Employing thiocyanate salts as a nitrogen source via CN bond cleavage: divergent synthesis of α-ketoamides and 2-acyloxazoles

2019 ◽  
Vol 6 (14) ◽  
pp. 2534-2538 ◽  
Author(s):  
Can Wang ◽  
Xiao Geng ◽  
Peng Zhao ◽  
You Zhou ◽  
Yan-Dong Wu ◽  
...  
Keyword(s):  
Nitrogen Source ◽  
Bond Cleavage ◽  
Methyl Ketones ◽  
Aryl Methyl

A switchable procedure for the synthesis of α-ketoamides and 2-acyloxazoles from aryl methyl ketones and thiocyanate salts is reported.

An aerobic Cu-mediated practical approach to aromatic nitriles using cyanide anions as the nitrogen source

2016 ◽  
Vol 14 (28) ◽  
pp. 6687-6690 ◽  
Author(s):  
Lijun Gu ◽  
Cheng Jin ◽  
Hongtao Zhang ◽  
Jiyan Liu ◽  
Ganpeng Li Ganpeng Li ◽  
...  
Keyword(s):  
Nitrogen Source ◽  
Practical Approach ◽  
Methyl Ketones ◽  
Aromatic Nitriles ◽  
Aryl Methyl

A copper-catalyzed cyanation of aryl methyl ketones using cyanide anions as the nitrogen source was developed. The reaction showed a broad substrate scope with moderate to excellent yields.

scholarly journals Innentitelbild: Chemoselective Oxidative C(CO)C(methyl) Bond Cleavage of Methyl Ketones to Aldehydes Catalyzed by CuI with Molecular Oxygen (Angew. Chem. 43/2013)

2013 ◽  
Vol 125 (43) ◽  
pp. 11384-11384
Author(s):  
Lin Zhang ◽  
Xihe Bi ◽  
Xiaoxue Guan ◽  
Xingqi Li ◽  
Qun Liu ◽  
...  
Keyword(s):  
Molecular Oxygen ◽  
Bond Cleavage ◽  
Methyl Ketones

ChemInform Abstract: A Convenient Conversion of Substituted Cyclohexenones into Aryl Methyl Ketones.

ChemInform ◽  
2012 ◽  
Vol 43 (46) ◽  
pp. no-no
Author(s):  
Andre P. Gehring ◽  
Franz Bracher
Keyword(s):  
Methyl Ketones ◽  
Aryl Methyl

Electrosynthesis of α-keto acetals by a selenium-catalyzed transformation of aryl methyl ketones

1998 ◽  
Vol 43 (3-4) ◽  
pp. 335-339 ◽  
Author(s):  
D.Scott Smith ◽  
Jack Winnick ◽  
Youzhen Ding ◽  
Lawrence A. Bottomley
Keyword(s):  
Methyl Ketones ◽  
Aryl Methyl

Direct Annulation of Hydrazides to 1,3,4-Oxadiazoles via Oxidative C(CO)–C(Methyl) Bond Cleavage of Methyl Ketones

2015 ◽  
Vol 17 (12) ◽  
pp. 2960-2963 ◽  
Author(s):  
Qinghe Gao ◽  
Shan Liu ◽  
Xia Wu ◽  
Jingjing Zhang ◽  
Anxin Wu
Keyword(s):  
Bond Cleavage ◽  
Methyl Ketones

ChemInform Abstract: Efficient Synthesis of 3-Aroylcinnolines from Aryl Methyl Ketones.

ChemInform ◽  
2010 ◽  
Vol 32 (27) ◽  
pp. no-no
Author(s):  
Nouria A. Al-Awadi ◽  
Mohamed Hilmy Elnagdi ◽  
Yehia A. Ibrahim ◽  
Kamini Kaul ◽  
Ajith Kumar
Keyword(s):  
Methyl Ketones ◽  
Efficient Synthesis ◽  
Aryl Methyl

ChemInform Abstract: Direct Annulation of Hydrazides to 1,3,4-Oxadiazoles via Oxidative C(CO)-C(Methyl) Bond Cleavage of Methyl Ketones.

ChemInform ◽  
2015 ◽  
Vol 46 (44) ◽  
pp. no-no
Author(s):  
Qinghe Gao ◽  
Shan Liu ◽  
Xia Wu ◽  
Jingjing Zhang ◽  
Anxin Wu
Keyword(s):  
Bond Cleavage ◽  
Methyl Ketones
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