An aerobic Cu-mediated practical approach to aromatic nitriles using cyanide anions as the nitrogen source

2016 ◽  
Vol 14 (28) ◽  
pp. 6687-6690 ◽  
Author(s):  
Lijun Gu ◽  
Cheng Jin ◽  
Hongtao Zhang ◽  
Jiyan Liu ◽  
Ganpeng Li Ganpeng Li ◽  
...  
Keyword(s):  
Nitrogen Source ◽  
Practical Approach ◽  
Methyl Ketones ◽  
Aromatic Nitriles ◽  
Aryl Methyl

A copper-catalyzed cyanation of aryl methyl ketones using cyanide anions as the nitrogen source was developed. The reaction showed a broad substrate scope with moderate to excellent yields.

ChemInform Abstract: An Aerobic Cu-Mediated Practical Approach to Aromatic Nitriles Using Cyanide Anions as the Nitrogen Source.

ChemInform ◽  
2016 ◽  
Vol 47 (47) ◽  
Author(s):  
Lijun Gu ◽  
Cheng Jin ◽  
Hongtao Zhang ◽  
Jiyan Liu ◽  
Ganpeng Li Ganpeng Li ◽  
...  
Keyword(s):  
Nitrogen Source ◽  
Practical Approach ◽  
Aromatic Nitriles

Employing thiocyanate salts as a nitrogen source via CN bond cleavage: divergent synthesis of α-ketoamides and 2-acyloxazoles

2019 ◽  
Vol 6 (14) ◽  
pp. 2534-2538 ◽  
Author(s):  
Can Wang ◽  
Xiao Geng ◽  
Peng Zhao ◽  
You Zhou ◽  
Yan-Dong Wu ◽  
...  
Keyword(s):  
Nitrogen Source ◽  
Bond Cleavage ◽  
Methyl Ketones ◽  
Aryl Methyl

A switchable procedure for the synthesis of α-ketoamides and 2-acyloxazoles from aryl methyl ketones and thiocyanate salts is reported.

Direct Conversion of Benzyl Ethers into Aryl Nitriles

Synlett ◽  
2018 ◽  
Vol 29 (18) ◽  
pp. 2444-2448 ◽  
Author(s):  
Yun-Lai Ren ◽  
Jianji Wang ◽  
Xinzhe Tian ◽  
Fangping Ren ◽  
Xinqiang Cheng ◽  
...  
Keyword(s):  
Nitrogen Source ◽  
Direct Method ◽  
Direct Conversion ◽  
Aromatic Nitriles ◽  
Organic Syntheses ◽  
Aryl Nitriles ◽  
Benzyl Ethers ◽  
Hydroxy Groups ◽  
A Direct Method

A direct method was developed for the conversion of benzyl ethers into aryl nitriles by using NH4OAc as the nitrogen source and ­oxygen as the terminal oxidant with catalysis by TEMPO/HNO3; the method is valuable for both the synthesis of aromatic nitriles and for the deprotection of ether-protected hydroxy groups to form nitrile groups in multistep organic syntheses.

ChemInform Abstract: A Convenient Conversion of Substituted Cyclohexenones into Aryl Methyl Ketones.

ChemInform ◽  
2012 ◽  
Vol 43 (46) ◽  
pp. no-no
Author(s):  
Andre P. Gehring ◽  
Franz Bracher
Keyword(s):  
Methyl Ketones ◽  
Aryl Methyl

Electrosynthesis of α-keto acetals by a selenium-catalyzed transformation of aryl methyl ketones

1998 ◽  
Vol 43 (3-4) ◽  
pp. 335-339 ◽  
Author(s):  
D.Scott Smith ◽  
Jack Winnick ◽  
Youzhen Ding ◽  
Lawrence A. Bottomley
Keyword(s):  
Methyl Ketones ◽  
Aryl Methyl

ChemInform Abstract: Efficient Synthesis of 3-Aroylcinnolines from Aryl Methyl Ketones.

ChemInform ◽  
2010 ◽  
Vol 32 (27) ◽  
pp. no-no
Author(s):  
Nouria A. Al-Awadi ◽  
Mohamed Hilmy Elnagdi ◽  
Yehia A. Ibrahim ◽  
Kamini Kaul ◽  
Ajith Kumar
Keyword(s):  
Methyl Ketones ◽  
Efficient Synthesis ◽  
Aryl Methyl

Construction of substituted imidazoles from aryl methyl ketones and benzylamines via N-heterocyclic carbene-catalysis

2019 ◽  
Vol 125 ◽  
pp. 26-31 ◽  
Author(s):  
Anitha Alanthadka ◽  
Sankari Devi Elango ◽  
Pavithra Thangavel ◽  
Nagarajan Subbiah ◽  
Sridharan Vellaisamy ◽  
...  
Keyword(s):  
Methyl Ketones ◽  
Aryl Methyl

scholarly journals CuO-catalyzed conversion of arylacetic acids into aromatic nitriles with K4Fe(CN)6 as the nitrogen source

2021 ◽  
Vol 149 ◽  
pp. 106175
Author(s):  
Ai-Ping Xing ◽  
Zhenpeng Shen ◽  
Zhe Zhao ◽  
Xinzhe Tian ◽  
Yun-Lai Ren
Keyword(s):  
Nitrogen Source ◽  
Aromatic Nitriles ◽  
Arylacetic Acids
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