scholarly journals Supramolecular interaction of non-racemic benzimidazolium based ion pairs with chiral substrates

2018 ◽  
Vol 20 (32) ◽  
pp. 20821-20826 ◽  
Author(s):  
Salma Mumtaz ◽  
Israel Cano ◽  
Nargis Mumtaz ◽  
Ahmed Abbas ◽  
Jairton Dupont ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Chiral Recognition ◽  
Ion Pairs ◽  
Supramolecular Interactions ◽  
Supramolecular Interaction ◽  
Mosher’S Acid ◽  
Acid Salts

Benzimidazolium-based non-racemic ionic liquids as chiral recognition agents showed supramolecular interactions between H–C2 of cation and racemic Mosher's acid salts.

Synthesis and Properties of Novel Chiral Ionic Liquids from L-Proline

2008 ◽  
Vol 61 (7) ◽  
pp. 521 ◽  
Author(s):  
Hong-Shuai Gao ◽  
Zhi-Guo Hu ◽  
Jian-Ji Wang ◽  
Zhao-Fa Qiu ◽  
Feng-Qiu Fan
Keyword(s):  
Ionic Liquids ◽  
Melting Point ◽  
Thermal Degradation ◽  
Physical Properties ◽  
Chiral Recognition ◽  
Specific Rotation ◽  
Acid Salt ◽  
Chiral Ionic Liquids ◽  
Potential Use ◽  
Mosher’S Acid

A novel class of chiral ionic liquids with chiral cations directly derived from natural l-proline has been synthesized and their physical properties such as melting point, thermal degradation, and specific rotation have been characterized. Further, their potential use in chiral recognition was demonstrated by studying interactions with racemic Mosher’s acid salt.

A remarkable chiral recognition of racemic Mosher's acid salt by naturally derived chiral ionic liquids using 19F NMR spectroscopy

RSC Advances ◽  
2016 ◽  
Vol 6 (46) ◽  
pp. 39758-39761 ◽  
Author(s):  
R. Jayachandra ◽  
Sabbasani Rajasekhara Reddy
Keyword(s):  
Ionic Liquids ◽  
Nmr Spectroscopy ◽  
Chiral Recognition ◽  
19F Nmr ◽  
Acid Salt ◽  
19F Nmr Spectroscopy ◽  
Chiral Ionic Liquids ◽  
New Class ◽  
Mosher’S Acid

A new class of d-xylose derived imidazolium-based chiral ionic liquids were designed and synthesized via simple tuning approaches.

Dynamics of Ion Locking in Doubly Polymerized Ionic Liquids

2020 ◽  
Author(s):  
Swati Arora ◽  
Julisa Rozon ◽  
Jennifer Laaser
Keyword(s):  
Dielectric Constant ◽  
Ionic Liquid ◽  
Ionic Liquids ◽  
Ion Pairs ◽  
Polymer Chains ◽  
Ion Motion ◽  
Charged Species ◽  
Broadband Dielectric Spectroscopy ◽  
Covalently Linked ◽  
Insight Into

<div>In this work, we investigate the dynamics of ion motion in “doubly-polymerized” ionic liquids (DPILs) in which both charged species of an ionic liquid are covalently linked to the same polymer chains. Broadband dielectric spectroscopy is used to characterize these materials over a broad frequency and temperature range, and their behavior is compared to that of conventional “singly-polymerized” ionic liquids (SPILs) in which only one of the charged species is attached to the polymer chains. Polymerization of the DPIL decreases the bulk ionic conductivity by four orders of magnitude relative to both SPILs. The timescales for local ionic rearrangement are similarly found to be approximately four orders of magnitude slower in the DPILs than in the SPILs, and the DPILs also have a lower static dielectric constant. These results suggest that copolymerization of the ionic monomers affects ion motion on both the bulk and the local scales, with ion pairs serving to form strong physical crosslinks between the polymer chains. This study provides quantitative insight into the energetics and timescales of ion motion that drive the phenomenon of “ion locking” currently under investigation for new classes of organic electronics.</div>

Delivery of ionizable hydrophilic drugs based on pharmaceutical formulation of ion pairs and ionic liquids

2020 ◽  
Vol 156 ◽  
pp. 203-218 ◽  
Author(s):  
Alexander Gamboa ◽  
Nina Schüßler ◽  
Eduardo Soto-Bustamante ◽  
Patricio Romero-Hasler ◽  
Lorenz Meinel ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Ion Pairs ◽  
Pharmaceutical Formulation ◽  
Hydrophilic Drugs

Amino alcohol-derived chiral ionic liquids: structural investigations toward chiral recognition

