Absorber modeling for NGCC carbon capture with aqueous piperazine

2016 ◽  
Vol 192 ◽  
pp. 459-477 ◽  
Author(s):  
Yue Zhang ◽  
Brice Freeman ◽  
Pingjiao Hao ◽  
Gary T. Rochelle

A hybrid system combining amine scrubbing with membrane technology for carbon capture from natural gas combined cycle (NGCC) power plants is proposed in this paper. In this process, the CO2 in the flue gas can be enriched from 4% to 18% by the membrane, and the amine scrubbing system will have lower capture costs. Aqueous piperazine (PZ) is chosen as the solvent. Different direct contact cooler (DCC) options, multiple absorber operating conditions, optimal intercooling designs, and different cooling options have been evaluated across a wide range of inlet CO2. Amine scrubbing without DCC is a superior design for NGCC carbon capture. Pump-around cooling at the bottom of the absorber can effectively manage the temperature of the hot flue gas, and still be effective for CO2 absorption. The absorber gas inlet must be designed to avoid excessive localized temperature and solvent evaporation. When the inlet CO2 increases from 4% to 18%, total absorber CAPEX decreases by 60%; another 10% of the total absorber CAPEX can be saved by eliminating the DCC. In-and-out intercooling works well for high CO2, while pump-around intercooling is more effective for low CO2. Dry cooling requires more packing and energy but appears to be technically and economically feasible if cooling water availability is limited.

2019 ◽  
Vol 12 (7) ◽  
pp. 2161-2173 ◽  
Author(s):  
Rebecca L. Siegelman ◽  
Phillip J. Milner ◽  
Eugene J. Kim ◽  
Simon C. Weston ◽  
Jeffrey R. Long

As natural gas supplies a growing share of global primary energy, new research efforts are needed to develop adsorbents for carbon capture from gas-fired power plants alongside efforts targeting emissions from coal-fired plants.


Author(s):  
Geoffrey Short ◽  
Addison K. Stark ◽  
Daniel Matuszak ◽  
James F. Klausner

Fresh water withdrawal for thermoelectric power generation in the U.S. is approximately 139 billion gallons per day (BGD), or 41% of total fresh water draw, making it the largest single use of fresh water in the U.S. Of the fresh water withdrawn for the power generation sector, 4.3 BGD is dissipated to the atmosphere by cooling towers and spray ponds. Dry-cooled power plants are attractive and sometimes necessary because they avoid significant withdrawal and consumption of freshwater resources that could otherwise be used for other purposes. This could become even more important when considering the potential effects of climate change (1). Additional benefits of dry-cooling include power plant site flexibility, reduced risk of water scarcity, and faster permitting (reducing project development time and cost). However, dry-cooling systems are known to be more costly and larger than their wet-cooling counterparts. Additionally, without the benefit of additional latent heat transfer through evaporation, the Rankine cycle condensing (cold) temperature for dry-cooling is typically higher than that for wet-cooling, affecting the efficiency of power production and the resultant levelized cost of electricity (LCOE). The Advanced Research Projects Agency - Energy (ARPA-E) has developed a technoeconomic analysis (TEA) model for the development of indirect dry-cooling systems employing steam condensation within a natural gas combined cycle power plant. The TEA model has been used to inform the Advanced Research in Dry-Cooling (ARID) Program on the performance metrics needed to achieve an economical dry-cooling technology. In order to assess the relationship between air-cooled heat exchanger (ACHX) performance, including air side heat transfer coefficient and pressure drop, and power plant economics, ARPA-E has employed a modified version of the National Energy Technology Laboratory (NETL) model of a 550 MW natural gas combined cycle (NGCC) plant employing an evaporative cooling system. The evaporative cooling system, including associated balance of system costs, was replaced with a thermodynamic model for an ACHX with the desired improved heat transfer performance and supplemental cooling and storage systems. Monte Carlo simulation determined an optimal ACHX geometry and associated ACHX cost. Allowing for an increase in LCOE of 5%, the maximum allowable additional cost of the supplemental cooling system was determined as a function of the degree of cooling of the working fluid required. This paper describes the methodologies employed in the TEA, details the results, and includes related models as supplemental material, while providing insight on how the open source tool might be used for thermal management innovation.


