Tri(o-tolyl)phosphine for highly efficient Suzuki coupling of propargylic carbonates with boronic acids

2018 ◽  
Vol 54 (74) ◽  
pp. 10451-10454 ◽  
Author(s):  
Junzhe Xiao ◽  
Hongwen Luo ◽  
Shan Huang ◽  
Hui Qian ◽  
Shengming Ma

Tri(o-tolyl)phosphine has been identified as a highly efficient ligand for Pd-catalyzed coupling of propargylic carbonates with different types of organo boronic acids at room temperature.

2014 ◽  
Vol 50 (56) ◽  
pp. 7527-7530 ◽  
Author(s):  
Guobin Ma ◽  
Wen Wan ◽  
Qingyang Hu ◽  
Haizhen Jiang ◽  
Jing Wang ◽  
...  

A simple and highly efficient Cu-mediated gem-difluoromethylenation of a variety of aryl boronic acids with bromodifluoromethylated heterocyclic compounds has been disclosed. The transformations were performed in air at room temperature without ligands, bases, or additives.


RSC Advances ◽  
2015 ◽  
Vol 5 (61) ◽  
pp. 49568-49576 ◽  
Author(s):  
Mohammad Gholinejad ◽  
Mehran Razeghi ◽  
Carmen Najera

Magnetic nanoparticles of Fe3O4 supported oxime palladacycle as a novel catalyst for room temperature Suzuki coupling reaction in aqueous media.


Molecules ◽  
2014 ◽  
Vol 19 (5) ◽  
pp. 6524-6533 ◽  
Author(s):  
Mengping Guo ◽  
Shiwen Liu ◽  
Xiuling Zhou ◽  
Meiyun Lv ◽  
Sanbao Chen ◽  
...  

2014 ◽  
Vol 12 (25) ◽  
pp. 4511-4516 ◽  
Author(s):  
Shiwen Liu ◽  
Meiyun Lv ◽  
Daoan Xiao ◽  
Xiaogang Li ◽  
Xiuling Zhou ◽  
...  

Glycine is used to prepare an air-stable and water-soluble catalyst for the Suzuki–Miyaura reaction. In the presence of 0.1% [PdCl2(NH2CH2COOH)2], excellent catalytic activity is observed at room temperature under air in neat water.


2004 ◽  
Vol 6 (9) ◽  
pp. 1473-1476 ◽  
Author(s):  
Wei Zhang ◽  
Christine Hiu-Tung Chen ◽  
Yimin Lu ◽  
Tadamichi Nagashima

Author(s):  
Pan Xie ◽  
Cheng Xue ◽  
Cancan Wang ◽  
Dongdong Du ◽  
Sanshan Shi

A CF3SO2Na/Pd(OAc)2 co-catalyzed strategy is developed to produce aryl ketones via visible-light-induced decarboxylative cross-coupling of α-oxocarboxylic acids and aryl boronic acids. This process was perfomed under air at room temperature,...


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