Regioselective B–H/C–H activation and metal–metal bond formation induced by half-sandwich metals complexes at hydroxy-substituted o-carboranes

2018 ◽  
Vol 47 (38) ◽  
pp. 13641-13646 ◽  
Author(s):  
Shu-Ting Guo ◽  
Peng-Fei Cui ◽  
Yang Gao ◽  
Guo-Xin Jin
Keyword(s):  
Bond Formation ◽  
Iridium Complex ◽  
Metal Bond ◽  
Metal Metal ◽  
Half Sandwich

A binuclear iridium complex, (Cp2*Ir2(CH2O)C2B10H8) (6), with a unique metal–metal bond has been synthesized and fully characterized.

Metal-metal bond formation and rearrangement of the S2CPR3 ligands in binuclear manganese-molybdenum complexes. X-ray structure of [MnMo(SnPh3)(CO)6(.mu.-S2CPPr-iso3)]

1993 ◽  
Vol 12 (8) ◽  
pp. 2888-2890 ◽  
Author(s):  
Daniel Miguel ◽  
Julio A. Perez-Martinez ◽  
Victor Riera ◽  
Santiago Garcia-Granda
Keyword(s):  
Bond Formation ◽  
Molybdenum Complexes ◽  
X Ray ◽  
Metal Bond ◽  
Metal Metal

Dinitrogen Fixation versus Metal-Metal Bond Formation in the Chemistry of Vanadium(II) Amidinates

1994 ◽  
Vol 116 (16) ◽  
pp. 7417-7418 ◽  
Author(s):  
Pietro Berno ◽  
Shoukang Hao ◽  
Ravinder Minhas ◽  
Sandro Gambarotta
Keyword(s):  
Bond Formation ◽  
Dinitrogen Fixation ◽  
Metal Bond ◽  
Metal Metal

The synthesis and reactivity of 16-electron half-sandwich iridium complexes bearing a carboranylthioamide ligand

2017 ◽  
Vol 46 (44) ◽  
pp. 15535-15540 ◽  
Author(s):  
Peng-Fei Cui ◽  
Yue-Jian Lin ◽  
Guo-Xin Jin
Keyword(s):  
Binuclear Complex ◽  
Donor Ligands ◽  
Iridium Complexes ◽  
Insertion Reactions ◽  
Metal Bond ◽  
Metal Metal ◽  
Half Sandwich

The 16-electron complex 2 has been synthesized. It can react with different donor ligands and undergoes M–S bond insertion reactions with DMAD. Complex 2 is shown to react with [Cp*Ir] unit to form a M–M-bound binuclear complex. Interestingly, the metal–metal bond could be broken by HCl to produce the selective B(6)–H activation species.

Unique Oxidative Metal−Metal Bond Formation of Linearly Aligned Tetranuclear Rh−Mo−Mo−Rh Clusters

2004 ◽  
Vol 126 (39) ◽  
pp. 12244-12245 ◽  
Author(s):  
Tobias Rüffer ◽  
Masato Ohashi ◽  
Asuka Shima ◽  
Hitoshi Mizomoto ◽  
Yutaka Kaneda ◽  
...  
Keyword(s):  
Bond Formation ◽  
Metal Bond ◽  
Metal Metal
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