Crystalline Cu(ii) metal–organic frameworks based on a carboxamide pincer ligand and an NCONCON–Pd(ii) pincer complex

CrystEngComm ◽  
2021 ◽  
Author(s):  
Siphelele S. P. Malaza ◽  
Gift Mehlana ◽  
Ocean Cheung ◽  
Roger Hunter ◽  
Banothile C. E. Makhubela
Keyword(s):  
Carbon Dioxide ◽  
Metal Organic Frameworks ◽  
Organometallic Complexes ◽  
Carbon Dioxide Conversion ◽  
Pincer Ligand ◽  
Pincer Complex ◽  
Metal Organic

Two copper MOFs based on carboxamide linkers are presented. This work shows how organometallic complexes with carboxylate functionalities can be repurposed to produce crystalline MOFs which can be used in carbon dioxide conversion.

In-situ cleavage and rearrangement synthesis of an easy-obtained and high stable Cu(II)-based MOF for efficient heterogeneous catalysis of carbon dioxide conversion

CrystEngComm ◽  
2021 ◽  
Author(s):  
Lan Qin ◽  
Yu Pan ◽  
Lei Yu ◽  
Ranran Huai ◽  
Lu Yang ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Heterogeneous Catalysis ◽  
Metal Organic Frameworks ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Carbon Dioxide Conversion ◽  
Metal Organic ◽  
Carbon Dioxide Co2

Cycloaddition into cyclic carbonates has been attracted substantial attentions for metal-organic frameworks based catalysis of carbon dioxide (CO2) chemical fixation, not only due to the contributions that solving the environmental...

Dual-linker metal-organic frameworks as efficient carbon dioxide conversion catalysts

2018 ◽  
Vol 566 ◽  
pp. 44-51 ◽  
Author(s):  
Xianghai Song ◽  
Yuanfeng Wu ◽  
Donghui Pan ◽  
Jiahui Zhang ◽  
Siquan Xu ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Metal Organic Frameworks ◽  
Carbon Dioxide Conversion ◽  
Metal Organic

N-Functionality Actuated Largely Improved CO2 Adsorption and Nanomolar Turn-on Detection of Organo-Toxins with Guest-Induced Fluorescence Modulation in Isostructural Diamondoid Frameworks

2021 ◽  
Author(s):  
Manpreet Singh ◽  
Athulya S. Palakkal ◽  
Renjith S. Pillai ◽  
Subhadip Neogi
Keyword(s):  
Carbon Dioxide ◽  
Functional Group ◽  
Co2 Adsorption ◽  
Metal Organic Frameworks ◽  
Turn On ◽  
Metal Organic ◽  
Fluorescence Modulation

Metal-organic frameworks (MOFs) have surfaced as incipient class of multifaceted materials for selective carbon dioxide (CO2) adsorption and luminescent detection of assorted classes of lethal organo-aromatics, where functional group assisted...

Synergistic effect of phosphomolybdic acid on rhodium-based metal-organic frameworks for the efficient selective photocatalytic reduction of CO2 to CO

2021 ◽  
Author(s):  
Yurong Shan ◽  
Dexiang Liu ◽  
Chunyan Xu ◽  
Peng Zhan ◽  
Hui Wang ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Electronic Structure ◽  
Synergistic Effect ◽  
Metal Organic Frameworks ◽  
Phosphomolybdic Acid ◽  
Photocatalytic Reduction ◽  
Structure And Morphology ◽  
Spherical Structure ◽  
Metal Organic ◽  
Reduction Of Co2

In this work, PMA@NH2-MIL-68(Rh) with a mangosteen spherical structure was successfully synthesized by a hydrothermal method for the photocatalytic reduction of carbon dioxide. The electronic structure and morphology of the...

Metal-organic frameworks for electrochemical reduction of carbon dioxide: The role of metal centers

2020 ◽  
Vol 40 ◽  
pp. 156-170 ◽  
Author(s):  
Ping Shao ◽  
Luocai Yi ◽  
Shumei Chen ◽  
Tianhua Zhou ◽  
Jian Zhang
Keyword(s):  
Carbon Dioxide ◽  
Electrochemical Reduction ◽  
Metal Organic Frameworks ◽  
Metal Centers ◽  
Metal Organic
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