A smart ratiometric red fluorescent chemodosimeter for fluoride based on anthraquinone nosylate

2017 ◽  
Vol 41 (12) ◽  
pp. 5098-5104 ◽  
Author(s):  
Shweta Shweta ◽  
Ajit Kumar ◽  
Neeraj Neeraj ◽  
Sharad Kumar Asthana ◽  
K. K. Upadhyay

A smart ratiometric red fluorescent chemodosimeter (AH) has been explored for specific detection of F− with a lowest detection limit of 3.45 × 10−10 M. The sensing mechanism was worked out as fluoride-triggered deprotonation of imidazole accompanied by deprotection of the nosylate group.

2021 ◽  
Author(s):  
Hong-Min Lv ◽  
Zi-Ke Jiang ◽  
Jing Wang ◽  
Tao Wang ◽  
Xiao-Nan Zhang ◽  
...  

The sensing mechanism toward Hcy/Cys is realized based on the condensation reaction, which breaks CN to form a thiazolidine adduct.


2015 ◽  
Vol 60 (2) ◽  
Author(s):  
Silvana Carnevale ◽  
María Laura Pantano ◽  
Laura Kamenetzky ◽  
Jorge Bruno Malandrini ◽  
Claudia Cecilia Soria ◽  
...  

AbstractFasciolosis is an important parasitic zoonosis considered the most important helminth infection of ruminants in tropical countries. The aim of this study was to develop a PCR assay for the sensitive and specific detection of F. hepatica in formalin preserved sheep faeces. A 405-bp fragment of the cytochrome c oxidase subunit 1 gene of F. hepatica was amplified from stool samples of infected sheep. The PCR assay showed a detection limit of 20 pg of F. hepatica DNA. No cross-reactions were observed with samples containing coccidian oocysts or gastrointestinal nematodes eggs. Our PCR technique showed to be effective for specific detection of F. hepatica infections in sheep.


2013 ◽  
Vol 66 (4) ◽  
pp. 485 ◽  
Author(s):  
Lan He ◽  
Yanfang Luo ◽  
Wenting Zhi ◽  
Yuangen Wu ◽  
Pei Zhou

This paper proposes a sensing strategy which employs an aptamer, unmodified gold nanoparticles (AuNP), and hexadecyltrimethylammonium bromide (CTAB) to detect tetracycline (TET) in raw milk. The method is based on the colorimetric assay of aggregating AuNP. In the absence of TET, the CTAB and aptamer form a complex which allows the aggregation of AuNP. In the presence of TET, the TET aptamer is exhausted first due to the formation of aptamer-TET complexes, which prevents assembly of the CTAB–aptamer supramolecule, causing a colour change and no aggregation of AuNP. This mechanism for the detection of TET proved to be sensitive and convenient. The colorimetric assay has a detection limit of 122 nM TET. This sensor has great potential for the sensitive, colorimetric detection of a wide range of molecular analytes.


RSC Advances ◽  
2014 ◽  
Vol 4 (87) ◽  
pp. 47076-47080 ◽  
Author(s):  
Dipratn G. Khandare ◽  
Hrishikesh Joshi ◽  
Mainak Banerjee ◽  
Mahesh S. Majik ◽  
Amrita Chatterjee

An aggregation-induced emission (AIE) based “turn-on” fluorescent chemodosimeter for selective detection of Pb2+ ions has been developed. The probe is a phosphate functionalized tetraphenylethylene derivative and the resulting lead–TPE complex has very low solubility in working solvent and triggers AIE and shows a low detection limit of 10 ppb.


2015 ◽  
Vol 51 (9) ◽  
pp. 1725-1727 ◽  
Author(s):  
L. Alberto Juárez ◽  
Ana M. Costero ◽  
Margarita Parra ◽  
Salvador Gil ◽  
Félix Sancenón ◽  
...  

A new fluorescent chemodosimeter for detecting NO2 has been synthesized. The sensing mechanism is based on the regeneration of the carbonyl group induced by the target molecule. This reaction gives rise to both colorimetric and fluorescent changes. A LOD of 0.1 ppm has been determined.


RSC Advances ◽  
2015 ◽  
Vol 5 (112) ◽  
pp. 92564-92572 ◽  
Author(s):  
Radhakanta Ghosh ◽  
Sandip Das ◽  
Dhruba P. Chatterjee ◽  
Arun K. Nandi

A new fluorometric cyanide sensor using cationic polythiophene exhibits high sensitivity, selectivity with a low detection limit (4.4 ppb) in water.


2018 ◽  
Vol 6 (12) ◽  
pp. 1791-1798 ◽  
Author(s):  
Lulu Tong ◽  
Ying Qian

A new near-infrared probe for detecting glutathione based on conjugate addition and intramolecular amino induced spirolactam opening named RhAN was designed and synthesized. Its emission intensity enhance more than 90-fold upon addition of GSH. In addition, it also has high sensitivity with low detection limit of 0.1 μM.


1986 ◽  
Vol 69 (5) ◽  
pp. 852-855 ◽  
Author(s):  
Brian D McGarvey ◽  
Mikio Chiba ◽  
A Bruce Broadbent

Abstract An efficient simplified method for the extraction, cleanup, and capillary gas chromatographic (GC) analysis of residues of aldicarb, aldicarb sulfoxide, and aldicarb sulfone in chrysanthemum leaves is presented. Samples are extracted with methanol and cleaned up using columns consisting of 0.2 g Nuchar-Attaclay in disposable pipets. The 3 compounds are easily quantitated by capillary GC with splitless injection and thermionic-specific detection. Recovery of the 3 compounds at 2 levels from spiked leaves ranged from 74.3 to 90.9%. The detection limit of the GC analysis, with a 1 μL injection, is 0.01 μg/mL for aldicarb and aldicarb sulfone, and 0.06 p.g/mL for aldicarb sulfoxide.


2015 ◽  
Vol 51 (6) ◽  
pp. 1154-1156 ◽  
Author(s):  
Leiming Zhu ◽  
Junchao Xu ◽  
Zhe Sun ◽  
Boqiao Fu ◽  
Caiqin Qin ◽  
...  

A highly “reactive” probe showed a ratiometric fluorescence response to HSO3− with fast response and low detection limit (3.0 nM).


RSC Advances ◽  
2022 ◽  
Vol 12 (4) ◽  
pp. 2262-2269
Author(s):  
Ran Wei ◽  
Lifeng Jia ◽  
Xueli Jia ◽  
Hongsheng Zhai

The sensing mechanism of 3-hydroxyflavone-based (3-HF) fluorescent chemodosimeter 3-triisopropylsilylflavone (3-TPSF) for detecting fluoride (F−) has been theoretically investigated.


Sign in / Sign up

Export Citation Format

Share Document