Thermoresponsive plasmonic core–satellite nanostructures with reversible, temperature sensitive optical properties

Nanoscale ◽  
2018 ◽  
Vol 10 (9) ◽  
pp. 4284-4290 ◽  
Author(s):  
Fei Han ◽  
S. R. C. Vivekchand ◽  
Alexander H. Soeriyadi ◽  
Yuanhui Zheng ◽  
J. Justin Gooding
Keyword(s):  
Optical Properties ◽  
Surface Plasmon Resonance ◽  
Surface Plasmon ◽  
Plasmon Resonance ◽  
Plasmonic Nanoparticles ◽  
Temperature Sensitive

Herein is described plasmonic nanoparticles assembled into core–satellite nanostructures that exhibit dynamic and reversible tuning of the surface plasmon resonance.

scholarly journals Optical Characterization of Ultra-Thin Films of Azo-Dye-Doped Polymers Using Ellipsometry and Surface Plasmon Resonance Spectroscopy

Photonics ◽  
2021 ◽  
Vol 8 (2) ◽  
pp. 41
Author(s):  
Najat Andam ◽  
Siham Refki ◽  
Hidekazu Ishitobi ◽  
Yasushi Inouye ◽  
Zouheir Sekkat
Keyword(s):  
Refractive Index ◽  
Optical Properties ◽  
Surface Plasmon Resonance ◽  
Surface Plasmon ◽  
Spectroscopic Ellipsometry ◽  
Plasmon Resonance ◽  
Complex Refractive Index ◽  
Resonance Spectroscopy ◽  
Doped Polymers

The determination of optical constants (i.e., real and imaginary parts of the complex refractive index (nc) and thickness (d)) of ultrathin films is often required in photonics. It may be done by using, for example, surface plasmon resonance (SPR) spectroscopy combined with either profilometry or atomic force microscopy (AFM). SPR yields the optical thickness (i.e., the product of nc and d) of the film, while profilometry and AFM yield its thickness, thereby allowing for the separate determination of nc and d. In this paper, we use SPR and profilometry to determine the complex refractive index of very thin (i.e., 58 nm) films of dye-doped polymers at different dye/polymer concentrations (a feature which constitutes the originality of this work), and we compare the SPR results with those obtained by using spectroscopic ellipsometry measurements performed on the same samples. To determine the optical properties of our film samples by ellipsometry, we used, for the theoretical fits to experimental data, Bruggeman’s effective medium model for the dye/polymer, assumed as a composite material, and the Lorentz model for dye absorption. We found an excellent agreement between the results obtained by SPR and ellipsometry, confirming that SPR is appropriate for measuring the optical properties of very thin coatings at a single light frequency, given that it is simpler in operation and data analysis than spectroscopic ellipsometry.

scholarly journals Numerical Study on the Surface Plasmon Resonance Tunability of Spherical and Non-Spherical Core-Shell Dimer Nanostructures

Nanomaterials ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1728
Author(s):  
Joshua Fernandes ◽  
Sangmo Kang
Keyword(s):  
Refractive Index ◽  
Optical Properties ◽  
Surface Plasmon Resonance ◽  
Aspect Ratio ◽  
Surface Plasmon ◽  
Plasmon Resonance ◽  
Shell Thickness ◽  
Numerical Study ◽  
Field Enhancement ◽  
Core Shell

The near-field enhancement and localized surface plasmon resonance (LSPR) on the core-shell noble metal nanostructure surfaces are widely studied for various biomedical applications. However, the study of the optical properties of new plasmonic non-spherical nanostructures is less explored. This numerical study quantifies the optical properties of spherical and non-spherical (prolate and oblate) dimer nanostructures by introducing finite element modelling in COMSOL Multiphysics. The surface plasmon resonance peaks of gold nanostructures should be understood and controlled for use in biological applications such as photothermal therapy and drug delivery. In this study, we find that non-spherical prolate and oblate gold dimers give excellent tunability in a wide range of biological windows. The electromagnetic field enhancement and surface plasmon resonance peak can be tuned by varying the aspect ratio of non-spherical nanostructures, the refractive index of the surrounding medium, shell thickness, and the distance of separation between nanostructures. The absorption spectra exhibit considerably greater dependency on the aspect ratio and refractive index than the shell thickness and separation distance. These results may be essential for applying the spherical and non-spherical nanostructures to various absorption-based applications.

scholarly journals Optical properties of size selected neutral Ag clusters: electronic shell structures and the surface plasmon resonance

Nanoscale ◽  
2018 ◽  
Vol 10 (44) ◽  
pp. 20821-20827 ◽  
Author(s):  
Chongqi Yu ◽  
Romain Schira ◽  
Harald Brune ◽  
Bernd von Issendorff ◽  
Franck Rabilloud ◽  
...  
Keyword(s):  
Optical Properties ◽  
Surface Plasmon Resonance ◽  
Optical Absorption ◽  
Absorption Spectra ◽  
Surface Plasmon ◽  
Plasmon Resonance ◽  
Shell Structures ◽  
Optical Absorption Spectra ◽  
Electronic Shell ◽  
Ag Clusters

We present optical absorption spectra from the ultraviolet to the visible for size selected neutral Agn clusters (n = 5–120) embedded in solid Ne.

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