scholarly journals Molecular design for growth of supramolecular membranes with hierarchical structure

Soft Matter ◽  
2016 ◽  
Vol 12 (5) ◽  
pp. 1401-1410 ◽  
Author(s):  
R. Helen Zha ◽  
Yuri S. Velichko ◽  
Ronit Bitton ◽  
Samuel I. Stupp

Computational and experimental investigation of interfacial self-assembly between peptide amphiphiles and polyelectrolytes into microstructured membranes.

Author(s):  
Ziqi Liu ◽  
Xuan Tang ◽  
Feng Feng ◽  
Jing Xu ◽  
Can Wu ◽  
...  

Peptide amphiphile-based supramolecular hydrogels hold great promise in drug delivery applications. To cater for specific drug dose in a demanding biomedical scenario, sophisticated design of peptide amphiphile (PA) molecule is...


Soft Matter ◽  
2021 ◽  
Author(s):  
Zhiqiang Zhao ◽  
Zheng Bian ◽  
Yu Chen ◽  
Chuanqing Kang ◽  
Lianxun Gao ◽  
...  

Chiral oligo(methylene-p-phenyleneethynylene)s can form vesicular assemblies no matter whether side chains and solvents are hydrophilic or hydrophobic. The self-assembly processes are highly independent of molecular design and chemical environments.


2013 ◽  
Vol 58 (4) ◽  
pp. 927-931 ◽  
Author(s):  
Xu Wu ◽  
Xiaoxin Cai ◽  
Ahui Hao ◽  
Jinben Wang

2007 ◽  
Vol 5 (18) ◽  
pp. 47-54 ◽  
Author(s):  
A.P.J Middelberg ◽  
L He ◽  
A.F Dexter ◽  
H.-H Shen ◽  
S.A Holt ◽  
...  

We report the structure and Young's modulus of switchable films formed by peptide self-assembly at the air–water interface. Peptide surfactant AM1 forms an interfacial film that can be switched, reversibly, from a high- to low-elasticity state, with rapid loss of emulsion and foam stability. Using neutron reflectometry, we find that the AM1 film comprises a thin (approx. 15 Å) layer of ordered peptide in both states, confirming that it is possible to drastically alter the mechanical properties of an interfacial ensemble without significantly altering its concentration or macromolecular organization. We also report the first experimentally determined Young's modulus of a peptide film self-assembled at the air–water interface ( E =80 MPa for AM1, switching to E <20 MPa). These findings suggest a fundamental link between E and the macroscopic stability of peptide-containing foam. Finally, we report studies of a designed peptide surfactant, Lac21E, which we find forms a stronger switchable film than AM1 ( E =335 MPa switching to E <4 MPa). In contrast to AM1, Lac21E switching is caused by peptide dissociation from the interface (i.e. by self-disassembly). This research confirms that small changes in molecular design can lead to similar macroscopic behaviour via surprisingly different mechanisms.


ACS Nano ◽  
2018 ◽  
Vol 12 (3) ◽  
pp. 2160-2168 ◽  
Author(s):  
Franziska Jehle ◽  
Peter Fratzl ◽  
Matthew J. Harrington

2018 ◽  
Vol 6 (15) ◽  
pp. 3968-3975 ◽  
Author(s):  
Paula Gómez ◽  
Stamatis Georgakopoulos ◽  
José Pedro Cerón ◽  
Iván da Silva ◽  
Miriam Más-Montoya ◽  
...  

Molecular design for the self-assembly of molecular materials.


Cellulose ◽  
2020 ◽  
Vol 27 (9) ◽  
pp. 5241-5253 ◽  
Author(s):  
Lingfeng Yan ◽  
Baojiang Liu ◽  
Weiya Li ◽  
Tao Zhao ◽  
Yatao Wang ◽  
...  

2020 ◽  
Vol 8 (31) ◽  
pp. 6739-6752
Author(s):  
Kaiqi Long ◽  
Yuwei Liu ◽  
Yafei Li ◽  
Weiping Wang

This review introduces trigonal building blocks and summarizes their structural characteristics, self-assembly ability and biomedical applications.


2020 ◽  
Vol 421 ◽  
pp. 213418
Author(s):  
Jie Li ◽  
Jiqian Wang ◽  
Yurong Zhao ◽  
Peng Zhou ◽  
Jessica Carter ◽  
...  

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