scholarly journals A novel modified MIL-101-NH2 ligand for CuI-catalyzed and air promoted oxidation of secondary alcohols

RSC Advances ◽  
2017 ◽  
Vol 7 (36) ◽  
pp. 22353-22359 ◽  
Author(s):  
Hui Liu ◽  
Daniele Ramella ◽  
Peng Yu ◽  
Yi Luan
Keyword(s):  
Room Temperature ◽  
Alcohol Oxidation ◽  
Secondary Alcohols ◽  
Oxidation System

An efficient Cu(i)/MOF ligand catalyzed aerobic alcohol oxidation system was developed utilizing the ligand at room temperature.

An NAD+-type earth-abundant metal complex enabling photo-driven alcohol oxidation

2021 ◽  
Author(s):  
Hideki Ohtsu ◽  
Mikio Takaoka ◽  
Yosuke Tezuka ◽  
Kiyoshi Tsuge ◽  
Koji Tanaka
Keyword(s):  
Metal Complex ◽  
Alcohol Oxidation ◽  
Secondary Alcohols ◽  
Earth Abundant

The first NAD+-type earth-abundant metal complex [Zn(pbn)2(H2O)](ClO4)2 (1) was found to exhibit the photo-induced oxidizing ability for various primary and secondary alcohols to convert the corresponding aldehyde and ketone compounds....

scholarly journals Catalytic Performance of a Magnetic Core-Shell Iron(II) C-Scorpionate under Unconventional Oxidation Conditions

Nanomaterials ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 2111
Author(s):  
Inês A. S. Matias ◽  
Ana P. C. Ribeiro ◽  
Ana M. Ferraria ◽  
Ana M. Botelho do Rego ◽  
Luísa M. D. R. S. Martins
Keyword(s):  
Alternative Energy ◽  
Alcohol Oxidation ◽  
Catalytic Performance ◽  
Magnetic Core ◽  
Core Shell ◽  
Secondary Alcohols ◽  
Alternative Energy Sources ◽  
Metallic Complex ◽  
Shell Particles ◽  
First Time

For the first time, herein is reported the use of a magnetic core-shell support for a C-scorpionate metallic complex. The prepared hybrid material, that consists on the C-scorpionate iron(II) complex [FeCl2{κ3-HC(pz)3}] (pz, pyrazolyl) immobilized at magnetic core-shell particles (Fe3O4/TiO2), was tested as catalyst for the oxidation of secondary alcohols using the model substrate 1-phenylethanol. Moreover, the application of alternative energy sources (e.g., ultrasounds, microwaves, mechanical or thermal) for the peroxidative alcohol oxidation using the magnetic heterogenized iron(II) scorpionate led to different/unusual outcomes that are presented and discussed.

AIBN/NaBr-promoted aerobic oxidation of benzylic alcohols via a radical process

2016 ◽  
Vol 14 (2) ◽  
pp. 577-581 ◽  
Author(s):  
Chengkou Liu ◽  
Zheng Fang ◽  
Zhao Yang ◽  
Qingwen Li ◽  
Shiyu Guo ◽  
...  
Keyword(s):  
Aerobic Oxidation ◽  
Alcohol Oxidation ◽  
Radical Mechanism ◽  
Radical Process ◽  
Benzylic Alcohols ◽  
First Time ◽  
Oxidation System

A new aerobic alcohol oxidation system of AIBN/NaBr was described for the first time. Moreover, a radical mechanism was assumed and confirmed.

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