ChemInform Abstract: An Aerobic Cu-Mediated Practical Approach to Aromatic Nitriles Using Cyanide Anions as the Nitrogen Source.

ChemInform ◽  
2016 ◽  
Vol 47 (47) ◽  
Author(s):  
Lijun Gu ◽  
Cheng Jin ◽  
Hongtao Zhang ◽  
Jiyan Liu ◽  
Ganpeng Li Ganpeng Li ◽  
...  
Keyword(s):  
Nitrogen Source ◽  
Practical Approach ◽  
Aromatic Nitriles

An aerobic Cu-mediated practical approach to aromatic nitriles using cyanide anions as the nitrogen source

2016 ◽  
Vol 14 (28) ◽  
pp. 6687-6690 ◽  
Author(s):  
Lijun Gu ◽  
Cheng Jin ◽  
Hongtao Zhang ◽  
Jiyan Liu ◽  
Ganpeng Li Ganpeng Li ◽  
...  
Keyword(s):  
Nitrogen Source ◽  
Practical Approach ◽  
Methyl Ketones ◽  
Aromatic Nitriles ◽  
Aryl Methyl

A copper-catalyzed cyanation of aryl methyl ketones using cyanide anions as the nitrogen source was developed. The reaction showed a broad substrate scope with moderate to excellent yields.

Direct Conversion of Benzyl Ethers into Aryl Nitriles

Synlett ◽  
2018 ◽  
Vol 29 (18) ◽  
pp. 2444-2448 ◽  
Author(s):  
Yun-Lai Ren ◽  
Jianji Wang ◽  
Xinzhe Tian ◽  
Fangping Ren ◽  
Xinqiang Cheng ◽  
...  
Keyword(s):  
Nitrogen Source ◽  
Direct Method ◽  
Direct Conversion ◽  
Aromatic Nitriles ◽  
Organic Syntheses ◽  
Aryl Nitriles ◽  
Benzyl Ethers ◽  
Hydroxy Groups ◽  
A Direct Method

A direct method was developed for the conversion of benzyl ethers into aryl nitriles by using NH4OAc as the nitrogen source and ­oxygen as the terminal oxidant with catalysis by TEMPO/HNO3; the method is valuable for both the synthesis of aromatic nitriles and for the deprotection of ether-protected hydroxy groups to form nitrile groups in multistep organic syntheses.

scholarly journals CuO-catalyzed conversion of arylacetic acids into aromatic nitriles with K4Fe(CN)6 as the nitrogen source

2021 ◽  
Vol 149 ◽  
pp. 106175
Author(s):  
Ai-Ping Xing ◽  
Zhenpeng Shen ◽  
Zhe Zhao ◽  
Xinzhe Tian ◽  
Yun-Lai Ren
Keyword(s):  
Nitrogen Source ◽  
Aromatic Nitriles ◽  
Arylacetic Acids

Iron-Promoted Decarboxylation of Arylacetic Acids for the Synthesis of Aromatic Nitriles with Sodium Nitrite as the Nitrogen Source

Synlett ◽  
2020 ◽  
Vol 31 (18) ◽  
pp. 1805-1808 ◽  
Author(s):  
Zhenpeng Shen ◽  
Wenbo Liu ◽  
Xinzhe Tian ◽  
Yun-Lai Ren ◽  
Zhe Zhao
Keyword(s):  
Nitrogen Source ◽  
Functional Groups ◽  
Sodium Nitrite ◽  
Aromatic Nitriles ◽  
Mild Conditions ◽  
Arylacetic Acids

AbstractA new and effective method was developed for the synthesis of aromatic nitriles from arylacetic acids by using NaNO2 as the nitrogen source and Fe(OTf)3 as the promoter at 50 °C. A series of arylacetic acids underwent this transformation to give the targeted products in yields of 51–90%. Because of the mild conditions, the reaction is compatible with a broad range of functional groups, including ester, carboxy, hydroxy, acetamido, halo, nitro, cyano, methoxy, and even highly reactive formyl groups.

A practical approach to identifying and creating subgroup survey norms

2010 ◽  
Author(s):  
Scott A. Withrow ◽  
William K. Balzer ◽  
Michael T. Sliter ◽  
Purnima Gopalkrishnan ◽  
Michael A. Gillespie ◽  
...  
Keyword(s):  
Practical Approach
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