Thermally stable coordinatively unsaturated alkyl complexes resistant to β-hydride elimination: TpiPrM–CH2CH3 (M = Co, Fe)

1999 ◽  
pp. 417-418 ◽  
Author(s):  
Nobuhiko Shirasawa ◽  
Munetaka Akita ◽  
Shiro Hikichi ◽  
Yoshihiko Moro-oka
Keyword(s):  
Thermally Stable ◽  
Alkyl Complexes ◽  
Hydride Elimination

β-Hydride Elimination/Abstraction from Metal–Alkyl Complexes

2003 ◽  
pp. 1
Author(s):  
K. H. Theopold ◽  
A. Mommertz ◽  
B. A. Salisbury
Keyword(s):  
Alkyl Complexes ◽  
Hydride Elimination

Competitive uncatalyzed geometrical isomerization and .beta.-hydride elimination of alkyl complexes of platinum(II)

1989 ◽  
Vol 28 (2) ◽  
pp. 342-347 ◽  
Author(s):  
Giuseppe Alibrandi ◽  
Matteo Cusumano ◽  
Domenico Minniti ◽  
Luigi Monsu Scolaro ◽  
Raffaello Romeo
Keyword(s):  
Geometrical Isomerization ◽  
Alkyl Complexes ◽  
Beta Hydride Elimination ◽  
Hydride Elimination

ChemInform Abstract: Competitive Uncatalyzed Geometrical Isomerization and β-Hydride Elimination of Alkyl Complexes of Platinum(II).

ChemInform ◽  
1989 ◽  
Vol 20 (20) ◽  
Author(s):  
G. ALIBRANDI ◽  
M. CUSUMANO ◽  
D. MINNITI ◽  
L. MONSU SCOLARO ◽  
R. ROMEO
Keyword(s):  
Geometrical Isomerization ◽  
Alkyl Complexes ◽  
Hydride Elimination

Alkene-alkyl interconversion: an experimental and computational study of the olefin insertion and β-hydride elimination processes

2018 ◽  
Vol 47 (19) ◽  
pp. 6808-6818 ◽  
Author(s):  
S. Azpeitia ◽  
U. Prieto ◽  
E. San Sebastián ◽  
A. Rodríguez-Diéguez ◽  
M. A. Garralda ◽  
...  
Keyword(s):  
Computational Study ◽  
Alkyl Complexes ◽  
Hydride Elimination

Six new silyl-thioether rhodium and iridium compounds have been used to study the transformation of alkene- into alkyl-complexes and vice versa.

Computational Analysis of Two-State Reactivity in β-Hydride Elimination Mechanisms of Fe(II)– and Co(II)–Alkyl Complexes Supported by β-Diketiminate Ligand

2019 ◽  
Vol 38 (19) ◽  
pp. 3582-3589 ◽  
Author(s):  
Toshiyuki Takayanagi ◽  
Kohei Saito ◽  
Haruya Suzuki ◽  
Yuya Watabe ◽  
Takashi Fujihara
Keyword(s):  
Computational Analysis ◽  
Alkyl Complexes ◽  
Hydride Elimination

Spin Crossover during β-Hydride Elimination in High-Spin Iron(II)– and Cobalt(II)–Alkyl Complexes

2013 ◽  
Vol 32 (17) ◽  
pp. 4741-4751 ◽  
Author(s):  
Sarina M. Bellows ◽  
Thomas R. Cundari ◽  
Patrick L. Holland
Keyword(s):  
High Spin ◽  
Spin Crossover ◽  
Alkyl Complexes ◽  
Hydride Elimination ◽  
High Spin Iron

Investigation of the V4+-Centre in 6H- and 4H-SIC by the Method of Spectral-Hole Burning

1998 ◽  
Vol 512 ◽  
Author(s):  
C. Hecht ◽  
R. Kummer ◽  
A. Winnacker
Keyword(s):  
Electronic Properties ◽  
Room Temperature ◽  
Hole Burning ◽  
Band Offset ◽  
Spectral Hole Burning ◽  
Type Ii ◽  
Thermally Stable ◽  
Spectral Hole

ABSTRACTIn the context of spectral-hole burning experiments in 4H- and 6H-SiC doped with vanadium the energy positions of the V4+/5+ level in both polytypes were determined in order to resolve discrepancies in literature. From these numbers the band offset of 6H/4H-SiC is calculated by using the Langer-Heinrich rule, and found to be of staggered type II. Furthermore the experiments show that thermally stable electronic traps exist in both polytypes at room temperature and considerably above, which may result in longtime transient shifts of electronic properties.

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