Regio- and chemoselective rearrangement of terminal epoxides into methyl alkyl and aryl ketones

2018 ◽  
Vol 54 (80) ◽  
pp. 11340-11343 ◽  
Author(s):  
Yingying Tian ◽  
Eva Jürgens ◽  
Doris Kunz
Keyword(s):  
Methyl Ketones ◽  
Mild Conditions ◽  
Aryl Ketones ◽  
Rh Catalyst

The efficient and selective isomerisation of terminal epoxides into methyl ketones applying the nucleophilic Rh-catalyst 2LiX under mild conditions is reported.

Triple condensation of aryl methyl ketones catalyzed by amine and trifluoroacetic acid: straightforward access to 1,3,5-triarylbenzenes under mild conditions

2012 ◽  
Vol 53 (19) ◽  
pp. 2436-2439 ◽  
Author(s):  
Shao-Liang Zhang ◽  
Zhao-Feng Xue ◽  
Ya-Ru Gao ◽  
Shuai Mao ◽  
Yong-Qiang Wang
Keyword(s):  
Trifluoroacetic Acid ◽  
Methyl Ketones ◽  
Mild Conditions ◽  
Aryl Methyl

Highly Active Gold(I)–Silver(I) Oxo Cluster Activating sp3C–H Bonds of Methyl Ketones under Mild Conditions

2015 ◽  
Vol 137 (16) ◽  
pp. 5520-5525 ◽  
Author(s):  
Xiao-Li Pei ◽  
Yang Yang ◽  
Zhen Lei ◽  
Shan-Shan Chang ◽  
Zong-Jie Guan ◽  
...  
Keyword(s):  
Methyl Ketones ◽  
Mild Conditions ◽  
Highly Active

A visible-light-induced chemoselective radical/oxidative addition domino process to access α-chloro and α-alkoxy aryl ketones

2016 ◽  
Vol 52 (89) ◽  
pp. 13105-13108 ◽  
Author(s):  
Teng-fei Niu ◽  
Ding-yun Jiang ◽  
Si-yuan Li ◽  
Bang-qing Ni ◽  
Liang Wang
Keyword(s):  
Visible Light ◽  
Oxidative Addition ◽  
Mild Conditions ◽  
Aryl Ketones

A visible-light-induced radical-triggered chemoselective domino process to access α,α-di-functionalized ketones under mild conditions has been developed.

A Concise and Efficient Approach to 2,6-Disubstituted 4-Fluoro­pyrimidines from α-CF3 Aryl Ketones

Synthesis ◽  
2019 ◽  
Vol 52 (02) ◽  
pp. 273-280 ◽  
Author(s):  
Fangran Liu ◽  
Xiaofei Zhang ◽  
Qun Qian ◽  
Chunhao Yang
Keyword(s):  
Medicinal Chemistry ◽  
Building Blocks ◽  
Practical Approach ◽  
Efficient Approach ◽  
Mild Conditions ◽  
Aryl Ketones

Herein, a concise and efficient protocol to synthesize a series of 2,6-disubstituted 4-fluoropyrimidines as universal and useful building blocks in medicinal chemistry is reported. From readily accessible α-CF3 aryl ketones and different amidine hydrochlorides, this method provides a very practical approach to this kind of compounds under mild conditions with good to excellent yields.

scholarly journals Ligand-Mediated and Copper-Catalyzed C(sp3)-H Bond Functionalization of Aryl Ketones with Sodium Sulfinates under Mild Conditions

2015 ◽  
Vol 5 (1) ◽  
Author(s):  
Xing-Wang Lan ◽  
Nai-Xing Wang ◽  
Cui-Bing Bai ◽  
Wei Zhang ◽  
Yalan Xing ◽  
...  
Keyword(s):  
Bond Functionalization ◽  
Mild Conditions ◽  
Aryl Ketones

Electrochemical synthesis of α-enaminones from aryl ketones

2016 ◽  
Vol 52 (55) ◽  
pp. 8600-8603 ◽  
Author(s):  
Yanan Li ◽  
Huihui Gao ◽  
Zhenlei Zhang ◽  
Peng Qian ◽  
Meixiang Bi ◽  
...  
Keyword(s):  
Electrochemical Oxidation ◽  
Electrochemical Synthesis ◽  
Mild Conditions ◽  
Novel Approach ◽  
Aryl Ketones

A novel approach to realize the synthesis of α-enaminones via electrochemical oxidation was developed under mild conditions.

ChemInform Abstract: Concise Synthesis of 1-Naphthols under Mild Conditions Through a Copper-Catalyzed Arylation of Methyl Ketones.

ChemInform ◽  
2014 ◽  
Vol 45 (31) ◽  
pp. no-no
Author(s):  
Zhenbang Lou ◽  
Shu Zhang ◽  
Chao Chen ◽  
Xinlong Pang ◽  
Ming Li ◽  
...  
Keyword(s):  
Methyl Ketones ◽  
Mild Conditions
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