A reaction-based fluorescent turn-on probe for Cu2+ in complete aqueous solution

RSC Advances ◽  
2016 ◽  
Vol 6 (90) ◽  
pp. 87110-87114 ◽  
Author(s):  
Dongjian Zhu ◽  
Yanghe Luo ◽  
Xiaowei Yan ◽  
Wei Xie ◽  
Wen Cai ◽  
...  

FP can detect Cu2+ in complete aqueous solution with a rapid response time, high sensitivity, and high selectivity.

2013 ◽  
Vol 295-298 ◽  
pp. 475-478 ◽  
Author(s):  
Zhi Xiang Han ◽  
Ming Hui Du ◽  
Guo Xi Liang ◽  
Xiang Yang Wu

Rhodamine B thiohydrazide (RBS) was firstly employed as turn-on fluorescent probe for hypochlorite in aqueous solution and living cells. It exhibits a stable response to hypochlorite from 1.0×10-6to 1.0×10-5M with a detection limit of 3.3×10-7M. The response of this probe to hypochlorite is fast and highly selective compared with other reactive oxygen species (such as.OH,1O2, H2O2) and other common anions (such as X-, ClO2-, ClO4-, NO3-, NO2-, OH-, Ac-, CO32-, SO42-).


2016 ◽  
Vol 40 (3) ◽  
pp. 1930-1934 ◽  
Author(s):  
M. Raju ◽  
Tapasya J. Patel ◽  
Ratish R. Nair ◽  
Pabitra B. Chatterjee

Synopsis: A well-known tryptophan metabolite, xanthurenic acid, a natural non-fluorescent intermediate siderophore, showed a very selective turn-on response to K+ over other competing metal ions and the detection limit of this natural ionophore was found to be 53 nM at physiological pH.


2019 ◽  
Vol 11 (2) ◽  
pp. 232-235 ◽  
Author(s):  
Na Jiang ◽  
Bin Wang ◽  
Tao Liu ◽  
Qingyu Liu ◽  
Qin Wei ◽  
...  

A hemicyanine-based fluorescent dye, Mito-BT, was developed to ratiometrically detect H2S. This dye was of high selectivity, photostability and sensitivity with a rapid response time of 10 seconds. In addition, Mito-BT was localized in mitochondria, making it a promising probe for detecting H2S in cells.


2014 ◽  
Vol 881-883 ◽  
pp. 1079-1082 ◽  
Author(s):  
Gao Zhang Gou ◽  
He Ping Yan ◽  
Shi Juan Xu ◽  
Na Wu ◽  
Bo Zhou ◽  
...  

A 1,8-naphthyridine modified rhodamine B derivative, one Cu2+-selective chemosensors was designed, synthesized and characterized, which display a high selectivity for Cu2+among environmentally and biologically relevant metal ions. It can detect Cu2+in aqueous solution selectively with a dramatic colour change from colorless to magenta. The detection mechanism involves a ring-opening process as a consequence of metal complex formation. Jobs plots study indicated that the chemosensor chelated Cu2+with 2:1 stoichiometry.


2014 ◽  
Vol 50 (63) ◽  
pp. 8640-8643 ◽  
Author(s):  
Ji-Ting Hou ◽  
Ming-Yu Wu ◽  
Kun Li ◽  
Jin Yang ◽  
Kang-Kang Yu ◽  
...  

Two probes that exhibited high sensitivity and excellent selectivity toward ClO−among ROS with a rapid response time were presented, which could selectively detect ClO−in the mitochondria of the cells.


RSC Advances ◽  
2016 ◽  
Vol 6 (89) ◽  
pp. 85787-85794 ◽  
Author(s):  
Xiao-Lin Lu ◽  
Min Xia

A novel V-shaped probe is reported with extremely rapid response, high selectivity and very low detection limit to cyanide anions in aqueous solution based on the intensely emissive aggregates of the probe adduct.


2019 ◽  
Vol 9 (3) ◽  
pp. 577 ◽  
Author(s):  
Zhi-Yan Gao ◽  
Cui-Jiao Zhang ◽  
Xian Zhang ◽  
Shu Xing ◽  
Jin-Shui Yao ◽  
...  

An excess of Al3+ will lead to biological disorders and even many diseases. Therefore, detecting the levels of Al3+ in the human body has drawn great attention for health monitoring. The fluorescence method has been broadly applied because of high sensitivity, real-time detection, and intracellular imaging. In this work, a new probe with “turn-on” fluorescence based on Schiff base derivative, 3,6-imine-triphenylamine-(9-ethyl) carbazole (ITEC), has been successfully synthesized and studied. The high selectivity and sensitivity of ITEC to Al3+ were verified by fluorescence spectra and the detection limit was 2.19 nmol/L. A 1:2 stoichiometry of ITEC-Al3+ was obtained by the 1H NMR spectra and Job’s plot. Furthermore, ITEC was successfully applied to the detection of Al3+ with different concentrations in living HeLa cells. The analog experiments about nature contamination of Al3+ in cells and real samples were finished.


2020 ◽  
Vol 44 (5-6) ◽  
pp. 349-353
Author(s):  
Xue-Tao Pan ◽  
Qiao Li ◽  
Yuan-Yuan Xu ◽  
Sheng-Li Hu

A new 3-hydroxyphthalimide-based turn-on fluorescent probe is designed and synthesized. This probe can be used to determine the presence of Hg2+ ions by fluorescence spectroscope with high selectivity over other metal ions in aqueous solution. The analytical detection limit for Hg2+ is as low as 6.5 × 10−7 M. The recognition mechanism is attributed to Hg2+-promoted carbonothioate group cleavage and a subsequent excited-state intramolecular proton transfer mechanisms.


2016 ◽  
Vol 14 (15) ◽  
pp. 3690-3694 ◽  
Author(s):  
Sharad Kumar Asthana ◽  
Ajit Kumar ◽  
Neeraj Neeraj ◽  
Shweta Shweta ◽  
K. K. Upadhyay

A meticulous design strategy of incorporating three electrophilic centres in an optical probe (FLA) led to the achievement of high sensitivity and rapid response time (40 s) towards H2S detection.


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