The synthesis and reactivity of 16-electron half-sandwich iridium complexes bearing a carboranylthioamide ligand

2017 ◽  
Vol 46 (44) ◽  
pp. 15535-15540 ◽  
Author(s):  
Peng-Fei Cui ◽  
Yue-Jian Lin ◽  
Guo-Xin Jin
Keyword(s):  
Binuclear Complex ◽  
Donor Ligands ◽  
Iridium Complexes ◽  
Insertion Reactions ◽  
Metal Bond ◽  
Metal Metal ◽  
Half Sandwich

The 16-electron complex 2 has been synthesized. It can react with different donor ligands and undergoes M–S bond insertion reactions with DMAD. Complex 2 is shown to react with [Cp*Ir] unit to form a M–M-bound binuclear complex. Interestingly, the metal–metal bond could be broken by HCl to produce the selective B(6)–H activation species.

scholarly journals [(C5(CH3)5)CoCl]2(μ-NO)(μ-Cl), a binuclear complex containing a nitrosyl bridge without a metalmetal bond

1988 ◽  
Vol 340 (2) ◽  
pp. 249-256 ◽  
Author(s):  
R. Christian Strauss ◽  
Egbert Keller ◽  
Hans H. Brintzinger
Keyword(s):  
Binuclear Complex ◽  
Metal Bond ◽  
Metal Metal

Regioselective B–H/C–H activation and metal–metal bond formation induced by half-sandwich metals complexes at hydroxy-substituted o-carboranes

2018 ◽  
Vol 47 (38) ◽  
pp. 13641-13646 ◽  
Author(s):  
Shu-Ting Guo ◽  
Peng-Fei Cui ◽  
Yang Gao ◽  
Guo-Xin Jin
Keyword(s):  
Bond Formation ◽  
Iridium Complex ◽  
Metal Bond ◽  
Metal Metal ◽  
Half Sandwich

A binuclear iridium complex, (Cp2*Ir2(CH2O)C2B10H8) (6), with a unique metal–metal bond has been synthesized and fully characterized.

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