Catalyst-free iodine-mediated living radical polymerization under irradiation over a wide visible-light spectral scope

2016 ◽  
Vol 7 (21) ◽  
pp. 3576-3588 ◽  
Author(s):  
Xiaodong Liu ◽  
Lifen Zhang ◽  
Zhenping Cheng ◽  
Xiulin Zhu
Keyword(s):  
Visible Light ◽  
Radical Polymerization ◽  
Living Radical Polymerization ◽  
Led Light ◽  
Catalyst Free ◽  
Wide Range ◽  
Free Iodine ◽  
Methyl Methacrylates

Catalyst-free iodine-mediated photo-induced solution LRP of methyl methacrylates under LED light was successfully established over a wide range of irradiation wavelengths (390–630 nm).

Straightforward catalyst/solvent-free iodine-mediated living radical polymerization of functional monomers driven by visible light irradiation

2016 ◽  
Vol 52 (72) ◽  
pp. 10850-10853 ◽  
Author(s):  
Xiaodong Liu ◽  
Lifen Zhang ◽  
Zhenping Cheng ◽  
Xiulin Zhu
Keyword(s):  
Visible Light ◽  
Radical Polymerization ◽  
Visible Light Irradiation ◽  
Living Radical Polymerization ◽  
Solvent Free ◽  
Light Irradiation ◽  
Efficient Catalyst ◽  
Functional Monomers ◽  
Polymerization System ◽  
Free Iodine

A simple and highly efficient catalyst/solvent-free iodine-mediated polymerization system for functional monomers (DMAEMA, PEGMA and GMA) was successfully developed under irradiation of visible light or sunlight.

Visible-light-induced living radical polymerization using in situ bromine-iodine transformation as an internal boost

2017 ◽  
Vol 8 (16) ◽  
pp. 2538-2551 ◽  
Author(s):  
Xiaodong Liu ◽  
Qinghua Xu ◽  
Lifen Zhang ◽  
Zhenping Cheng ◽  
Xiulin Zhu
Keyword(s):  
Visible Light ◽  
Radical Polymerization ◽  
Living Radical Polymerization

A new visible-light-induced methodology, termed as “bromine-iodine transformation activated living radical polymerization”, was successfully established to build a “bridge” between ATRP and iodine-mediated LRP techniques.

scholarly journals A well-defined, versatile photoinitiator (salen)Co–CO2CH3 for visible light-initiated living/controlled radical polymerization

2015 ◽  
Vol 6 (5) ◽  
pp. 2979-2988 ◽  
Author(s):  
Yaguang Zhao ◽  
Mengmeng Yu ◽  
Shuailin Zhang ◽  
Zhenqiang Wu ◽  
Yuchu Liu ◽  
...  
Keyword(s):  
Visible Light ◽  
Radical Polymerization ◽  
Living Radical Polymerization ◽  
Controlled Radical Polymerization ◽  
Salen Complex ◽  
Living Controlled Radical Polymerization

A well-defined organocobalt salen complex (salen)Co–CO2CH3 is used as a versatile photoinitiator for visible light-initiated living radical polymerization.

Visible-Light-Induced Living Radical Polymerization (LRP) Mediated by (salen)Co(II)/TPO at Ambient Temperature

2015 ◽  
Vol 48 (15) ◽  
pp. 5132-5139 ◽  
Author(s):  
Yaguang Zhao ◽  
Shuailin Zhang ◽  
Zhenqiang Wu ◽  
Xu Liu ◽  
Xianyuan Zhao ◽  
...  
Keyword(s):  
Visible Light ◽  
Ambient Temperature ◽  
Radical Polymerization ◽  
Living Radical Polymerization

Visible-Light-Regulated Controlled/Living Radical Polymerization in Miniemulsion

2015 ◽  
Vol 4 (10) ◽  
pp. 1139-1143 ◽  
Author(s):  
Kenward Jung ◽  
Jiangtao Xu ◽  
Per B. Zetterlund ◽  
Cyrille Boyer
Keyword(s):  
Visible Light ◽  
Radical Polymerization ◽  
Living Radical Polymerization ◽  
Controlled Living Radical Polymerization

Facile and universal photo-induced living radical polymerization system mediated by iniferter agent and copper(ii) acetate at ambient temperature

RSC Advances ◽  
2015 ◽  
Vol 5 (40) ◽  
pp. 31657-31663 ◽  
Author(s):  
Liangfang Fan ◽  
Hongjuan Jiang ◽  
Lifen Zhang ◽  
Zhenping Cheng ◽  
Xiulin Zhu
Keyword(s):  
Ambient Temperature ◽  
Radical Polymerization ◽  
Uv Irradiation ◽  
Living Radical Polymerization ◽  
Wide Range ◽  
Polymerization System ◽  
Organic Catalyst

A facile and universal photo-induced living radical polymerization with a wide range of monomers was developed in the presence of iniferter agent MANDC and organic catalyst copper(ii) acetate under UV irradiation at ambient temperature.

When CMRP met alkyl vinyl ketone: visible light induced living radical polymerization (LRP) of ethyl vinyl ketone (EVK)

2016 ◽  
Vol 52 (81) ◽  
pp. 12092-12095 ◽  
Author(s):  
Yaguang Zhao ◽  
Xu Liu ◽  
Yuchu Liu ◽  
Zhenqiang Wu ◽  
Xianyuan Zhao ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Visible Light ◽  
Radical Polymerization ◽  
Living Radical Polymerization ◽  
Vinyl Ketone ◽  
Ethyl Vinyl

Photo responsive polyethyl vinyl ketone (PEVK) and various block copolymers were prepared through the visible light induced cobalt mediated radical polymerization (CMRP) process.

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