kevin J. Naidoo

Keyword(s):

Molecular Structure ◽

Molecular Orbital ◽

Density Functional Calculations ◽

Density Functional ◽

Crystal And Molecular Structure ◽

X Ray ◽

Alkyl Complexes ◽

Hydride Elimination

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β-Hydride Elimination/Abstraction from Metal–Alkyl Complexes

Category 1, Organometallics ◽

10.1055/sos-sd-002-00312 ◽

2003 ◽

pp. 1

Author(s):

K. H. Theopold ◽

A. Mommertz ◽

B. A. Salisbury

Keyword(s):

Alkyl Complexes ◽

Hydride Elimination

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Competitive uncatalyzed geometrical isomerization and .beta.-hydride elimination of alkyl complexes of platinum(II)

Inorganic Chemistry ◽

10.1021/ic00301a038 ◽

1989 ◽

Vol 28 (2) ◽

pp. 342-347 ◽

Cited By ~ 7

Author(s):

Giuseppe Alibrandi ◽

Matteo Cusumano ◽

Domenico Minniti ◽

Luigi Monsu Scolaro ◽

Raffaello Romeo

Keyword(s):

Geometrical Isomerization ◽

Alkyl Complexes ◽

Beta Hydride Elimination ◽

Hydride Elimination

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Cationic Hafnium Alkyl Complexes that Are Stable toward β-Hydride Elimination below 10 °C and Active as Initiators for the Living Polymerization of 1-Hexene

Journal of the American Chemical Society ◽

10.1021/ja0114198 ◽

2001 ◽

Vol 123 (43) ◽

pp. 10746-10747 ◽

Cited By ~ 40

Author(s):

Parisa Mehrkhodavandi ◽

Richard R. Schrock

Keyword(s):

Living Polymerization ◽

Alkyl Complexes ◽

Hydride Elimination

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Thermally stable coordinatively unsaturated alkyl complexes resistant to β-hydride elimination: TpiPrM–CH2CH3 (M = Co, Fe)

Chemical Communications ◽

10.1039/a809441a ◽

1999 ◽

pp. 417-418 ◽

Cited By ~ 35

Author(s):

Nobuhiko Shirasawa ◽

Munetaka Akita ◽

Shiro Hikichi ◽

Yoshihiko Moro-oka

Keyword(s):

Thermally Stable ◽

Alkyl Complexes ◽

Hydride Elimination

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Trends within a triad: comparison between σ-alkyl complexes of nickel, palladium and platinum with respect to association of ethylene, migratory insertion and β-hydride elimination. A theoretical study §

Journal of the Chemical Society Dalton Transactions ◽

10.1039/a704584k ◽

1997 ◽

pp. 4147-4152 ◽

Cited By ~ 47

Author(s):

Staffan Strömberg ◽

Krister Zetterberg ◽

Per E. M. Siegbahn

Keyword(s):

Theoretical Study ◽

Alkyl Complexes ◽

Migratory Insertion ◽

Hydride Elimination

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ChemInform Abstract: Competitive Uncatalyzed Geometrical Isomerization and β-Hydride Elimination of Alkyl Complexes of Platinum(II).

ChemInform ◽

10.1002/chin.198920280 ◽

1989 ◽

Vol 20 (20) ◽

Author(s):

G. ALIBRANDI ◽

M. CUSUMANO ◽

D. MINNITI ◽

L. MONSU SCOLARO ◽

R. ROMEO

Keyword(s):

Geometrical Isomerization ◽

Alkyl Complexes ◽

Hydride Elimination

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Computational Analysis of Two-State Reactivity in β-Hydride Elimination Mechanisms of Fe(II)– and Co(II)–Alkyl Complexes Supported by β-Diketiminate Ligand

Organometallics ◽

10.1021/acs.organomet.9b00418 ◽

2019 ◽

Vol 38 (19) ◽

pp. 3582-3589 ◽

Cited By ~ 3

Author(s):

Toshiyuki Takayanagi ◽

Kohei Saito ◽

Haruya Suzuki ◽

Yuya Watabe ◽

Takashi Fujihara

Keyword(s):

Computational Analysis ◽

Alkyl Complexes ◽

Hydride Elimination

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Palladium(II)-Catalyzed Cycloisomerization of Substituted 1,5-Hexadienes: A Combined Experimental and Computational Study on an Open and an Interrupted Hydropalladation/Carbopalladation/β-Hydride Elimination (HCHe) Catalytic Cycle

The Journal of Organic Chemistry ◽

10.1021/jo3004088 ◽

2012 ◽

Vol 77 (11) ◽

pp. 4980-4995 ◽

Cited By ~ 6

Author(s):

Björn Nelson ◽

Sonja Herres-Pawlis ◽

Wolf Hiller ◽

Hans Preut ◽

Carsten Strohmann ◽

...

Keyword(s):

Computational Study ◽

Catalytic Cycle ◽

Hydride Elimination

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Spin Crossover during β-Hydride Elimination in High-Spin Iron(II)– and Cobalt(II)–Alkyl Complexes

Organometallics ◽

10.1021/om400325x ◽

2013 ◽

Vol 32 (17) ◽

pp. 4741-4751 ◽

Cited By ~ 43

Author(s):

Sarina M. Bellows ◽

Thomas R. Cundari ◽

Patrick L. Holland

Keyword(s):

High Spin ◽

Spin Crossover ◽

Alkyl Complexes ◽

Hydride Elimination ◽

High Spin Iron

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