When CMRP met alkyl vinyl ketone: visible light induced living radical polymerization (LRP) of ethyl vinyl ketone (EVK)

2016 ◽  
Vol 52 (81) ◽  
pp. 12092-12095 ◽  
Author(s):  
Yaguang Zhao ◽  
Xu Liu ◽  
Yuchu Liu ◽  
Zhenqiang Wu ◽  
Xianyuan Zhao ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Visible Light ◽  
Radical Polymerization ◽  
Living Radical Polymerization ◽  
Vinyl Ketone ◽  
Ethyl Vinyl

Photo responsive polyethyl vinyl ketone (PEVK) and various block copolymers were prepared through the visible light induced cobalt mediated radical polymerization (CMRP) process.

Visible-light-induced living radical polymerization using in situ bromine-iodine transformation as an internal boost

2017 ◽  
Vol 8 (16) ◽  
pp. 2538-2551 ◽  
Author(s):  
Xiaodong Liu ◽  
Qinghua Xu ◽  
Lifen Zhang ◽  
Zhenping Cheng ◽  
Xiulin Zhu
Keyword(s):  
Visible Light ◽  
Radical Polymerization ◽  
Living Radical Polymerization

A new visible-light-induced methodology, termed as “bromine-iodine transformation activated living radical polymerization”, was successfully established to build a “bridge” between ATRP and iodine-mediated LRP techniques.

scholarly journals A well-defined, versatile photoinitiator (salen)Co–CO2CH3 for visible light-initiated living/controlled radical polymerization

2015 ◽  
Vol 6 (5) ◽  
pp. 2979-2988 ◽  
Author(s):  
Yaguang Zhao ◽  
Mengmeng Yu ◽  
Shuailin Zhang ◽  
Zhenqiang Wu ◽  
Yuchu Liu ◽  
...  
Keyword(s):  
Visible Light ◽  
Radical Polymerization ◽  
Living Radical Polymerization ◽  
Controlled Radical Polymerization ◽  
Salen Complex ◽  
Living Controlled Radical Polymerization

A well-defined organocobalt salen complex (salen)Co–CO2CH3 is used as a versatile photoinitiator for visible light-initiated living radical polymerization.

Synthesis of amphiphilic nanoparticles and multi-block hydrophilic copolymers by a facile and effective “living” radical polymerization in water

2016 ◽  
Vol 7 (14) ◽  
pp. 2486-2491 ◽  
Author(s):  
Juanjuan Wu ◽  
Hongjuan Jiang ◽  
Lifen Zhang ◽  
Zhenping Cheng ◽  
Xiulin Zhu
Keyword(s):  
Block Copolymers ◽  
Radical Polymerization ◽  
Living Radical Polymerization ◽  
Robust Approach ◽  
Amphiphilic Nanoparticles

A convenient and robust approach using MANDC-COOH as the initiator and oxidatively stable Cu(OAc)2as the catalyst to synthesize amphiphilic nanoparticles and hydrophilic multi-block copolymers was successfully developed in water.

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