The Molecular Structure of a Diamagnetic, Doubly Oxygen-Bridged, Binuclear Complex of Molybdenum(V) Containing a Metal-Metal Bond

1965 ◽  
Vol 4 (10) ◽  
pp. 1377-1381 ◽  
Author(s):  
F. A. Cotton ◽  
Sheila M. Morehouse
Keyword(s):  
Molecular Structure ◽  
Binuclear Complex ◽  
Metal Bond ◽  
Metal Metal

The synthesis and reactivity of 16-electron half-sandwich iridium complexes bearing a carboranylthioamide ligand

2017 ◽  
Vol 46 (44) ◽  
pp. 15535-15540 ◽  
Author(s):  
Peng-Fei Cui ◽  
Yue-Jian Lin ◽  
Guo-Xin Jin
Keyword(s):  
Binuclear Complex ◽  
Donor Ligands ◽  
Iridium Complexes ◽  
Insertion Reactions ◽  
Metal Bond ◽  
Metal Metal ◽  
Half Sandwich

The 16-electron complex 2 has been synthesized. It can react with different donor ligands and undergoes M–S bond insertion reactions with DMAD. Complex 2 is shown to react with [Cp*Ir] unit to form a M–M-bound binuclear complex. Interestingly, the metal–metal bond could be broken by HCl to produce the selective B(6)–H activation species.

Synthesis and molecular structure of niobocene(tricarbonyl)(π-cyclopentadienyl)molybdenum with metalmetal bond and unusual coordination of carbonyl groups

1979 ◽  
Vol 165 (1) ◽  
pp. 49-56 ◽  
Author(s):  
A.A. Pasynskii ◽  
Yu.V. Skripkin ◽  
I.L. Eremenko ◽  
V.T. Kalinnikov ◽  
G.G. Aleksandrov ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Carbonyl Groups ◽  
Metal Bond ◽  
Metal Metal

Antiferromagnetic complexes with the metal-metal bond XXVIII. Synthesis and molecular structure of the antiferromagnetic cluster [CpCr(μ-SCMe3)]2(μ4-S) [PtMe3(μ-I)]2

1997 ◽  
Vol 536-537 ◽  
pp. 433-436 ◽  
Author(s):  
A.A. Pasynskii ◽  
Y.V. Torubaev ◽  
S.E. Nefedov ◽  
I.L. Eremenko ◽  
O.G. Ellert ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Metal Bond ◽  
Metal Metal
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