Author(s):  
Maria Elena Diego ◽  
Jean-Michel Bellas ◽  
Mohamed Pourkashanian

Post-combustion CO2 capture from natural gas combined cycle (NGCC) power plants is challenging due to the large flow of flue gas with low CO2 content (∼3–4%vol.) that needs to be processed in the capture stage. A number of alternatives have been proposed to solve this issue and reduce the costs of the associated CO2 capture plant. This work focuses on the selective exhaust gas recirculation (S-EGR) configuration, which uses a membrane to selectively recirculate CO2 back to the inlet of the compressor of the turbine, thereby greatly increasing the CO2 content of the flue gas sent to the capture system. For this purpose, a parallel S-EGR NGCC system (53% S-EGR ratio) coupled to an amine capture plant using MEA 30%wt. was simulated using gCCS (gPROMS). It was benchmarked against an unabated NGCC system, a conventional NGCC coupled with an amine capture plant (NGCC+CCS), and an EGR NGCC power plant (39% EGR ratio) using amine scrubbing as the downstream capture technology. The results obtained indicate that the net power efficiency of the parallel S-EGR system can be up to 49.3% depending on the specific consumption of the auxiliary S-EGR systems, compared to the 49.0% and 49.8% values obtained for the NGCC+CCS and EGR systems, respectively. A preliminary economic study was also carried out to quantify the potential of the parallel S-EGR configuration. This high-level analysis shows that the cost of electricity for the parallel S-EGR system varies from 82.1–90.0 $/MWhe for the scenarios considered, with the cost of CO2 avoided being in the range of 79.7–105.1 $/tonne CO2. The results obtained indicate that there are potential advantages of the parallel S-EGR system in comparison to the NGCC+CCS configuration in some scenarios. However, further benefits with respect to the EGR configuration will depend on future advancements and cost reductions achieved on membrane-based systems.


Author(s):  
Ondrej Novak ◽  
Marek Bobcik ◽  
Martin Luxa ◽  
Jaroslav Fort ◽  
Bartolomej Rudas ◽  
...  

Recent trends in the electric energy market such as biomass, waste incineration or combined cycle power plants require innovative solutions in steam turbine design. Variable operating conditions cause significant changes in flow field surrounding the steam turbine last stage blades. Therefore, the enlargement of operating range for last stage blades presents new challenges in design of turbine cascades. Several turbine cascades were designed and analyzed by commercial and in-house software of CTU Prague. Selected profiles were experimentally validated in the high-speed wind tunnel for 2D cascade measurements of the Institute of Thermomechanics of the Czech Academy of Sciences which is equipped by an adjustable supersonic inlet nozzle, perforated inserts at side walls and adjustable perforated tailboard. Comparisons are presented of numerical results with optical and pneumatic measurements for a wide range of inlet and outlet Mach numbers for optimized hub and tip profile cascades.


2020 ◽  
Vol 13 (1) ◽  
pp. 72
Author(s):  
Saman Hasan ◽  
Abubakar Jibrin Abbas ◽  
Ghasem Ghavami Nasr

Environmental concern for our planet has changed significantly over time due to climate change, caused by an increasing population and the subsequent demand for electricity, and thus increased power generation. Considering that natural gas is regarded as a promising fuel for such a purpose, the need to integrate carbon capture technologies in such plants is becoming a necessity, if gas power plants are to be aligned with the reduction of CO2 in the atmosphere, through understanding the capturing efficacy of different absorbents under different operating conditions. Therefore, this study provided for the first time the comparison of available absorbents in relation to amine solvents (MEA, DEA, and DEA) CO2 removal efficiency, cost, and recirculation rate to achieve Climate change action through caron capture without causing absorbent disintegration. The study analyzed Flue under different amine-based solvent solutions (monoethanolamine (MEA), diethanolamine (DEA), and methyldiethanolamine (MDEA)), in order to compare their potential for CO2 reduction under different operating conditions and costs. This was simulated using ProMax 5.0 software modeled as a simple absorber tower to absorb CO2 from flue gas. Furthermore, MEA, DEA, and MDEA adsorbents were used with a temperature of 38 °C and their concentration varied from 10 to 15%. Circulation rates of 200–300 m3/h were used for each concentration and solvent. The findings deduced that MEA is a promising solvent compared to DEA and MDEA in terms of the highest CO2 captured; however, it is limited at the top outlet for clean flue gas, which contained 3.6295% of CO2 and less than half a percent of DEA and MDEA, but this can be addressed either by increasing the concentration to 15% or increasing the MEA circulation rate to 300 m3/h.


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