scholarly journals A multi-dimensional quasi-zeolite with 12 × 10 × 7-ring channels demonstrates high thermal stability and good gas adsorption selectivity

2016 ◽  
Vol 7 (5) ◽  
pp. 3025-3030 ◽  
Author(s):  
Jie Liang ◽  
Wei Xia ◽  
Junliang Sun ◽  
Jie Su ◽  
Maofeng Dou ◽  
...  

A quasi-zeolite with three-dimensional 12 × 10 × 7-ring channels is synthesised and exhibits high thermal stability and good gas adsorption selectivity.

RSC Advances ◽  
2019 ◽  
Vol 9 (28) ◽  
pp. 16183-16186 ◽  
Author(s):  
W. Xu ◽  
S. S. Yu ◽  
H. Zhang ◽  
H. B. Duan

A MOFs compound [NH2(CH3)2]2[Zn3(bpdc)4]·3DMF (1) shows two step dielectric relaxation and its guest-free framework (1′) possesses an ultra-low κ value of 1.80 (at 100 kHz) over a wide temperature range and high thermal stability.


2021 ◽  
Author(s):  
Xiaota Cheng ◽  
Yang Si ◽  
Jianyong Yu ◽  
Bin Ding

Abstract Ceramic aerogels are attractive for many applications due to their ultralow density, high porosity, and multifunctionalities but are limited by the typical trade-off relationship between mechanical properties and thermal stability when used in extreme environments. In this work, we designed and synthesized a unique ceramic nanofibrous aerogels with three-dimensional (3D) interwoven crimped-nanofibre structures that endow the aerogels with superior mechanical performances and high thermal stability. These ceramic aerogels were synthesized by a direct and facile route, 3D reaction electrospinning. They displayed robust structural stability with structure-derived mechanical ultra-stretchability up to 100% tensile strain and superior restoring capacity up to 40% tensile strain, 95% bending strain and 60% compressive strain, high thermal stability from -196 to 1400°C, repeatable stretchability at working temperatures up to 1300 ℃, and a low thermal conductivity of 0.0228 W m−1 K−1 in air. This work should enable the innovative design of high-performance ceramic aerogels for various applications.


2022 ◽  
Author(s):  
Chun-Hua Gong ◽  
Xiaozong Hu ◽  
Zhen Han ◽  
Xiao-Fei Liu ◽  
Min-Zi Yang ◽  
...  

Using carboxylic acid linker, this work achieved the epitaxially coordination assembly of the Ag−S layer into three-dimensional semi-conductive framework, with high thermal stability, as well as interesting temperature-dependent luminescence response....


2016 ◽  
Vol 12 ◽  
pp. 2570-2576 ◽  
Author(s):  
Mathias Lang ◽  
Alexandra Schade ◽  
Stefan Bräse

Herein we report the syntheses of two porous hyper-crosslinked polymers (HCPs) via thiol–yne reaction with rigid tetrahedral and pseudo-octahedral core structures. Sorption measurements with nitrogen gas at 77 K revealed BET-surface areas up to 650 m²/g. Those networks also showed a high thermal stability as well as insolubility in common organic solvents.


RSC Advances ◽  
2020 ◽  
Vol 10 (54) ◽  
pp. 32609-32615 ◽  
Author(s):  
Haihong Xiao ◽  
Guoqing Ma ◽  
Junyu Tan ◽  
Shuai Ru ◽  
Zhaoquan Ai ◽  
...  

ZnCo2O4 has become one of the most widely used anode materials due to its good specific capacity, cost-efficiency, high thermal stability and environmental benignity.


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