Oxygen vacancy induces self-doping effect and metalloid LSPR in non-stoichiometric tungsten suboxide synergistically contributing to the enhanced photoelectrocatalytic performance of WO3−x/TiO2−x heterojunction

2018 ◽  
Vol 20 (25) ◽  
pp. 17268-17278 ◽  
Author(s):  
Weicheng Huang ◽  
Jinxin Wang ◽  
Lang Bian ◽  
Chaoyue Zhao ◽  
Danqing Liu ◽  
...  

An oxygen-defective heterojunction was made to support the synergistic effect of band-gap narrowing and LSPR-enhanced photoelectrocatalysis.

Author(s):  
Jin Ye ◽  
Jiating Xu ◽  
Chunsheng Li ◽  
Di Tian ◽  
Xiaohan Zhao ◽  
...  

Utilizing semiconductors to catalyze N2 into NH3 has brought great promise in alleviating the issue of energy shortage. However, the wide band gap and high recombination rate of photogenerated (e-/h+)...


Nanoscale ◽  
2013 ◽  
Vol 5 (19) ◽  
pp. 9238 ◽  
Author(s):  
Sajid Ali Ansari ◽  
Mohammad Mansoob Khan ◽  
Shafeer Kalathil ◽  
Ambreen Nisar ◽  
Jintae Lee ◽  
...  

2012 ◽  
Vol 4 (8) ◽  
pp. 4024-4030 ◽  
Author(s):  
Junpeng Wang ◽  
Zeyan Wang ◽  
Baibiao Huang ◽  
Yandong Ma ◽  
Yuanyuan Liu ◽  
...  

2021 ◽  
Vol 2 (19) ◽  
pp. 6267-6271 ◽  
Author(s):  
U. Sandhya Shenoy ◽  
D. Krishna Bhat

Extraordinary tuning of electronic structure of SnTe by Bi in the presence of Pb as a co-adjuvant dopant. Synergistic effect of resonance level, increase in the band gap, valence and conduction sub-bands convergence leads to enhanced TE performance.


2019 ◽  
Vol 7 (16) ◽  
pp. 4817-4821 ◽  
Author(s):  
U. Sandhya Shenoy ◽  
D. Krishna Bhat

Resonance states due to Bi and In co-doping, band gap enlargement, and a reduced valence-band offset in SnTe lead to a record high room-temperature ZT.


RSC Advances ◽  
2014 ◽  
Vol 4 (107) ◽  
pp. 62423-62429 ◽  
Author(s):  
Sara Rahimnejad ◽  
Jing Hui He ◽  
Wei Chen ◽  
Kai Wu ◽  
Guo Qin Xu

WO3 nanoplates derived from NiWO4 were found to have the highest concentration of oxygen vacancy, narrowest band gap, longest electron–hole recombination time, and in turn the highest rate of photodegradation of azo dye methylene blue.


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