Bioinspired design of a hybrid bifunctional enzymatic/organic electrocatalyst for site selective alcohol oxidation

2018 ◽  
Vol 54 (5) ◽  
pp. 491-494 ◽  
Author(s):  
Louis Lancaster ◽  
David P. Hickey ◽  
Matthew S. Sigman ◽  
Shelley D. Minteer ◽  
Ian Wheeldon
Keyword(s):  
Alcohol Oxidation ◽  
Bifunctional Catalyst ◽  
Secondary Alcohols ◽  
Bioinspired Design ◽  
Site Selective

TEMPO and AdhD were chemically conjugated into a bifunctional catalyst that selectively oxidizes primary and secondary alcohols.

An NAD+-type earth-abundant metal complex enabling photo-driven alcohol oxidation

2021 ◽  
Author(s):  
Hideki Ohtsu ◽  
Mikio Takaoka ◽  
Yosuke Tezuka ◽  
Kiyoshi Tsuge ◽  
Koji Tanaka
Keyword(s):  
Metal Complex ◽  
Alcohol Oxidation ◽  
Secondary Alcohols ◽  
Earth Abundant

The first NAD+-type earth-abundant metal complex [Zn(pbn)2(H2O)](ClO4)2 (1) was found to exhibit the photo-induced oxidizing ability for various primary and secondary alcohols to convert the corresponding aldehyde and ketone compounds....

scholarly journals Catalytic Performance of a Magnetic Core-Shell Iron(II) C-Scorpionate under Unconventional Oxidation Conditions

Nanomaterials ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 2111
Author(s):  
Inês A. S. Matias ◽  
Ana P. C. Ribeiro ◽  
Ana M. Ferraria ◽  
Ana M. Botelho do Rego ◽  
Luísa M. D. R. S. Martins
Keyword(s):  
Alternative Energy ◽  
Alcohol Oxidation ◽  
Catalytic Performance ◽  
Magnetic Core ◽  
Core Shell ◽  
Secondary Alcohols ◽  
Alternative Energy Sources ◽  
Metallic Complex ◽  
Shell Particles ◽  
First Time

For the first time, herein is reported the use of a magnetic core-shell support for a C-scorpionate metallic complex. The prepared hybrid material, that consists on the C-scorpionate iron(II) complex [FeCl2{κ3-HC(pz)3}] (pz, pyrazolyl) immobilized at magnetic core-shell particles (Fe3O4/TiO2), was tested as catalyst for the oxidation of secondary alcohols using the model substrate 1-phenylethanol. Moreover, the application of alternative energy sources (e.g., ultrasounds, microwaves, mechanical or thermal) for the peroxidative alcohol oxidation using the magnetic heterogenized iron(II) scorpionate led to different/unusual outcomes that are presented and discussed.

Studies on transition-metal nitrido and oxo complexes. Part 20. Oxoruthenates and oxo-osmates in oxidation catalysis; cis-[Os(OH)2O4]2- as a catalytic oxidant for primary amines and for alcohols

2001 ◽  
Vol 79 (5-6) ◽  
pp. 598-606 ◽  
Author(s):  
William P Griffith ◽  
Maria Suriaatmaja
Keyword(s):  
Raman Spectroscopy ◽  
Transition Metal ◽  
Carboxylic Acids ◽  
Oxidative Dehydrogenation ◽  
Alcohol Oxidation ◽  
Oxidation Catalysis ◽  
Primary Amines ◽  
Secondary Alcohols ◽  
Primary Alcohols ◽  
Aromatic And Aliphatic Amines

cis-[Os(OH)2O4]2– with [Fe(CN)6]3– and other co-oxidants has been studied as a catalytic reagent for the oxidative dehydrogenation of primary aromatic and aliphatic amines to nitriles, the oxidation of primary alcohols to carboxylic acids and of secondary alcohols to ketones. Electronic and Raman spectroscopy have been used to elucidate the nature of the oxoruthenates and oxo-osmates present in a number of reported organic oxidations catalyzed by ruthenium and osmium species.Key words: oxidation catalysis, ruthenium, osmium, amine dehydrogenation, alcohol oxidation.

N,O-ligated Pd(ii) complexes for catalytic alcohol oxidation

2014 ◽  
Vol 4 (8) ◽  
pp. 2526-2534 ◽  
Author(s):  
Laura M. Dornan ◽  
Gráinne M. A. Clendenning ◽  
Mateusz B. Pitak ◽  
Simon J. Coles ◽  
Mark J. Muldoon
Keyword(s):  
Crystal Structure ◽  
Sulfonic Acid ◽  
Active Catalyst ◽  
Alcohol Oxidation ◽  
Secondary Alcohols ◽  
Reaction Conditions ◽  
Highly Active

The (HSA)Pd(OAc)2 complex (where HSA = 8-hydroxyquinoline-2-sulfonic acid) is a highly active catalyst for the oxidation of a range of secondary alcohols in 4–6 hours at a low loading of 0.5 mol%. The crystal structure has been obtained and the influence of reaction conditions on catalyst degradation was also examined.

