scholarly journals Chemical bonding states and solar selective characteristics of unbalanced magnetron sputtered TixM1−x−yNy films

RSC Advances ◽  
2016 ◽  
Vol 6 (43) ◽  
pp. 36373-36383 ◽  
Author(s):  
M. Mahbubur Rahman ◽  
Zhong-Tao Jiang ◽  
Paul Munroe ◽  
Lee Siang Chuah ◽  
Zhi-feng Zhou ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Thin Films ◽  
Transition Metal ◽  
Mechanical Strength ◽  
Chemical Bonding ◽  
Metal Nitride ◽  
Bonding State ◽  
Transition Metal Nitride ◽  
Unbalanced Magnetron ◽  
Chemical Bonding State

Transition metal nitride TixM1−x−yNy (M = Al or AlSi) based thin films are evaluated as solar selective surfaces by correlating their spectral selective features with their crystal structure and chemical bonding state including mechanical strength.

scholarly journals Transition-metal-nitride-based thin films as novel energy harvesting materials

2016 ◽  
Vol 4 (18) ◽  
pp. 3905-3914 ◽  
Author(s):  
Per Eklund ◽  
Sit Kerdsongpanya ◽  
Björn Alling
Keyword(s):  
Thin Films ◽  
Energy Harvesting ◽  
Transition Metal ◽  
Theoretical Research ◽  
Metal Nitride ◽  
Transition Metal Nitride

We review experimental and theoretical research on ScN- and CrN-based transition-metal nitride materials for thermoelectrics, drawing parallels with piezoelectricity.

The Spray Deposition of Transition Metal Nitride thin Films Using Alcohol Based Precursor Solutions

1997 ◽  
Vol 495 ◽  
Author(s):  
K. S. Weil ◽  
P. N. Kumta
Keyword(s):  
Thin Films ◽  
Transition Metal ◽  
Spray Deposition ◽  
Silicon Substrates ◽  
Metal Nitride ◽  
Transition Metal Nitride ◽  
Solvent Phase ◽  
Heat Treated ◽  
Viscous Solution ◽  
Electrical Components

ABSTRACTA new alcohol solution based approach has been developed for preparing transition metal nitride thin films and coatings. In this technique, the metal of interest is dissolved as a chloride in acetonitrile, then chelated with triethanolamine to form a highly viscous solution which settles out of the solvent phase. The acetonitrile is then evaporated off and the remaining thick liquid precursor is easily diluted with water or methanol, yielding a semi-viscous liquid which can be used directly to coat various substrates. When heat treated under the appropriate conditions in ammonia, the precursor coating transforms to yield the corresponding nitride. This approach is currently being considered for preparing nitride-based thin film electrical components and has been successfully used thus far to spray deposit TaN and NbN nitride films onto silicon substrates. Results of the preliminary study on these two nitride films are discussed in this paper.

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