ChemInform Abstract: Concise Synthesis of 1-Naphthols under Mild Conditions Through a Copper-Catalyzed Arylation of Methyl Ketones.

ChemInform ◽  
2014 ◽  
Vol 45 (31) ◽  
pp. no-no
Author(s):  
Zhenbang Lou ◽  
Shu Zhang ◽  
Chao Chen ◽  
Xinlong Pang ◽  
Ming Li ◽  
...  
Keyword(s):  
Methyl Ketones ◽  
Mild Conditions

Regio- and chemoselective rearrangement of terminal epoxides into methyl alkyl and aryl ketones

2018 ◽  
Vol 54 (80) ◽  
pp. 11340-11343 ◽  
Author(s):  
Yingying Tian ◽  
Eva Jürgens ◽  
Doris Kunz
Keyword(s):  
Methyl Ketones ◽  
Mild Conditions ◽  
Aryl Ketones ◽  
Rh Catalyst

The efficient and selective isomerisation of terminal epoxides into methyl ketones applying the nucleophilic Rh-catalyst 2LiX under mild conditions is reported.

Triple condensation of aryl methyl ketones catalyzed by amine and trifluoroacetic acid: straightforward access to 1,3,5-triarylbenzenes under mild conditions

2012 ◽  
Vol 53 (19) ◽  
pp. 2436-2439 ◽  
Author(s):  
Shao-Liang Zhang ◽  
Zhao-Feng Xue ◽  
Ya-Ru Gao ◽  
Shuai Mao ◽  
Yong-Qiang Wang
Keyword(s):  
Trifluoroacetic Acid ◽  
Methyl Ketones ◽  
Mild Conditions ◽  
Aryl Methyl

Highly Active Gold(I)–Silver(I) Oxo Cluster Activating sp3C–H Bonds of Methyl Ketones under Mild Conditions

2015 ◽  
Vol 137 (16) ◽  
pp. 5520-5525 ◽  
Author(s):  
Xiao-Li Pei ◽  
Yang Yang ◽  
Zhen Lei ◽  
Shan-Shan Chang ◽  
Zong-Jie Guan ◽  
...  
Keyword(s):  
Methyl Ketones ◽  
Mild Conditions ◽  
Highly Active

Copper-Catalyzed Oxidative Synthesis of α-Ketoamides from Aryl Methyl Ketones and N-Bromobutanimide Using N,N-Dimethylformamide as Dimethylamine Source

Synlett ◽  
2020 ◽  
Vol 31 (04) ◽  
pp. 393-397 ◽  
Author(s):  
Ying Wei ◽  
Yongxia Yan ◽  
Xiaoyan Li
Keyword(s):  
Acid Hydrolysis ◽  
Dual Role ◽  
Methyl Ketones ◽  
Mechanistic Studies ◽  
Mild Conditions ◽  
Aryl Methyl

A novel and practical Cu(OAc)2-catalyzed oxidative synthesis of α-ketoamides from aryl methyl ketones and N-bromobutanimide (NBS) using N,N-dimethylformamide (DMF) as dimethylamine (HNMe2) source and solvent has been developed under mild conditions. DMF was used as a HNMe2 source and can be easily converted into HNMe2 by acid hydrolysis. The mechanistic studies indicate that Cu(OAc)2 plays a dual role in providing both catalyst and oxidant.

nBu4NI-Mediated oxidation of methyl ketones to α-ketoamides: using ammonium, primary and secondary amine-salt as an amine moiety

2017 ◽  
Vol 15 (16) ◽  
pp. 3427-3434 ◽  
Author(s):  
Dan Wang ◽  
Kuan Zhang ◽  
Luhan Jia ◽  
Danting Zhang ◽  
Yue Zhang ◽  
...  
Keyword(s):  
Secondary Amine ◽  
Amine Salt ◽  
Ammonium Salts ◽  
Methyl Ketones ◽  
Mild Conditions ◽  
Mediated Oxidation

Presented is the first example of synthesizing an array of primary-, secondary-, and tertiary-α-ketoamides in moderate to excellent yields with a catalyst nBu4NI from methyl ketones and amine/ammonium salts under mild conditions using oxidant TBHP.

Concise Synthesis of 1-Naphthols under Mild Conditions through a Copper-Catalyzed Arylation of Methyl Ketones

2014 ◽  
Vol 356 (1) ◽  
pp. 153-159 ◽  
Author(s):  
Zhenbang Lou ◽  
Shu Zhang ◽  
Chao Chen ◽  
Xinlong Pang ◽  
Ming Li ◽  
...  
Keyword(s):  
Methyl Ketones ◽  
Mild Conditions

Synthesis of 1,3,4-Oxadiazoles by Iodine-mediated Oxidative Cyclization of Methyl Ketones with 4-Phenylsemicarbazide

Synlett ◽  
2021 ◽  
Author(s):  
Shanshan Zhang ◽  
Chuang Liu ◽  
Xiaojun Wu ◽  
Wen Li ◽  
He Li ◽  
...  
Keyword(s):  
Functional Groups ◽  
Oxidative Cyclization ◽  
Methyl Ketones ◽  
One Pot ◽  
Mild Conditions ◽  
Wide Range ◽  
Reaction Proceeds ◽  
Aryl Methyl

An efficient one-pot method to access 5-amino-2-benzoyl-1,3,4-oxadiazoles via I2/DMSO promoted oxidative cyclization of 4-phenylsemicarbazide with (het)aryl methyl ketones under mild conditions was developed. This reaction proceeds smoothly with a wide range of methyl ketones containing different functional groups to give the corresponding products in moderate yields under mild conditions.

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