scholarly journals A novel modified MIL-101-NH2 ligand for CuI-catalyzed and air promoted oxidation of secondary alcohols

RSC Advances ◽  
2017 ◽  
Vol 7 (36) ◽  
pp. 22353-22359 ◽  
Author(s):  
Hui Liu ◽  
Daniele Ramella ◽  
Peng Yu ◽  
Yi Luan
Keyword(s):  
Room Temperature ◽  
Alcohol Oxidation ◽  
Secondary Alcohols ◽  
Oxidation System

An efficient Cu(i)/MOF ligand catalyzed aerobic alcohol oxidation system was developed utilizing the ligand at room temperature.

scholarly journals Recent Advances in Copper Catalyzed Alcohol Oxidation in Homogeneous Medium

Molecules ◽  
2020 ◽  
Vol 25 (3) ◽  
pp. 748 ◽  
Author(s):  
Telma F. S. Silva ◽  
Luísa M. D. R. S. Martins
Keyword(s):  
Organic Synthesis ◽  
Alternative Energy ◽  
Copper Complexes ◽  
Homogeneous Medium ◽  
Alcohol Oxidation ◽  
Short Review ◽  
Secondary Alcohols ◽  
Alternative Energy Source ◽  
Use Of Resources ◽  
Oxidation Of Alcohols

The development of sustainable processes and products through innovative catalytic materials and procedures that allow a better use of resources is undoubtedly one of the most significant issues facing researchers nowadays. Environmental and economically advanced catalytic processes for selective oxidation of alcohols are currently focused on designing new catalysts able to activate green oxidants (dioxygen or peroxides) and applying unconventional conditions of sustainable significance, like the use of microwave irradiation as an alternative energy source. This short review aims to provide an overview of the recently (2015–2020) discovered homogeneous aerobic and peroxidative oxidations of primary and secondary alcohols catalyzed by copper complexes, highlighting new catalysts with potential application in sustainable organic synthesis, with significance in academia and industry.

scholarly journals High-Affinity-Assisted Nanoscale Alloys as Remarkable Bifunctional Catalyst for Alcohol Oxidation and Oxygen Reduction Reactions

ACS Nano ◽  
2017 ◽  
Vol 11 (8) ◽  
pp. 7729-7735 ◽  
Author(s):  
Jitendra N. Tiwari ◽  
Wang Geun Lee ◽  
Siraj Sultan ◽  
Muhammad Yousuf ◽  
Ahmad M. Harzandi ◽  
...  
Keyword(s):  
Oxygen Reduction ◽  
Alcohol Oxidation ◽  
Bifunctional Catalyst ◽  
Reduction Reactions ◽  
Oxygen Reduction Reactions ◽  
High Affinity

Copper(i)/ketoABNO catalysed aerobic alcohol oxidation

2014 ◽  
Vol 4 (6) ◽  
pp. 1720-1725 ◽  
Author(s):  
Luke Rogan ◽  
N. Louise Hughes ◽  
Qun Cao ◽  
Laura M. Dornan ◽  
Mark J. Muldoon
Keyword(s):  
Alcohol Oxidation ◽  
Catalyst System ◽  
Secondary Alcohols ◽  
Gas Composition ◽  
Solid Supports ◽  
Highly Effective

A copper(i)/ketoABNO aerobic catalyst system is highly effective for the oxidation of secondary alcohols, including unactivated aliphatic substrates. The effects of pressure and gas composition on catalyst performance are examined. The radical can be employed at low loadings and it is also amenable to immobilisation on to solid supports.

Chemical and Electrochemical Heteroepitaxial Growth of Chalcogenide Semiconductors from Solutions

1996 ◽  
Vol 451 ◽  
Author(s):  
D. Lincot ◽  
M. J. Furlong ◽  
M. Froment ◽  
R. Cortes ◽  
M. C. Bernard
Keyword(s):  
Heteroepitaxial Growth ◽  
X Ray Diffraction ◽  
Basic Principles ◽  
Lattice Match ◽  
X Ray ◽  
Chalcogenide Semiconductors ◽  
Influence Of Temperature On ◽  
Deposition Processes ◽  
A Site ◽  
Site Selective

ABSTRACTChalcogenide semiconductors have been deposited epitaxially from aqueous solutions either chemically or electrochemically at growth rates of up to 0.7 μmhr−1. After recalling the basic principles of these deposition processes, results are presented concerning chemically deposited CdS on InP, GaP and CuInSe2 substrates, electrodeposited CdTe on InP, and CdSAnP heterostructures. Characterisation of these structures by RHEED, TEM, HRTEM, and glazing angle X ray diffraction allows to analyse the effects of substrate orientation, polarity, lattice match plus the influence of temperature on epitaxial growth. These results are discussed in terms of self organisation and a site selective growth mechanisms due to the free enegy of formation of each compound.

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