Highly effective copper-mediated gem-difluoromethylenation of arylboronic acids

2014 ◽  
Vol 50 (56) ◽  
pp. 7527-7530 ◽  
Author(s):  
Guobin Ma ◽  
Wen Wan ◽  
Qingyang Hu ◽  
Haizhen Jiang ◽  
Jing Wang ◽  
...  
Keyword(s):  
Heterocyclic Compounds ◽  
Room Temperature ◽  
Boronic Acids ◽  
Arylboronic Acids ◽  
Highly Efficient ◽  
Highly Effective

A simple and highly efficient Cu-mediated gem-difluoromethylenation of a variety of aryl boronic acids with bromodifluoromethylated heterocyclic compounds has been disclosed. The transformations were performed in air at room temperature without ligands, bases, or additives.

Room temperature nickel-catalyzed cross-coupling of aryl-boronic acids with thiophenols: synthesis of diarylsulfides

2020 ◽  
Vol 18 (13) ◽  
pp. 2447-2458 ◽  
Author(s):  
Amit Bhowmik ◽  
Mahesh Yadav ◽  
Rodney A. Fernandes
Keyword(s):  
Room Temperature ◽  
Cross Coupling ◽  
Boronic Acids ◽  
Arylboronic Acids

A mild and easy to operate NiCl2/2,2′-bipyridine-catalyzed cross-coupling of thiophenols with arylboronic acids has been developed for the synthesis of symmetric and unsymmetric diarylsulfides at room temperature and in air.

Highly Efficient Synthesis of Phenols by Copper-Catalyzed Oxidative Hydroxylation of Arylboronic Acids at Room Temperature in Water

2010 ◽  
Vol 12 (9) ◽  
pp. 1964-1967 ◽  
Author(s):  
Jimin Xu ◽  
Xinyan Wang ◽  
Changwei Shao ◽  
Deyong Su ◽  
Guolin Cheng ◽  
...  
Keyword(s):  
Room Temperature ◽  
Efficient Synthesis ◽  
Arylboronic Acids ◽  
Highly Efficient

Phosphine-catalyzed [3 + 2] cycloaddition of phthalazinium dicyanomethanides with allenoates: highly efficient synthesis of 1,2,3,10b-tetrahydropyrrolo[2,1-a]phthalazine derivatives

RSC Advances ◽  
2016 ◽  
Vol 6 (81) ◽  
pp. 77931-77936 ◽  
Author(s):  
Chunhao Yuan ◽  
Leijie Zhou ◽  
Zhanhu Sun ◽  
Hongchao Guo
Keyword(s):  
Heterocyclic Compounds ◽  
Room Temperature ◽  
Efficient Synthesis ◽  
Highly Efficient

The phosphine-catalyzed [3 + 2] cycloaddition has been achieved at room temperature, providing novel heterocyclic compounds, 1,2,3,10b-tetrahydropyrrolo[2,1-a]phthalazine derivatives, as single (Z)-isomers in excellent yields (88–99% yield).

ChemInform Abstract: Highly Efficient Synthesis of Phenols by Copper-Catalyzed Oxidative Hydroxylation of Arylboronic Acids at Room Temperature in Water.

ChemInform ◽  
2010 ◽  
Vol 41 (36) ◽  
pp. no-no
Author(s):  
Jimin Xu ◽  
Xinyan Wang ◽  
Changwei Shao ◽  
Deyong Su ◽  
Guolin Cheng ◽  
...  
Keyword(s):  
Room Temperature ◽  
Efficient Synthesis ◽  
Arylboronic Acids ◽  
Highly Efficient

Copper-Catalyzed N-Arylation of Sulfoximines with Arylboronic Acids under Mild Conditions

Synthesis ◽  
2019 ◽  
Vol 51 (10) ◽  
pp. 2171-2182 ◽  
Author(s):  
Surabhi Gupta ◽  
Siddharth Baranwal ◽  
Nalluchamy Muniyappan ◽  
Shahulhameed Sabiah ◽  
Jeyakumar Kandasamy
Keyword(s):  
Room Temperature ◽  
Boronic Acids ◽  
Methionine Sulfoximine ◽  
Reaction Conditions ◽  
Biologically Relevant ◽  
Arylboronic Acids ◽  
Mild Conditions ◽  
Short Span ◽  
Sterically Hindered ◽  
First Time

N-Arylation of sulfoximines with different arylboronic acids, including sterically hindered boronic acids, is achieved using copper(I) iodide and 4-DMAP at room temperature. Moreover, N-arylation of biologically relevant l-methionine sulfoximine is demonstrated for the first time. All these reactions provided the desired products in excellent yields within a short span of time. The optimized reaction conditions are well suited to the task of N-vinylation of sulfoximine with trans-2-phenylvinylboronic acid.

Tri(o-tolyl)phosphine for highly efficient Suzuki coupling of propargylic carbonates with boronic acids

2018 ◽  
Vol 54 (74) ◽  
pp. 10451-10454 ◽  
Author(s):  
Junzhe Xiao ◽  
Hongwen Luo ◽  
Shan Huang ◽  
Hui Qian ◽  
Shengming Ma
Keyword(s):  
Room Temperature ◽  
Suzuki Coupling ◽  
Boronic Acids ◽  
Highly Efficient ◽  
Different Types

Tri(o-tolyl)phosphine has been identified as a highly efficient ligand for Pd-catalyzed coupling of propargylic carbonates with different types of organo boronic acids at room temperature.

Green Photoorganocatalytic Synthesis of Phenols from Arylboronic Acids

Synlett ◽  
2017 ◽  
Vol 29 (10) ◽  
pp. 1324-1328 ◽  
Author(s):  
Christoforos Kokotos ◽  
Ioanna Sideri ◽  
Errika Voutyritsa
Keyword(s):  
Functional Groups ◽  
Room Temperature ◽  
Boronic Acids ◽  
Light Irradiation ◽  
Reaction Conditions ◽  
Arylboronic Acids ◽  
Water As Solvent ◽  
High Yields

A green and cheap protocol for the photocatalytic hydroxylation of arylboronic acids is presented. 2,2-Dimethoxy-2-phenylacetophenone proved to be the best photoinitiator, among a range of organocatalysts in promoting this reaction. This photocatalytic protocol can be expanded into a wide substrate scope of aromatic boronic acids bearing various functional groups, leading to the corresponding phenols in good to high yields under mild reaction conditions, which include water as solvent, light irradiation provided from standard light-bulbs at room temperature.

A highly efficient heterogeneous copper-catalyzed Chan–Lam coupling reaction of sulfonyl azides with arylboronic acids leading to N-arylsulfonamides

RSC Advances ◽  
2016 ◽  
Vol 6 (49) ◽  
pp. 43605-43612 ◽  
Author(s):  
Chongren You ◽  
Fang Yao ◽  
Tao Yan ◽  
Mingzhong Cai
Keyword(s):  
Coupling Reaction ◽  
Practical Method ◽  
Boronic Acids ◽  
Arylboronic Acids ◽  
Highly Efficient ◽  
Sulfonyl Azides

A highly efficient and practical method for the synthesis of N-arylsulfonamides has been developed by a heterogeneous copper-catalyzed Chan–Lam coupling between sulfonyl azides and boronic acids.

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