Cationic Hafnium Alkyl Complexes that Are Stable toward β-Hydride Elimination below 10 °C and Active as Initiators for the Living Polymerization of 1-Hexene

2001 ◽  
Vol 123 (43) ◽  
pp. 10746-10747 ◽  
Author(s):  
Parisa Mehrkhodavandi ◽  
Richard R. Schrock
Keyword(s):  
Living Polymerization ◽  
Alkyl Complexes ◽  
Hydride Elimination

β-Hydride Elimination/Abstraction from Metal–Alkyl Complexes

2003 ◽  
pp. 1
Author(s):  
K. H. Theopold ◽  
A. Mommertz ◽  
B. A. Salisbury
Keyword(s):  
Alkyl Complexes ◽  
Hydride Elimination

Competitive uncatalyzed geometrical isomerization and .beta.-hydride elimination of alkyl complexes of platinum(II)

1989 ◽  
Vol 28 (2) ◽  
pp. 342-347 ◽  
Author(s):  
Giuseppe Alibrandi ◽  
Matteo Cusumano ◽  
Domenico Minniti ◽  
Luigi Monsu Scolaro ◽  
Raffaello Romeo
Keyword(s):  
Geometrical Isomerization ◽  
Alkyl Complexes ◽  
Beta Hydride Elimination ◽  
Hydride Elimination

Thermally stable coordinatively unsaturated alkyl complexes resistant to β-hydride elimination: TpiPrM–CH2CH3 (M = Co, Fe)

1999 ◽  
pp. 417-418 ◽  
Author(s):  
Nobuhiko Shirasawa ◽  
Munetaka Akita ◽  
Shiro Hikichi ◽  
Yoshihiko Moro-oka
Keyword(s):  
Thermally Stable ◽  
Alkyl Complexes ◽  
Hydride Elimination

Aluminium alkyl complexes supported by [OSSO] type bisphenolato ligands: synthesis, characterization and living polymerization of rac-lactide

2005 ◽  
pp. 721 ◽  
Author(s):  
Haiyan Ma ◽  
Gianluca Melillo ◽  
Leone Oliva ◽  
Thomas P. Spaniol ◽  
Ulli Englert ◽  
...  
Keyword(s):  
Living Polymerization ◽  
Alkyl Complexes

Highly 3,4-selective living polymerization of 2-phenyl-1,3-butadiene with amidino N-heterocyclic carbene ligated rare-earth metal bis(alkyl) complexes

RSC Advances ◽  
2015 ◽  
Vol 5 (113) ◽  
pp. 93507-93512 ◽  
Author(s):  
Changguang Yao ◽  
Hongyan Xie ◽  
Dongmei Cui
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Living Polymerization ◽  
Alkyl Complexes

2-Phenyl-1,3-butadiene was polymerized using an amidino N-heterocyclic carbene lutetium bis(alkyl) precursor in high 3,4-selectivity (96.9%) and a living mode to afford a new plastic polydiene with a high Tg of 56.1 °C.

ChemInform Abstract: Competitive Uncatalyzed Geometrical Isomerization and β-Hydride Elimination of Alkyl Complexes of Platinum(II).

ChemInform ◽  
1989 ◽  
Vol 20 (20) ◽  
Author(s):  
G. ALIBRANDI ◽  
M. CUSUMANO ◽  
D. MINNITI ◽  
L. MONSU SCOLARO ◽  
R. ROMEO
Keyword(s):  
Geometrical Isomerization ◽  
Alkyl Complexes ◽  
Hydride Elimination

Alkene-alkyl interconversion: an experimental and computational study of the olefin insertion and β-hydride elimination processes

2018 ◽  
Vol 47 (19) ◽  
pp. 6808-6818 ◽  
Author(s):  
S. Azpeitia ◽  
U. Prieto ◽  
E. San Sebastián ◽  
A. Rodríguez-Diéguez ◽  
M. A. Garralda ◽  
...  
Keyword(s):  
Computational Study ◽  
Alkyl Complexes ◽  
Hydride Elimination

Six new silyl-thioether rhodium and iridium compounds have been used to study the transformation of alkene- into alkyl-complexes and vice versa.

Computational Analysis of Two-State Reactivity in β-Hydride Elimination Mechanisms of Fe(II)– and Co(II)–Alkyl Complexes Supported by β-Diketiminate Ligand

2019 ◽  
Vol 38 (19) ◽  
pp. 3582-3589 ◽  
Author(s):  
Toshiyuki Takayanagi ◽  
Kohei Saito ◽  
Haruya Suzuki ◽  
Yuya Watabe ◽  
Takashi Fujihara
Keyword(s):  
Computational Analysis ◽  
Alkyl Complexes ◽  
Hydride Elimination
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