2015 ◽  
Vol 26 (18-19) ◽  
pp. 1069-1082 ◽  
Author(s):  
Maria Vasiloiu ◽  
Isabella Cervenka ◽  
Peter Gaertner ◽  
Matthias Weil ◽  
Christian Schröder ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Amino Alcohol ◽  
Chiral Recognition ◽  
Structural Investigations ◽  
Chiral Ionic Liquids

scholarly journals Pyr1,xTFSI Ionic Liquids (x = 1–8): A Computational Chemistry Study

2020 ◽  
Vol 10 (23) ◽  
pp. 8552
Author(s):  
Sergio Brutti
Keyword(s):  
Ionic Liquids ◽  
Physicochemical Properties ◽  
Density Functional ◽  
Ion Pairs ◽  
Molecular Size ◽  
Molecular Structures ◽  
Safety Standards ◽  
Oxidation Reduction ◽  
Reduction Stability ◽  
The Impact

Pyrrolidinium-based (Pyr) ionic liquids are a very wide family of molecular species. Pyrrolidinium cations are electrochemically stable in a large potential interval and their molecular size hinders their transport properties. The corresponding ionic liquids with trifluoromethyl sulphonyl imide anions are excellent solvents for lithium/sodium salts and have been demonstrated as electrolytes in aprotic batteries with enhanced safety standards. In this study, the analysis of the physicochemical properties of a homologous series of pyrrolidinium-based ionic liquids with general formula Pyr1,xTFSI (x = 1–8) have been tackled by first principles calculations based on the density functional theory. The molecular structures of isolated ions and ion pairs have been predicted by electronic structure calculations at B3LYP level of theory in vacuum or in simulated solvents. Thermodynamic properties have been calculated to evaluate the ion pairs dissociation and oxidation/reduction stability. This is the first systematic computational analysis of this series of molecules with a specific focus on the impact of the length of the alkyl chain on the pyrrolidinium cation on the overall physicochemical properties of the ion pairs.

Density Functional Theory Study on the Absorption of CO2 by the Ionic Liquid of 1-butyl-3-methylimidazolium Acetate

2013 ◽  
Vol 807-809 ◽  
pp. 543-548 ◽  
Author(s):  
Yan Fei Chen ◽  
Yan Hong Cui ◽  
Dong Shun Deng ◽  
Ning Ai
Keyword(s):  
Density Functional Theory ◽  
Ionic Liquid ◽  
Ionic Liquids ◽  
Density Functional ◽  
Ion Pairs ◽  
Ion Pair ◽  
Frontier Molecular Orbitals ◽  
Density Functional Theory Study ◽  
Electronic Density ◽  
Functional Theory

The absorptions of CO2on the 1-butyl-3-methylimidazolium acetate ([Bmi [Ac]) with different substituents are calculated systematically at GGA/PW91 level. Three hydrogen bonds are formed between [A and cations of 1-n-[Bmi [A ([NBmi+) and 1-tert-[Bmi [A ([TBmi+). The interaction between CO2and the [NBmi [A by a C-O bond is much weaker than that with the [TBmi [A by forming a O...O...C...C four member-ring. The chemisorption of CO2on the ion pairs of [NBmi [A is much weaker than that on the [TBmi [A, resulted from the absorption energies analysis. The frontier molecular orbitals shows the electronic density overlap between absorbed CO2and the [A in CO2-[NBmi [A is much weaker than that in [TBmi [A. Therefore, the chemisorption of CO2on the ion pair of [NBmi [A is much weaker than that on the [TBmi [A. The ionic liquids based [NBmi+can be used repetitively, and the adsorbed CO2would be easier desorbed.

Liquids intermediate between “molecular” and “ionic” liquids: Liquid Ion Pairs?

2007 ◽  
pp. 3817 ◽  
Author(s):  
Kevin J. Fraser ◽  
Ekaterina I. Izgorodina ◽  
Maria Forsyth ◽  
Janet L. Scott ◽  
Douglas R. MacFarlane
Keyword(s):  
Ionic Liquids ◽  
Ion Pairs

Supramolecular control over pillararene-based LCST phase behaviour

2018 ◽  
Vol 42 (11) ◽  
pp. 8330-8333 ◽  
Author(s):  
Li Wang ◽  
Xing Li ◽  
Qiao Zhang ◽  
Zheng Luo ◽  
Yan Deng ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Phase Behaviour ◽  
Supramolecular Interactions ◽  
Responsive Systems ◽  
Supramolecular Control

Based on the supramolecular interactions between pillar[5]arenes and ionic liquids, supramolecular control was successfully introduced into thermo-responsive systems to adjust LCST phase behaviour in water.

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