A NIR rhodamine fluorescent chemodosimeter specific for glutathione: Knoevenagel condensation, detection of intracellular glutathione and living cell imaging

2018 ◽  
Vol 6 (12) ◽  
pp. 1791-1798 ◽  
Author(s):  
Lulu Tong ◽  
Ying Qian

A new near-infrared probe for detecting glutathione based on conjugate addition and intramolecular amino induced spirolactam opening named RhAN was designed and synthesized. Its emission intensity enhance more than 90-fold upon addition of GSH. In addition, it also has high sensitivity with low detection limit of 0.1 μM.

RSC Advances ◽  
2014 ◽  
Vol 4 (6) ◽  
pp. 2989-2992 ◽  
Author(s):  
Jia-Hai Ye ◽  
Yixin Wang ◽  
Yang Bai ◽  
Wenchao Zhang ◽  
Weijiang He

RSC Advances ◽  
2014 ◽  
Vol 4 (104) ◽  
pp. 59809-59816 ◽  
Author(s):  
Qi Zou ◽  
Xin Li ◽  
Qunjie Xu ◽  
Hans Ågren ◽  
Wandong Zhao ◽  
...  

RSC Advances ◽  
2017 ◽  
Vol 7 (88) ◽  
pp. 55839-55845 ◽  
Author(s):  
Li Zhu ◽  
Wensheng Xie ◽  
Lingyun Zhao ◽  
Yongjie Zhang ◽  
Zhijian Chen

The new NIR absorbing aza-BODIPY dyes bearing tetraphenylethylene and fluorinyl substituents were synthesized and characterized. The application potential of these new dyes in living cell imaging was demonstrated.


2019 ◽  
Vol 411 (30) ◽  
pp. 7957-7966 ◽  
Author(s):  
Xueyan Zhang ◽  
Xiangzhu Chen ◽  
Yuanyuan Zhang ◽  
Kaizheng Liu ◽  
Hongjing Shen ◽  
...  

ChemPlusChem ◽  
2019 ◽  
Vol 84 (3) ◽  
pp. 252-259 ◽  
Author(s):  
Pornthip Piyanuch ◽  
Jitnapa Sirirak ◽  
Anyanee Kamkaew ◽  
Oratai Weeranantanapan ◽  
Vinich Promarak ◽  
...  

2018 ◽  
Vol 9 (15) ◽  
pp. 3742-3753 ◽  
Author(s):  
Yingying Ning ◽  
Juan Tang ◽  
Yi-Wei Liu ◽  
Jing Jing ◽  
Yuansheng Sun ◽  
...  

We report three synthetic methods to prepare biocompatible Yb3+complexes, which displayed high NIR luminescence with quantum yields up to 13% in aqueous media. This renders β-fluorinated Yb3+porphyrinoids a new class of NIR probes for living cell imaging including time-resolved fluorescence lifetime imaging.


RSC Advances ◽  
2015 ◽  
Vol 5 (119) ◽  
pp. 98144-98153 ◽  
Author(s):  
Dan Wang ◽  
Ai-Min Ren ◽  
Jing-Fu Guo ◽  
Lu-Yi Zou ◽  
Shuang Huang

A novel TP FRET ratiometric fluorescent probe 2a for Cu2+ is designed. 2a has a large TPA peak in the near-infrared light region and its energy transfer efficiency is nearly 100%.


2021 ◽  
Vol 10 (1) ◽  
pp. 25-35 ◽  
Author(s):  
Thomas Strahl ◽  
Johannes Herbst ◽  
Eric Maier ◽  
Sven Rademacher ◽  
Christian Weber ◽  
...  

Abstract. The measurement of low methane (CH4) concentrations is a key objective for safety of industrial and public infrastructures and in environmental research. Laser spectroscopy is best suited for this purpose because it offers high sensitivity, selectivity, dynamic range, and a fast measurement rate. The physical basis of this technique is infrared absorption of molecular gases. Two detection schemes – direct absorption spectroscopy (DAS) and photoacoustic spectroscopy (PAS) – are compared at three wavelength regions in the near-infrared (NIR), mid-wavelength (MWIR), and long-wavelength (LWIR) infrared ranges. For each spectral range a suitable semiconductor laser is selected and used for both detection techniques: a diode laser (DL), an interband cascade laser (ICL), and a quantum cascade laser (QCL) for NIR, MWIR and LWIR, respectively. For DAS short absorption path lengths comparable to the cell dimensions of the photoacoustic cell for PAS are employed. We show that for DAS the lowest detection limit can be achieved in the MWIR range with noise-equivalent concentrations (NECs) below 10 ppb. Using PAS, lower detection limits and higher system stabilities can be reached compared to DAS, especially for long integration times. The lowest detection limit for PAS is obtained in the LWIR with a NEC of 7 ppb. The different DAS and PAS configurations are discussed with respect to potential applications.


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