scholarly journals Experimental and computational study of alkane dehydrogenation catalyzed by a carbazolide-based rhodium PNP pincer complex

2016 ◽  
Vol 7 (4) ◽  
pp. 2579-2586 ◽  
Author(s):  
David Bézier ◽  
Changjian Guan ◽  
Karsten Krogh-Jespersen ◽  
Alan S. Goldman ◽  
Maurice Brookhart
Keyword(s):  
Computational Study ◽  
Rhodium Complex ◽  
Pincer Ligand ◽  
Alkane Dehydrogenation ◽  
Pincer Complex

A rhodium complex based on the bis-phosphine carbazolide pincer ligand was investigated in the context of alkane dehydrogenation and in comparison with its iridium analogue.

scholarly journals An electron poor iridium pincer complex for catalytic alkane dehydrogenation

2016 ◽  
Vol 45 (40) ◽  
pp. 15963-15969 ◽  
Author(s):  
Oleksandr O. Kovalenko ◽  
Ola F. Wendt
Keyword(s):  
Iridium Complex ◽  
Alkane Dehydrogenation ◽  
Pincer Complex ◽  
Dehydrogenation Reactions

A new electron deficient iridium complex demonstrates an improved TON in alkane transfer dehydrogenation reactions compared to similar pre-catalysts.

Synthesis, characterization, photophysical properties, and catalytic activity of an SCS bis(N-heterocyclic thione) (SCS-NHT) Pd pincer complex

2015 ◽  
Vol 44 (32) ◽  
pp. 14475-14482 ◽  
Author(s):  
Ginger E. Tyson ◽  
Kenan Tokmic ◽  
Casey S. Oian ◽  
Daniel Rabinovich ◽  
Henry U. Valle ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Photophysical Properties ◽  
Pincer Ligand ◽  
Pincer Complex

The first SCS-NHT pincer ligand and its Pd complex.

Crystalline Cu(ii) metal–organic frameworks based on a carboxamide pincer ligand and an NCONCON–Pd(ii) pincer complex

CrystEngComm ◽  
2021 ◽  
Author(s):  
Siphelele S. P. Malaza ◽  
Gift Mehlana ◽  
Ocean Cheung ◽  
Roger Hunter ◽  
Banothile C. E. Makhubela
Keyword(s):  
Carbon Dioxide ◽  
Metal Organic Frameworks ◽  
Organometallic Complexes ◽  
Carbon Dioxide Conversion ◽  
Pincer Ligand ◽  
Pincer Complex ◽  
Metal Organic

Two copper MOFs based on carboxamide linkers are presented. This work shows how organometallic complexes with carboxylate functionalities can be repurposed to produce crystalline MOFs which can be used in carbon dioxide conversion.

Exclusive C−C Activation in the Rhodium(I) PCN Pincer Complex. A Computational Study

2001 ◽  
Vol 20 (9) ◽  
pp. 1783-1791 ◽  
Author(s):  
Andreas Sundermann ◽  
Olivier Uzan ◽  
Jan M. L. Martin
Keyword(s):  
Computational Study ◽  
Pincer Complex

scholarly journals Metal–ligand cooperative activation of nitriles by a ruthenium complex with a de-aromatized PNN pincer ligand

2016 ◽  
Vol 45 (40) ◽  
pp. 16033-16039 ◽  
Author(s):  
Linda E. Eijsink ◽  
Sébastien C. P. Perdriau ◽  
Johannes G. de Vries ◽  
Edwin Otten
Keyword(s):  
Ruthenium Complex ◽  
Pincer Ligand ◽  
Pincer Complex ◽  
Cooperative Activation ◽  
Metal Ligand

Metal–ligand cooperative activation of nitriles by a de-aromatized Ru pincer complex leads to equilibrium mixtures (tautomers) as a result of ligand deprotonation by the Brønsted basic Ru-ketimido moiety.

Improved synthesis of pincer ligand precursor, and synthesis and structural characterization of terphenyl scaffolded S–C–S palladium pincer complex

2009 ◽  
Vol 12 (12) ◽  
pp. 1171-1174 ◽  
Author(s):  
Paul M. Schroder ◽  
Thomas F. Spilker ◽  
Wilson Luu ◽  
James B. Updegraff ◽  
Man Lung Kwan ◽  
...  
Keyword(s):  
Structural Characterization ◽  
Pincer Ligand ◽  
Pincer Complex

Reactivity of a T-Shaped Cobalt(I) Pincer-Complex

2021 ◽  
Author(s):  
Clemens Blasius ◽  
Regina Matveeva ◽  
Hubert Wadepohl ◽  
Lutz H Gade
Keyword(s):  
Carbon Monoxide ◽  
Neutral Ligand ◽  
Pincer Ligand ◽  
Pincer Complex

The reactivity of a paramagnetic T-shaped cobalt(I) complex, [(iPrboxmi)Co], stabilised by a monoanionic bis(oxazolinylmethylidene)-isoindolate (boxmi) NNN pincer ligand is described. The exposure to carbon monoxide as additional neutral ligand resulted...

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