scholarly journals A three-dimensional metal–organic framework for a guest-free ultra-low dielectric material

RSC Advances ◽  
2019 ◽  
Vol 9 (28) ◽  
pp. 16183-16186 ◽  
Author(s):  
W. Xu ◽  
S. S. Yu ◽  
H. Zhang ◽  
H. B. Duan
Keyword(s):  
Thermal Stability ◽  
Dielectric Relaxation ◽  
Wide Temperature Range ◽  
Dielectric Material ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
High Thermal Stability ◽  
Temperature Range ◽  
Low Dielectric ◽  
Metal Organic

A MOFs compound [NH2(CH3)2]2[Zn3(bpdc)4]·3DMF (1) shows two step dielectric relaxation and its guest-free framework (1′) possesses an ultra-low κ value of 1.80 (at 100 kHz) over a wide temperature range and high thermal stability.

Porous homo- and heterochiral cobalt(II) aspartates with high thermal stability of the metal-organic framework

2010 ◽  
Vol 59 (4) ◽  
pp. 733-740 ◽  
Author(s):  
M. P. Yutkin ◽  
M. S. Zavakhina ◽  
D. G. Samsonenko ◽  
D. N. Dybtsev ◽  
V. P. Fedin
Keyword(s):  
Thermal Stability ◽  
Metal Organic Framework ◽  
High Thermal Stability ◽  
Metal Organic ◽  
Thermal Stability Of ◽  
Organic Framework

A Novel (3,4,9)-Connected 3D Metal–Organic Framework Based on the Non-Planar Tricarboxyl Tecton and Zn5O4-Cluster SBU

2015 ◽  
Vol 68 (1) ◽  
pp. 161 ◽  
Author(s):  
Zhuo-Wei Wang ◽  
Hui Zhao ◽  
Min Chen ◽  
Min Hu
Keyword(s):  
Thermal Stability ◽  
Benzoic Acid ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Crystalline Material ◽  
Tripodal Ligand ◽  
Secondary Building Units ◽  
Metal Organic ◽  
Organic Framework

Combination of a non-planar tripodal ligand 3,4-bi(4-carboxyphenyl)-benzoic acid (H3L) and Zn5O4-cluster secondary building units affords a highly connected three-dimensional metal–organic framework, {[Zn5(μ3-OH)3(μ2-OH)L2(H2O)2](H2O)2}n (1), which exhibits an unusual (3,4,9)-connected (42.5)(3.43.52)(32.45.511.613.73.82) topological net. The thermal stability and solid luminescence of the crystalline material have also been investigated.

Superionic Conduction over a Wide Temperature Range in a Metal–Organic Framework Impregnated with Ionic Liquids

2019 ◽  
Vol 58 (32) ◽  
pp. 10909-10913 ◽  
Author(s):  
Yukihiro Yoshida ◽  
Kazuyuki Fujie ◽  
Dae‐Woon Lim ◽  
Ryuichi Ikeda ◽  
Hiroshi Kitagawa
Keyword(s):  
Ionic Liquids ◽  
Wide Temperature Range ◽  
Metal Organic Framework ◽  
Temperature Range ◽  
Metal Organic ◽  
Superionic Conduction ◽  
Organic Framework

Zn(ii)-based metal–organic framework: an exceptionally thermally stable, guest-free low dielectric material

2017 ◽  
Vol 5 (6) ◽  
pp. 1508-1513 ◽  
Author(s):  
Shruti Mendiratta ◽  
Muhammad Usman ◽  
Chun-Chi Chang ◽  
Yung-Chi Lee ◽  
Jenq-Wei Chen ◽  
...  
Keyword(s):  
Dielectric Material ◽  
Metal Organic Framework ◽  
Dielectric Behaviour ◽  
Thermally Stable ◽  
Low Dielectric ◽  
Metal Organic ◽  
Organic Framework

An exceptional thermally stable, chemically stable and guest-free Zn-based metal–organic framework exhibits low dielectric behaviour.

A lanthanide metal–organic framework with high thermal stability and available Lewis-acid metal sites

2006 ◽  
pp. 3172-3174 ◽  
Author(s):  
Xiaodan Guo ◽  
Guangshan Zhu ◽  
Zhongyue Li ◽  
Fuxing Sun ◽  
Zhenghong Yang ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Lewis Acid ◽  
Metal Organic Framework ◽  
High Thermal Stability ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Organic Framework
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